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Page 1 (Records 1 -- 1): [1 ] Record 1 of 1 Author(s): Wu, H (Wu, Hong); Zheng, B (Zheng, Bin); Zheng, XH (Zheng, Xiaohong); Wang, JT (Wang, Jingtao); Yuan, WK (Yuan, Weikang); Jiang, ZY (Jiang, Zhongyi) Title: Surface-modified Y zeolite-filled chitosan membrane for direct methanol fuel cell Source: JOURNAL OF POWER SOURCES, 173 (2): 842-852 NOV 15 2007 Language: English Document Type: Article Author Keywords: chitosan; zeolite; silane coupling agent; hybrid membrane; methanol permeability; proton conductivity Keywords Plus: POLYMER ELECTROLYTE MEMBRANE; PROTON-EXCHANGE MEMBRANE; MIXED MATRIX MEMBRANES; COMPOSITE MEMBRANES; PERVAPORATION SEPARATION; NANOCOMPOSITE MEMBRANES; BLEND MEMBRANES; DEHYDRATION; CROSSOVER; PERFORMANCE Abstract: Hybrid membranes composed of chitosan (CS) as organic matrix and surface-modified Y zeolite as inorganic filler are prepared and their applicability for DMFC is demonstrated by methanol permeability, proton conductivity and swelling property. Y zeolite is modified using silane coupling agents, 3-aminopropyl-triethoxysilane (APTES) and 3-mereaptopropyl-trimethoxysilane (MPTMS), to improve the organic-inorganic interfacial morphology. The mercapto group on MPTMS-modified Y zeolite is further oxidized into sulfonic group. Then, the resultant surface-modified Y zeolites with either aminopropyl groups or sulfonicpropyl groups are mixed with chitosan in acetic acid solution and cast into membranes. The transitional phase generated between chitosan matrix and zeolite filler reduces or even eliminates the nonselective voids commonly exist at the interface. The hybrid membranes exhibit a significant reduction in methanol permeability compared with pure chitosan and Nation 117 membranes, and this reduction extent becomes more pronounced with the increase of methanol concentration. By introducing -SO3H groups onto zeolite surface, the conductivity of hybrid membranes is increased up to 2.58 x 10(-2) S cm(-1). In terms of the overall selectivity index (beta = sigma/P), the hybrid membrane is comparable with Nation 117 at low methanol concentration (2 mol L-1) and much better (three times) at high methanol concentration (12 mol L-1). (C) 2007 Elsevier B.V. All rights reserved. Addresses: Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China Reprint Address: Jiang, ZY, Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China. E-mail Address: zhyjiang@tju.edu.cn Cited Reference Count: 42 Times Cited: 0 Publisher: ELSEVIER SCIENCE BV Publisher Address: PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS ISSN: 0378-7753 29-char Source Abbrev.: J POWER SOURCES ISO Source Abbrev.: J. Power Sources Source Item Page Count: 11 Subject Category: Electrochemistry; Energy & Fuels ISI Document Delivery No.: 231FQ -------------------------------------------------------------------------------- Page 1 (Records 1 -- 1): [1 ] -------------------------------------------------------------------------------- Acceptable Use Policy Copyright © 2006 The Thomson Corporation |
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