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Lagergren equation represents the pseudo-first order kinetics for the whole adsorption reaction, with a one-partial order with respect to the free concentration sites and a zero-partial order with respect to the solute in the solution.

In this case, the pseudo-second order kinetics for the whole adsorption reaction, it may be accepted a two-partial order with respect to the free sites concentration and a zero partial with respect to the solute in the solution.
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