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[资料] Analytical Electrochemistry (Third Edition) by Joseph Wang
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有资料大家共享，别忘了评价啊 Analytical Electrochemistry (Third Edition) by Joseph Wang CONTENTS Preface xi Abbreviations and Symbols xiii 1 Fundamental Concepts 1 1.1 Why Electroanalysis?, 1 1.2 Faradaic Processes, 3 1.2.1 Mass-Transport-Controlled Reactions, 4 1.2.2 Reactions Controlled by the Rate of Electron Transfer, 12 1.3 Electrical Double Layer, 19 1.4 Electrocapillary Effect, 23 1.5 Supplementary Reading, 25 Problems, 27 References, 28 2 Study of Electrode Reactions and Interfacial Properties 29 2.1 Cyclic Voltammetry, 29 2.1.1 Data Interpretation, 32 2.1.2 Study of Reaction Mechanisms, 35 2.1.3 Study of Adsorption Processes, 37 2.1.4 Quantitative Applications, 41 2.2 Spectroelectrochemistry, 42 2.2.1 Experimental Arrangement, 43 2.2.2 Principles and Applications, 44 2.2.3 Electrochemiluminescence, 47 2.2.4 Optical Probing of Electrode–Solution Interfaces, 48 2.3 Scanning Probe Microscopy, 49 2.3.1 Scanning Tunneling Microscopy, 50 2.3.2 Atomic Force Microscopy, 51 2.3.3 Scanning Electrochemical Microscopy, 53 2.4 Electrochemical Quartz Crystal Microbalance, 57 2.5 Impedance Spectroscopy, 58 Examples, 61 Problems, 63 References, 64 3 Controlled-Potential Techniques 67 3.1 Chronoamperometry, 67 3.2 Polarography, 69 3.3 Pulse Voltammetry, 76 3.3.1 Normal-Pulse Voltammetry, 76 3.3.2 Differential-Pulse Voltammetry, 77 3.3.3 Square-Wave Voltammetry, 80 3.3.4 Staircase Voltammetry, 82 3.4 AC Voltammetry, 84 3.5 Stripping Analysis, 85 3.5.1 Anodic Stripping Voltammetry, 86 3.5.2 Potentiometric Stripping Analysis, 89 3.5.3 Adsorptive Stripping Voltammetry and Potentiometry, 91 3.5.4 Cathodic Stripping Voltammetry, 94 3.5.5 Abrasive Stripping Voltammetry, 94 3.5.6 Applications, 94 3.6 Flow Analysis, 98 3.6.1 Principles, 98 3.6.2 Cell Design, 100 3.6.3 Mass Transport and Current Response, 103 3.6.4 Detection Modes, 105 Examples, 108 Problems, 111 References, 112 4 Practical Considerations 115 4.1 Electrochemical Cells, 115 4.2 Solvents and Supporting Electrolytes, 117 viii CONTENTS 4.3 Oxygen Removal, 118 4.4 Instrumentation, 119 4.5 Working Electrodes, 123 4.5.1 Mercury Electrodes, 123 4.5.2 Solid Electrodes, 127 4.5.3 Chemically Modified Electrodes, 136 4.5.4 Microelectrodes, 149 Examples, 158 Problems, 158 References, 159 5 Potentiometry 165 5.1 Principles of Potentiometric Measurements, 165 5.2 Ion-Selective Electrodes, 173 5.2.1 Glass Electrodes, 173 5.2.1.1 pH Electrodes, 173 5.2.1.2 Glass Electrodes for Other Cations, 177 5.2.2 Liquid Membrane Electrodes, 177 5.2.2.1 Ion Exchanger Electrodes, 179 5.2.2.2 Neutral Carrier Electrodes, 182 5.2.3 Solid-State Electrodes, 185 5.2.4 Coated-Wire Electrodes and Solid-State Electrodes Without an Internal Filling Solution, 188 5.3 On-line, On-site, and In Vivo Potentiometric Measurements, 190 Examples, 194 Problems, 196 References, 197 CONTENTS ix 6 Electrochemical Sensors 201 6.1 Electrochemical Biosensors, 202 6.1.1 Enzyme-Based Electrodes, 202 6.1.2 Affinity Biosensors, 216 Imprinted Polymers, 224 6.2 Gas Sensors, 224 6.2.1 Carbon Dioxide Sensors, 225 6.2.2 Oxygen Electrodes, 226 6.3 Solid-State Devices, 227 6.3.1 Ion-Selective Field Effect Transistors, 227 6.3.2 Microfabrication of Solid-State Sensor Assemblies, 229 6.3.3 Microfabrication Techniques, 229 6.3.4 Micromachined Analytical Microsystems, 232 6.4 Sensor Arrays, 234 Examples, 237 Problems, 238 References, 239 [search]Analytical Electrochemistry[/search] http://www.isload.com.cn/store/06qgaotxscwhw/Analytical+Electrochemistry+%28Third+Edition%29.pdf/downlaod [ Last edited by Rainycc on 2008-2-29 at 08:39 ] |
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