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至尊木虫 (著名写手)

[交流] MWCNT在260~290nm波长范围内的吸收峰

  很多文献用分光光度(UV-vis photospectrometer)表征MWCNT在溶液中悬浮的“浓度”。SWCNT在260~290nm波长范围内有吸收峰,这是有理论解释的,吸收峰和SWCNT直径、手性有关(H.J. Huang, H. Kajiura, and R. Maruyama, et al. , Relative optical absorption of metallic and semiconducting single-walled carbon nanotubes. JOURNAL OF PHYSICAL CHEMISTRY B, 2006. 110(10): p. 4686-4690.)。可是,看了N多文献,看了N多二次文献,却从来没有看到一篇文献正面解释为什么MWCNT有这个吸收峰。所有文章几乎都套用SWCNT的理论解释,来说明MWCNT用UV-vis的道理。真不解。两者的机理一样吗?
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my050666

木虫 (著名写手)

同样期待中,支持下。
2楼2008-01-16 23:21:47
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至尊木虫 (著名写手)

贴一下分散的相关文献

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[30].        L. Zhao and L. Gao, Stability of multi-walled carbon nanotubes dispersion with copolymer in ethanol. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2003. 224(1-3): p. 127-134.
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[36].        D. Li, H.Z. Wang, and J.W. Zhu, et al. , Dispersion of carbon nanotubes in aqueous solutions containing poly(diallyldimethylammonium chloride). JOURNAL OF MATERIALS SCIENCE LETTERS, 2002. 22(4): p. 253-255.
[37].        R. Bandyopadhyaya, E. Nativ-Roth, and O. Regev, et al. , Stabilization of individual carbon nanotubes in aqueous solutions. NANO LETTERS, 2002. 2(1): p. 25-28.
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[39].        Z.X. Jin, L. Huang, and S.H. Goh, et al. , Characterization and nonlinear optical properties of a poly(acrylic acid)-surfactant-multi-walled carbon nanotube complex. CHEMICAL PHYSICS LETTERS, 2000. 332(5-6): p. 461-466.
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low-key
3楼2008-01-17 11:30:40
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