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[资源] Adv. Mater.最新综述：空心结构介孔材料：化学合成，功能化与应用

Hollow-Structured Mesoporous Materials: Chemical Synthesis, Functionalization and Applications 共30页引文141篇
Yongsheng Li * and Jianlin Shi *

Hollow-structured mesoporous materials (HMMs), as a kind of mesoporous
material with unique morphology, have been of great interest in the past
decade because of the subtle combination of the hollow architecture with the
mesoporous nanostructure. Beneﬁ tting from the merits of low density, large
void space, large speciﬁ c surface area, and, especially, the good biocompat-
ibility, HMMs present promising application prospects in various ﬁ elds,
such as adsorption and storage, conﬁ ned catalysis when catalytically active
species are incorporated in the core and/or shell, controlled drug release,
targeted drug delivery, and simultaneous diagnosis and therapy of cancers
when the surface and/or core of the HMMs are functionalized with functional
ligands and/or nanoparticles, and so on. In this review, recent progress in the
design, synthesis, functionalization, and applications of hollow mesoporous
materials are discussed. Two main synthetic strategies, soft-templating and
hard-templating routes, are broadly sorted and described in detail. Progress
in the main application aspects of HMMs, such as adsorption and storage,
catalysis, and biomedicine, are also discussed in detail in this article, in terms
of the unique features of the combined large void space in the core and the
mesoporous network in the shell. Functionalization of the core and pore/
outer surfaces with functional organic groups and/or nanoparticles, and
their performance, are summarized in this article. Finally, an outlook of their
prospects and challenges in terms of their controlled synthesis and scaled
application is presented.