| 查看: 1544 | 回复: 35 | ||||||||
| 【奖励】 本帖被评价31次，作者nowitzki_ci增加金币 24.8 个 | ||||||||
nowitzki_ci专家顾问 (著名写手)
|
[资源]
Acc. Chem. Res. 热点综述：基于石墨烯的有机合成
|
|||||||
|
Organic Synthesis on Graphene FABIAN M. KOEHLER AND WENDELIN J. STARK* Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zurich, Switzerland 共10页 引文68篇 CONSPECTUS Graphene is a two-dimensional crystalline carbon allotrope that has fascinated researchers worldwide and has extended the interest in carbon structures such as fullerenes and nanotubes. In this Account, we use electrical characterization tools to study chemistry on supported graphene. These experiments elucidate the way covalently bound phenyl units can change graphene's physical properties. Can we use chemistry to control electronic properties of graphene? What can we learn from well- known carbon allotropes like fullerenes? The surfaces of fullerenes and graphene show distinct differences in reactivity because of the high strain of sp2carbon in fullerenes compared with the complete lack of strain in graphene. Diazonium chemistry provides a versatile tool for attaching phenyl units covalently to carbon to produce advanced materials and electronic components, but diazonium-based carbon chemistry is strongly influenced by strain. Although fullerenes are highly reactive, graphite (stacks of graphene) remains relatively inert. We chemically introduce n- and p-like doping patterns in two-dimensional graphene using photolithography and extend the ability to chemically control doping to the chemical design of conducting and insulating areas. Thereby we can shape graphene surfaces into functional electronic devices. This Account also describes multistep synthesis on graphene-coated nanoparticles and the introduction of various functional groups on graphene surfaces. Only few functional groups can be produced directly via diazonium chemistry. To overcome this issue, we used these functional groups as starting points for more demanding organic reactions. We covalently attached chelating agents, catalysts, or polymers on the carbon surface. These more complex reactions facilitate the design of electronic modifications, intergraphene connections, and anchors for polymer incorporation. Diazonium chemistry forms strong covalent bridges between graphene and other areas of chemistry. Biography Fabian M. Koehler received his M.Sc. degree in Chemical- and Bioengineering from ETH Zurich along with the Willi-Studer Award for outstanding master students. He obtained the Ph.D. degree for his thesis about electronic transport analysis of chemically modified graphene from ETH Zurich in 2011. Currently, he is a Pioneer Fellow at the Functional Materials Laboratory of ETH Zurich responsible for the development of next generation diagnostics focused on rapid and quantitative point of need analysis. Biography Wendelin J. Stark received his Master in Chemistry in 2000, followed by a Ph.D. in Mechanical Engineering in 2002, both from ETH Zurich. In 2004, he founded the Functional Materials Laboratory within the Department of Chemistry and Applied Bioscience at the ETH Zurich. His research group pursues application-oriented research at the interface of chemistry with material science and medicine.  [ Last edited by nowitzki_ci on 2014-3-26 at 12:12 ] |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : ar300125w.pdf
2014-03-25 17:09:16, 3.33 M
» 收录本帖的淘帖专辑推荐
 文献推荐 | 电化学电源、电源管理 | 资料 | 实验分析方法 |
» 猜你喜欢
稀土发光分析｜核壳结构｜寿命拟合
已经有13人回复
-
稀土发光分析｜核壳结构｜寿命拟合
已经有6人回复
-
无机化学论文润色/翻译怎么收费?
已经有148人回复
-
稀土发光分析｜核壳结构｜寿命拟合
已经有0人回复
-
稀土发光分析｜核壳结构｜寿命拟合
已经有0人回复
-
26 届青岛大学纺织化学与染整工程硕士（液体纳米分散染料方向）求申博建议
已经有4人回复
-
26 届青岛大学纺织化学与染整工程（液体纳米分散染料）求浙理工纺织 / 材料博导名额
已经有1人回复
-
敢问Acta Pharmaceutica Sinica B with Editor 三周了，能是什么情况？
已经有0人回复
-
求助 CeO2 Fe3O4 Cu2S CoFe2O4 标准卡 Jade 导出的数据
已经有0人回复
-
招生--河北大学26年秋季入学博士
已经有1人回复
-
求助一篇MEMS散热器件文献
已经有0人回复
» 本主题相关商家推荐: (我也要在这里推广)
» 本主题相关价值贴推荐，对您同样有帮助:
- Chemical Reviews热点综述：Magnetic Nanoparticles 磁性纳米粒子
已经有168人回复
- Nature最新石墨烯进展：大面积石墨烯的面对面转移技术
已经有345人回复
- 分享——纳米结构的薄膜与涂料：功能化性能（英文版）
已经有402人回复
- Acc Chem Res 最新综述 : 石墨烯发展的安全顾虑 - 碳纳米管的教训
已经有249人回复
- Acc Chem Res 最新综述：石墨烯的制备及其应用
已经有116人回复
- Acc Chem Res 综述 : 石墨烯纳米复合材料在太阳能转换，储存，传感方面的前景
已经有131人回复
- Acc. Chem. Res.最新综述：具有介孔-大孔多级纳米结构的碳材料---设计、表征及应用
已经有465人回复
- Acc. Chem. Res.最新综述：碳基催化剂---氧化石墨烯及其衍生物
已经有230人回复
- Acc. Chem. Res.最新综述：基于大面积高质量石墨烯薄膜的杂化功能系统
已经有151人回复
- Acc. Chem. Res.最新综述：用于太阳能转化、存储、传感的石墨烯基复合物的设计与展望
已经有214人回复
- Acc. Chem. Res.最新综述：纳米石墨烯和石墨烯边缘---电子结构以及纳米制造
已经有100人回复
- 化学所在石墨烯可控制备和性能研究方面取得系列进展
已经有17人回复
- Chem. Soc. Rev.最新综述：纳米复合物与宏观材料-化学修饰的石墨烯片的组装
已经有312人回复
- 超级电容器大牛Y. Gogotsi在Acc. Chem. Res.的最新综述-纳米碳材料的电容能量存储
已经有1039人回复
简单回复
pipi2楼
2014-03-25 19:29
回复
五星好评 顶一下，感谢分享！
2014-03-25 22:53
回复
顶一下，感谢分享！ [ 发自手机版 http://muchong.com/3g ]
林紫4楼
2014-03-25 23:10
回复
五星好评 顶一下，感谢分享！
2014-03-25 23:17
回复
五星好评 顶一下，感谢分享！
lwg36楼
2014-03-26 09:46
回复
五星好评 顶一下，感谢分享！
2014-03-27 14:01
回复
五星好评 顶一下，感谢分享！
2014-03-27 17:10
回复
五星好评 顶一下，感谢分享！
错落的光景9楼
2014-03-28 00:29
回复
五星好评 顶一下，感谢分享！
afu2008200810楼
2014-03-28 02:01
回复
五星好评 顶一下，感谢分享！
greenecho11楼
2014-03-28 07:44
回复
五星好评 顶一下，感谢分享！
jinronghua12楼
2014-03-28 08:44
回复
五星好评 顶一下，感谢分享！
温心若水13楼
2014-03-28 09:02
回复
五星好评 顶一下，感谢分享！
温心若水14楼
2014-03-28 09:02
回复
黄酮15楼
2014-03-28 10:08
回复
五星好评 顶一下，感谢分享！
islijin16楼
2014-03-28 11:34
回复
五星好评 顶一下，感谢分享！
2008013083617楼
2014-03-28 11:40
回复
五星好评
fire2hell18楼
2014-03-28 12:04
回复
五星好评 顶一下，感谢分享！
marchfeng19楼
2014-03-28 12:52
回复
五星好评 顶一下，感谢分享！
gengxin6020楼
2014-03-28 13:46
回复
五星好评 顶一下，感谢分享！
firechen98721楼
2014-03-28 14:29
回复
五星好评 顶一下，感谢分享！
lj110822楼
2014-03-28 17:13
回复
五星好评 顶一下，感谢分享！
fmbs11023楼
2014-03-28 17:22
回复
五星好评 顶一下，感谢分享！
yzj197224楼
2014-03-29 07:36
回复
五星好评 顶一下，感谢分享！
liu12325楼
2014-03-29 17:22
回复
五星好评 顶一下，感谢分享！
xiaoshm26楼
2014-03-29 18:15
回复
五星好评 顶一下，感谢分享！
yhxu195827楼
2014-03-29 22:32
回复
五星好评 顶一下，感谢分享！
杨sir28楼
2014-03-29 22:42
回复
五星好评 顶一下，感谢分享！
wangpinger29楼
2014-03-29 22:53
回复
五星好评 顶一下，感谢分享！
beidiwang30楼
2014-03-30 09:11
回复
五星好评 顶一下，感谢分享！
05061010531楼
2014-04-21 12:27
回复
五星好评 顶一下，感谢分享！
wangpinger32楼
2014-05-01 21:25
回复
顶一下，感谢分享！
05061010533楼
2014-05-04 16:13
回复
顶一下，感谢分享！
51532952534楼
2014-12-01 17:45
回复
五星好评 顶一下，感谢分享！
1230503135楼
2014-12-22 21:25
回复
五星好评 顶一下，感谢分享！
158246143036楼
2015-04-07 15:07
回复
五星好评 顶一下，感谢分享！
50