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[资源]
RSC新作:铌酸盐粉体-溶剂热合成及其温度诱导形貌和结构转变
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One dimensional (1D) NaNbO3 powders have attracted increasing attention for their excellent photocatalytic and piezoelectric properties, and the stable, moderate and low-energy synthesis of the targets is highly desirable. Herein, a facial solvothermal strategy is adapted to synthesize the one-dimensional (1D) rod-like precursors Na7(H3O)Nb6O19$14H2O by using isopropanol as the reaction medium. When the precursor is subjected to post-heating treatments, rod-like orthorhombic as well as approximate ellipsoid-like monoclinic NaNbO3 powders are obtained. Corresponding mechanisms for the stable solvothermal synthesis, morphological evolution and phase transition are further proposed and discussed. |
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2014-03-28 08:45:42, 1.04 M
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