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ZANCAI

新虫 (著名写手)

[交流] 请问什么是超顺磁性啊。

我看文献说纳米四氧化三铁有超顺磁性,什么是超顺磁性啊,与我们通常磁铁的磁性有区别吗,普通的四氧化三铁就没有超顺磁性吗,超顺磁性有什么应用吗?谢谢。
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FePt

木虫 (正式写手)


jackchen145(金币+1,VIP+0):谢谢应助!欢迎常来纳米版
这个解释起来太费劲,以下是Wikipedia的解释,看了一遍,大概能说清楚



Superparamagnetism
From Wikipedia, the free encyclopedia
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Superparamagnetism is a phenomenon by which magnetic materials may exhibit a behavior similar to paramagnetism even when at temperatures below the Curie or the Néel temperature. This is a small length-scale phenomenon, where the energy required to change the direction of the magnetic moment of a particle is comparable to the ambient thermal energy. At this point, the rate at which the particles will randomly reverse direction becomes significant.

Normally, coupling forces in ferromagnetic materials cause the magnetic moments of neighboring atoms to align, resulting in very large internal magnetic fields. This is what distinguishes ferromagnetic materials from paramagnetic materials. At temperatures above the Curie temperature (or the Neel temperature for antiferromagnetic materials), the thermal energy is sufficient to overcome the coupling forces, causing the atomic magnetic moments to fluctuate randomly. Because there is no longer any magnetic order, the internal magnetic field no longer exists and the material exhibits paramagnetic behavior. If the material is non-homogeneous, one can observe a mixture of ferromagnetic and paramagnetic clusters of atoms at the same temperature, the superparamagnetic stage. The idea of superparamagnetism is used in SuperParamagnetic Clustering algorithm (SPC) as well as in its extension global SPC.

Superparamagnetism occurs when the material is composed of very small crystallites (1–10 nm). In this case even when the temperature is below the Curie or Neel temperature (and hence the thermal energy is not sufficient to overcome the coupling forces between neighboring atoms), the thermal energy is sufficient to change the direction of magnetization of the entire crystallite. The resulting fluctuations in the direction of magnetization cause the magnetic field to average to zero. Thus the material behaves in a manner similar to paramagnetism, except that instead of each individual atom being independently influenced by an external magnetic field, the magnetic moment of the entire crystallite tends to align with the magnetic field.

The energy required to change the direction of magnetization of a crystallite is called the crystalline anisotropy energy and depends both on the material properties and the crystallite size. As the crystallite size decreases, so does the crystalline anisotropy energy, resulting in a decrease in the temperature at which the material becomes superparamagnetic.

The rate at which particles will lose their direction is governed by the Neel-Arrhenius equation. In particular, it is a function of the exponential of the grain volume.
2楼2008-03-10 11:35:42
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ZANCAI

新虫 (著名写手)

谢谢了,不过中文我还没有懂呢,更别说英文了。
3楼2008-03-10 13:14:47
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our360

木虫 (小有名气)

小兵


jackchen145(金币+1,VIP+0):谢谢应助!欢迎常来纳米版
当纳米粒子小到一定尺寸的时候,比如四氧化三铁粒子大小为十几二十纳米或者更小,每一个纳米粒子都相当于一个小的磁畴。当无外加磁场,粒子(磁畴)排列无序,表现为顺磁。当施加磁场,粒子按磁场排列,显示出铁磁(但比块体弱)。这就是我们常说的超顺磁了。而块体则不会,可以自己想象一下。
留颗丹心照汗青!
4楼2008-03-10 15:14:03
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chenkailai

想知道 你的材料是否有隐身性能么?

电磁参数和反射率测试(2~18GHz),可提供数据和曲线,价格根据数量而定( 一般为200元整个频段)。
张先生    zschenkai@163.com    13681011903            q19572435
5楼2008-03-10 21:10:18
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FePt

木虫 (正式写手)

很多概念英语比中文解释的清楚,呵呵
引用回帖:
Originally posted by ZANCAI at 2008-3-10 13:14:
谢谢了,不过中文我还没有懂呢,更别说英文了。

6楼2008-03-11 03:50:55
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ZANCAI

新虫 (著名写手)

可否大概地翻译一下啊,谢了。
7楼2008-03-11 08:54:34
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元小雪

木虫 (职业作家)

其实就是量子尺寸效应的作用了,找一些纳米材料科学导论的书看一下,应用都有的.我这里有,但是好长,又有些公式不好打出来
无聊的博士
8楼2008-03-13 09:05:56
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