| 查看: 11935 | 回复: 408 | |||||||||||||||||||||||||||||
| 【奖励】 本帖被评价252次，作者nowitzki_ci增加金币 200 个 | |||||||||||||||||||||||||||||
| 本帖产生 2 个 MN-EPI ，点击这里进行查看 | |||||||||||||||||||||||||||||
nowitzki_ci专家顾问 (著名写手)
|
[资源]
Chem. Soc. Rev.热点综述：模板法制备纳米结构材料——殷亚东出品
|
||||||||||||||||||||||||||||
|
Templated synthesis of nanostructured materials 44页 引文431篇 In the past two decades, tremendous efforts have been made towards the development of synthetic strategies for nanostructured materials with well controlled size, shape, composition and spatial arrangement. Synthesis using a pre-existing nanostructured tem- plate is one of the most effective strategies towards achieving high degrees of synthetic control. As defined in the Merriam-Webster’s Dictionary, a template is a ‘‘gauge, pattern or mold used as a guide to the form of a piece being made,’’ which reveals the general advantages of templated synthesis. Typically, nanomaterials synthesized by templating strategies hold a well-defined size, shape and configuration, which usually benefits from the directing effect of the templates. The general route for templated synthesis of nanostructured materials includes the following steps: (1) template preparation, (2) directed synthesis of target materials using the template, and (3) template removal (if necessary). In nanoscale synthesis, theoretically, a template can be any substance with nanostructured features. Thus, there are abun- dant types of materials that can be taken into consideration. Some are naturally occurring (such as nanostructured minerals, biological molecular assemblies, and organs), while others are sourced from synthetic nanostructures which usually benefit from pre-existing synthesis methods (both direct synthesis and templated synthesis), including top-down and bottom-up approaches. Their physical properties can vary greatly, from soft materials such as molecular assemblies to hard materials such as colloidal particles, porous membranes and patterned solid surfaces. With regard to their chemical properties, they can either behave as a pure physical directing agent, which we refer to as a physical template, or as a physical director which is also involved in a chemical transformation during the synthesis, which we refer to as a chemical template. For the synthesis of target materials, synthetic strategies based on physical templates include a variety of methods such as surface coating and channel replication. In cases of chemical templated synthesis, chemical transformations during the synthesis may include isomerisation, addition, substitution and elimination of chemical species. As a result, nearly all types of materials can be utilized, from metals, semiconductors, and ceramics to soft polymers, to form zero-dimensional (0D) nano- particles, one-dimensional (1D) nanowires and two- and three- dimensional (2D and 3D) hierarchical nanostructures. In order to remove the template after synthesis, as long as the physical and chemical properties of the resultant materials can be preserved, both physical methods such as dissolution and chemical methods including calcination and etching can be applied according to the nature of the templates. In this review, we aim to review the development of template- based synthetic strategies for nanostructured materials. To fully examine the procedures of different templated synthesis methods while comprehensively covering all types of templates, the organization of a review on this topic should be based either on the types of templates or the classification of synthetic methods, as shown in Scheme 1. Herein, we choose the former in order to emphasize the importance of template preparation methods, while different synthetic methods are sorted to an extent as most synthetic strategies are only utilized in conjunc- tion with certain types of templates. Overall, the discussion of templates will be divided between colloidal and non-colloidal templates. Of the colloidal type templates, templated synthesis on hard colloids will be introduced in cases of both physical (Section 2) and chemical (Section 3) templating. Templated synthesis on soft materials will be introduced afterwards (Section 4). Finally, various types of templated syntheses on other non-colloidal templates will be discussed (Section 5). In each section, the discussion will focus on the preparation of templates and classical synthesis techniques based on these specific templates. In some cases, template removal strategies as well as comments on their advantages and disadvantages will also be included. After covering each class of templated synthesis, we will conclude with our opinions on the future direction of the field and important areas for further research.  [ Last edited by nowitzki_ci on 2014-3-12 at 17:18 ] ·  [ Last edited by nowitzki_ci on 2015-2-7 at 22:44 ] |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : c2cs35369e.pdf
2014-03-12 17:17:03, 6.92 M
» 收录本帖的淘帖专辑推荐
 资源收集 | 纳米技术与能源及模拟 | 文献推荐 | 电化学电源、电源管理 |
| 光电化学及电化学 | 科技相关 | reviews paper | 综述精华集 |
| 专业书 | 纳米大牛 | 材料淘贴收录 | porous and hollow structures |
| 纳米 | 催化 | 科研资料 | 优秀帖子 |
| 功能复合材料F | 生化科研 | 导电聚合物F | 文献 |
| 经典论文集 | 杂货铺 | 光催化材料 | 急用 |
| 文献zy |
» 本帖已获得的红花（最新10朵）
chzlf2797131» 猜你喜欢
有关蒙脱土阳离子交换的问题！求助！
已经有2人回复
-
荧光粉分散在水溶液里经过光照射后可以看到荧光
已经有2人回复
-
无机化学论文润色/翻译怎么收费?
已经有88人回复
-
碳量子点
已经有0人回复
-
请教关于高温固相法合成氟取代氧化物的细节
已经有15人回复
-
【新加坡】【南洋理工大学】招聘博士后一名（Research Fellow）
已经有43人回复
-
钙钛矿 博士申请
已经有5人回复
-
求助 光强I=(ρνω^2A^2)/2 是怎么推导出来的 ？
已经有0人回复
-
钙钛矿 博士申请
已经有5人回复
-
25年申博，求导收留（24/25）
已经有1人回复
» 本主题相关商家推荐: (我也要在这里推广)
» 本主题相关价值贴推荐，对您同样有帮助:
简单回复
相识是缘2楼
2014-03-12 17:58
回复
五星好评 顶一下，感谢分享！
wkkkk3楼
2014-03-12 19:34
回复
五星好评 顶一下，感谢分享！
2014-03-12 19:41
回复
五星好评 顶一下，感谢分享！
2014-03-12 22:39
回复
五星好评 顶一下，感谢分享！
2014-03-13 08:31
回复
五星好评 顶一下，感谢分享！
2014-03-13 08:45
回复
五星好评 顶一下，感谢分享！
笃志笃行8楼
2014-03-13 11:19
回复
五星好评 顶一下，感谢分享！
2014-03-13 13:40
回复
五星好评 顶一下，感谢分享！
xuelai200910楼
2014-03-13 16:15
回复
五星好评 顶一下，感谢分享！
tandy_396411楼
2014-03-13 16:37
回复
五星好评 顶一下，感谢分享！
limh77052212楼
2014-03-13 18:13
回复
五星好评 顶一下，感谢分享！
guohuiqin13楼
2014-03-13 19:05
回复
五星好评 顶一下，感谢分享！
wangpinger14楼
2014-03-13 19:40
回复
五星好评 顶一下，感谢分享！
xiaolove200015楼
2014-03-13 20:25
回复
五星好评 顶一下，感谢分享！
guohuitian16楼
2014-03-13 20:58
回复
五星好评 顶一下，感谢分享！
songcumt17楼
2014-03-13 21:19
回复
五星好评 顶一下，感谢分享！
雪莲18楼
2014-03-14 08:17
回复
五星好评 顶一下，感谢分享！
songfoo19楼
2014-03-14 08:28
回复
五星好评 顶一下，感谢分享！
rzsongzc20楼
2014-03-14 08:56
回复
五星好评 顶一下，感谢分享！
xiu22121楼
2014-03-14 09:12
回复
五星好评 顶一下，感谢分享！
kaka0091322楼
2014-03-14 09:41
回复
五星好评 顶一下，感谢分享！
sjp038823楼
2014-03-14 09:52
回复
五星好评 顶一下，感谢分享！
鸢尾草24楼
2014-03-14 11:03
回复
五星好评 顶一下，感谢分享！
linzhirong25楼
2014-03-14 11:15
回复
五星好评 顶一下，感谢分享！
houyong26楼
2014-03-14 11:18
回复
五星好评 顶一下，感谢分享！
axblove27楼
2014-03-14 12:41
回复
五星好评 顶一下，感谢分享！
jiaguozhi28楼
2014-03-14 13:56
回复
五星好评 顶一下，感谢分享！
wu_gang100029楼
2014-03-14 14:07
回复
五星好评 顶一下，感谢分享！
situwanran30楼
2014-03-14 14:40
回复
五星好评 顶一下，感谢分享！
xiaoqij31楼
2014-03-14 14:58
回复
五星好评 顶一下，感谢分享！
可清天地心32楼
2014-03-14 16:39
回复
五星好评 顶一下，感谢分享！
粽子zst33楼
2014-03-14 17:00
回复
五星好评 顶一下，感谢分享！
chen_san34楼
2014-03-14 17:06
回复
五星好评 顶一下，感谢分享！
凤雏卧龙35楼
2014-03-14 17:22
回复
五星好评 顶一下，感谢分享！
yishengaihui36楼
2014-03-14 18:56
回复
三星好评 顶一下，感谢分享！
2014-03-14 19:03
回复
五星好评 顶一下，感谢分享！
liontu38楼
2014-03-14 19:44
回复
五星好评 顶一下，感谢分享！
那儿一梦39楼
2014-03-14 19:44
回复
五星好评 顶一下，感谢分享！
hellopanhh40楼
2014-03-14 20:00
回复
五星好评 顶一下，感谢分享！
duyuch41楼
2014-03-14 20:30
回复
五星好评 顶一下，感谢分享！
飞大人42楼
2014-03-15 10:17
回复
五星好评 顶一下，感谢分享！
krlp43楼
2014-03-15 10:43
回复
五星好评 顶一下，感谢分享！
tienslord44楼
2014-03-15 10:47
回复
五星好评 顶一下，感谢分享！
乾坤亮45楼
2014-03-15 11:07
回复
五星好评 顶一下，感谢分享！
jianganbang46楼
2014-03-15 11:19
回复
五星好评 顶一下，感谢分享！
cliao47楼
2014-03-15 12:30
回复
五星好评 顶一下，感谢分享！
fire2hell48楼
2014-03-15 12:55
回复
五星好评 顶一下，感谢分享！
wohao.200949楼
2014-03-15 14:34
回复
五星好评 顶一下，感谢分享！
huayuwuqi50楼
2014-03-15 14:38
回复
五星好评 顶一下，感谢分享！
10