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Polymerization and chiroptical behavior of N-[o-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl) phenyl] methacrylamide
AMM(2014) 477-478¾ípp 1187-1191
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Accession number:       
20140417220564
        Title:        Polymerization and chiroptical behavior of N-[o-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl) phenyl] methacrylamide
        Authors:         Fu, Zheng1 Email author fz19820528@163.com; Wei, Hong1 Email author bailing8861@sina.com; Ding, Yang2 Email author sunnyland@163.com; Yuan, Chao1 Email author yuanchao3723@163.com
        Author affiliation:        1 Department of Pharmacy, Shandong Medical College, Jinan 250002, China
                2 Dean's Office, Shandong Medical College, Jinan 250002, China
        Corresponding author:         Yuan, C. (yuanchao3723@163.com)
        Source title:        Applied Mechanics and Materials
        Abbreviated source title:        Appl. Mech. Mater.
        Volume:        477-478
        Monograph title:        Applied Mechanics and Materials II
        Issue date:        2014
        Publication year:        2014
        Pages:        1187-1191
        Language:        English
        ISSN:         16609336
        E-ISSN:         16627482
        ISBN-13:         9783037859841
        Document type:        Conference article (CA)
        Conference name:        2013 2nd International Conference on Applied Mechanics and Materials, ICAMM 2013
        Conference date:        November 23, 2013 - November 24, 2013
        Conference location:        Zhuhai, China
        Conference code:         101957
        Publisher:        Trans Tech Publications Ltd, Kreuzstrasse 10, Zurich-Durnten, CH-8635, Switzerland
        Abstract:        The radical polymerization of optically active methacrylamide derivative, N- [o-(4-isopropyl-4,5-dihydro -1,3-oxazol-2-yl)phenyl] methacrylamide ((S)-MeOPMAM), was carried out under various conditions. The effect of Lewis acid, that is, rare earth metal trifluoromethanesulfonates on the free-radical polymerization were examined under different solvents. The polymerization in the presence of rare earth metal trifluoromethanesulfonates produced isotactic-rich polymers compared with those obtained without the Lewis acid. The polymerization characteristics and the chiroptical behavior of the resultant polymers have been examined by using circular dichroism (CD), UV-Vis, and NMR spectroscopies. © (2014) Trans Tech Publications, Switzerland.
        Number of references:        16
        Main heading:         Polymers
        Controlled terms:         Atom transfer radical polymerization  -  Free radical polymerization  -  Nuclear magnetic resonance spectroscopy  -  Rare earth elements
        Uncontrolled terms:         Different solvents  -  Isotactic-rich  -  Lewis Acid  -  Methacrylamides  -  Optical activity  -  Optically Active  -  Oxazolines  -  Rare earth metals
        Classification code:         547.2 Rare Earth Metals -  815.1 Polymeric Materials -  815.2 Polymerization -  932.2 Nuclear Physics
        DOI:        10.4028/www.scientific.net/AMM.477-478.1187
        Database:        Compendex
                Compilation and indexing terms, © 2013 Elsevier Inc.
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