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Chem. Mater.最新综述: 纳米离子材料
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Nanoscale Ionic Materials 共13页 引文126篇 Nikhil J. Fernandes,† Thomas J. Wallin,‡ Richard A. Vaia, § Hilmar Koerner, § and Emmanuel P. Giannelis * , ‡ † School of Applied and Engineering Physics and ‡ Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853, United States § Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433, United States ABSTRACT: Within the general fi eld of polymer grafted or “ hairy ” nanoparticles, nanoscale ionic materials (NIMs), consisting of a soft polymeric canopy bound to a well-de fi ned nanoparticle core by an ionic bond, occupy a growing niche. They are the fi rst example of neat, self-suspended fl uids of nanoparticles (i.e., in the absence of a suspending medium). As such, the perennial dispersion challenges associated with polymer nanocomposites are minimized while the dynamic nature of the ionic bonds provides opportunities for self-healing behavior. Combining the properties of ionic liquids, charged colloid suspensions, and well-dispersed nanocomposites, this new materials platform o ff ers remarkable versatility for current and future applications. This perspective covers techniques and current challenges in synthesis, discusses the state of understanding of the theory behind their structure and properties, and examines successes and future prospects in application in a number of areas, notably in energy-related technologies.  |
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