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hsiaoeng.221新虫 (小有名气)
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论文求翻译
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Recently, Anslyn, James, and Bull introduced an attractive assay for the detection and ee analysis of primary amines that is based on a three-component assembly with enantiopure atropos BINOL and 2-formylphenylboronic acid. We assumed that the covalent binding of monoamines via condensation with a 2- formyl-4-methoxyphenylborate complex carrying binaphtholate 2 would yield a strong CD output originating from asymmetric amplification in our probe This largely changed when the same reaction was performed in the presence of 1 equiv of 2, and we observed significantly enhanced Cotton effects at higher wavelengths |
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