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ÄÄλ´óÏÀÄܰïÎÒ²é²é Polymerization and chiroptical behavior of N-[o-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl) phenyl] methacrylamide AMM(2014) 477-478¾ípp 1187-1191 ÊÇ·ñ±»¼ìË÷ÁË£¿×éί»á˵ÊÇ¿ÉÒÔ¼ìË÷ÁË£¬Ð»Ð» |
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glenda007982: ½ð±Ò+5, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2014-02-07 20:56:52
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glenda007982: ½ð±Ò+5, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸ 2014-02-07 20:56:52
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Accession number: 20140417220564 Title: Polymerization and chiroptical behavior of N-[o-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl) phenyl] methacrylamide Authors: Fu, Zheng1 Email author fz19820528@163.com; Wei, Hong1 Email author bailing8861@sina.com; Ding, Yang2 Email author sunnyland@163.com; Yuan, Chao1 Email author yuanchao3723@163.com Author affiliation: 1 Department of Pharmacy, Shandong Medical College, Jinan 250002, China 2 Dean's Office, Shandong Medical College, Jinan 250002, China Corresponding author: Yuan, C. (yuanchao3723@163.com) Source title: Applied Mechanics and Materials Abbreviated source title: Appl. Mech. Mater. Volume: 477-478 Monograph title: Applied Mechanics and Materials II Issue date: 2014 Publication year: 2014 Pages: 1187-1191 Language: English ISSN: 16609336 E-ISSN: 16627482 ISBN-13: 9783037859841 Document type: Conference article (CA) Conference name: 2013 2nd International Conference on Applied Mechanics and Materials, ICAMM 2013 Conference date: November 23, 2013 - November 24, 2013 Conference location: Zhuhai, China Conference code: 101957 Publisher: Trans Tech Publications Ltd, Kreuzstrasse 10, Zurich-Durnten, CH-8635, Switzerland Abstract: The radical polymerization of optically active methacrylamide derivative, N- [o-(4-isopropyl-4,5-dihydro -1,3-oxazol-2-yl)phenyl] methacrylamide ((S)-MeOPMAM), was carried out under various conditions. The effect of Lewis acid, that is, rare earth metal trifluoromethanesulfonates on the free-radical polymerization were examined under different solvents. The polymerization in the presence of rare earth metal trifluoromethanesulfonates produced isotactic-rich polymers compared with those obtained without the Lewis acid. The polymerization characteristics and the chiroptical behavior of the resultant polymers have been examined by using circular dichroism (CD), UV-Vis, and NMR spectroscopies. © (2014) Trans Tech Publications, Switzerland. Number of references: 16 Main heading: Polymers Controlled terms: Atom transfer radical polymerization - Free radical polymerization - Nuclear magnetic resonance spectroscopy - Rare earth elements Uncontrolled terms: Different solvents - Isotactic-rich - Lewis Acid - Methacrylamides - Optical activity - Optically Active - Oxazolines - Rare earth metals Classification code: 547.2 Rare Earth Metals - 815.1 Polymeric Materials - 815.2 Polymerization - 932.2 Nuclear Physics DOI: 10.4028/www.scientific.net/AMM.477-478.1187 Database: Compendex Compilation and indexing terms, © 2013 Elsevier Inc. |
4Â¥2014-02-07 19:21:50
yuxinghai455
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2Â¥2014-02-07 14:05:16
glenda007982
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3Â¥2014-02-07 14:16:52
glenda007982
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5Â¥2014-02-07 20:54:35













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