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However, extremely high mobilities are also observed in polymers with shorter bulky side chains, which challenges the notion that long linear chains are a necessity in high charge carrier mobility materials. In terms ofOPV performance, ethylhexyl side chains lead to very desirable phase separation in this polymer class (as observed by AFM) and extremely good device PCEs. Even shorter and bulkier side chains result in the formation of PCBM crystallites, whereas a long linear chain results in large domains. Further solid-state analysis of the interaction between the polymer side chains and the fullerene acceptor is ongoing and will be presented separately. |
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