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nowitzki_ci

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[资源] Polymer最新综述：乳液模板多孔聚合物

Emulsion-templated porous polymers: A retrospective perspective 共17页引文190篇
Michael S. Silverstein
Department of Materials Science and Engineering, Technion e Israel Institute of Technology, Haifa 32000, Israel

PolyHIPEs are porous emulsion-templated polymers synthesized within high internal phase emulsions
(HIPEs). HIPEs are highly viscous, paste-like emulsions in which the major, “internal” phase, usually
deﬁned as constituting more than 74% of the volume, is dispersed as discrete droplets within the
continuous, minor, “external” phase. The surge in polyHIPE research and development parallels that of
porous polymers in general and reﬂects the increasing number of potential applications (reaction sup-
ports, separation membranes, tissue engineering scaffolds, controlled release matrices, responsive and
smart materials, and templates for porous ceramics and porous carbons). This review focuses upon the
research and development in polyHIPEs through the prism of the work in our laboratory. The review
includes an overview of the developments in polymerization chemistry, in the types of monomers, in the
types of stabilization, in the generation of more complex polyHIPE-based systems (e.g. interpenetrating
polymer networks, hybrids, bicontinuous polymers), and in unusual materials systems such as water-
retaining polyHIPEs and shape-memory polyHIPEs.

[ Last edited by nowitzki_ci on 2014-5-10 at 19:36 ]

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2014-05-08 18:05:28, 6.11 M

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