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[资源] Chem. Soc. Rev.最新综述：Post-synthetic metalation of metal–organic frameworks

Post-synthetic metalation of metal–organic frameworks 共19页引文99篇
Jack D. Evans, Christopher J. Sumby and Christian J. Doonan*
School of Chemistry and Physics, Centre for Advanced Nanomaterials,
The University of Adelaide, Adelaide, South Australia, 5005, Australia.
E-mail: christian.doonan@adelaide.edu.au

Post-synthetic metalation (PSMet) oﬀers expansive scope for a targeted approach to tailoring the
properties of MOFs. Numerous methods for carrying-out PSMet chemistry have been reported,
however, these can be categorized into three general strategies: (a) addition to coordinating groups; (b)
counter-ion exchange in charged frameworks; or, (c) host–guest encapsulation of metal-containing
entities within the pores of the framework. PSMet has been applied to enhance the performance
characteristics of parent MOFs for gas storage and separation, and catalysis. Notably, PSMet is a
prominent strategy in the field of MOF catalysis as it offers a route to design size-selective catalysts, based
on the premise of reticular chemistry in MOFs and the ability to incorporate a range of catalytically-active
metal centres. Other applications for materials produced via or utilising PSMet strategies include
enhancing gas storage or molecular separations, the triggered release of drugs, sensing and tunable light
emission for luminescent materials. This review surveys seminal examples of PSMet to highlight the broad
scope of this technique for enhancing the performance characteristics of MOFs and to demonstrate how
the PSMet concept can be developed for future applications.

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