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Preparation and photocatalytic activity of nano-TiO2 codoped with fluorine and ferric
作者:
LI Fa-tang等
期刊
Transactions of Nonferrous Metals Society of China,2007,S1期
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Preparation and photocatalytic activity of nano-TiO2 codoped with fluorine and ferric
  
Peking Univ Xiamen Univ             more options  


Author(s): Li FT (Li Fa-tang), Liu RH (Liu Rui-hong), Zhao DS (Zhao Di-shun), Sun ZM (Sun Zhi-min), Qu ZM (Qu Zhi-min)  
Source: TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA    Volume: 17    Special Issue: Part B Sp. Iss. 1    Pages: S713-S715    Part: Part B Sp. Iss. 1    Published: 2007   
Times Cited: 0     References: 13      
Abstract: Nano-F-/Fe3+/TiO2 particles were prepared by hydrolysis of tetrabutyl titanate in a mixed CF3COOH-Fe(NO3)(3)-H2O solution. The photocatalytic decomposition of methylene blue in aqueous solution was used as a probe to evaluate their photocatalytic activities. The powders were characterized by X-ray diffraction (XRD), energy dispersion X-ray spectrum (EDS) and Brunauer-Emmett-Teller (BET) surface area analysis. The results show that F and Fe3+ are doped into TiO2. The F and Fe3+ doping can help to enhance the nano-TiO2 photocatalytic activity greatly. The appropriate codoping conditions for F-Fe are n(F)/n(TiO2)=2%, n(Fe)/n(TiO2)=0.05%, and the degradation rate of methylene blue at I h is improved from 73.2% to 87.5%. The codoped nano-F-/Fe3+/TiO2 particles have higher BET specific surface area, smaller crystallite size and higher photocatalytic activity than those of undoped TiO2 particles.
Document Type: Article  
Language: English  
Author Keywords: nano-TiO2; F/Fe3+/TiO2; codoping; photocatalytic activity  
KeyWords Plus: TIO2 POWDERS; METHANOL  
Addresses: Li, FT (reprint author), Hebei Univ Sci & Techmol, Coll Sci, Shijiazhuang 050018, Peoples R China
Hebei Univ Sci & Techmol, Coll Sci, Shijiazhuang 050018, Peoples R China
Hebei Univ Sci & Technol, Coll Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China
Hebei Engn Univ, Sch Civil Engn, Handan 056038, Peoples R China  
E-mail Addresses: lifatang@126.com  
Publisher: ALLERTON PRESS INC, 18 WEST 27TH ST, NEW YORK, NY 10001 USA  
IDS Number: 242PJ  
ISSN: 1003-6326
2楼2008-02-14 13:19:45
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3楼2008-02-14 14:04:39
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