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[资源] Angew. Chem.综述：混合过渡金属氧化物-设计、合成和能源相关领域的应用

最新一期的德国应用化学（Angewandte Chemie International Edition）刊发了由新加坡南洋理工大学楼雄文教授课题组与中国科技大学谢毅教授合作的综述文章，介绍了混合过渡金属氧化物这一类新型能源存储材料的设计与合成方面的现状，并着重介绍了其在能源相关领域的应用，包括电催化、锂离子电池、超级电容器等领域。文章17页，引文128篇。
A promising family of mixed transition-metal oxides (MTMOs) (designated as AxB3-xO4; A, B=Co, Ni, Zn, Mn, Fe, etc.) with stoichiometric or even non-stoichiometric compositions, typically in a spinel structure, has recently attracted increasing research interest worldwide. Benefiting from their remarkable electrochemical properties, these MTMOs will play significant roles for low-cost and environmentally friendly energy storage/conversion technologies. In this Review, we summarize recent research advances in the rational design and efficient synthesis of MTMOs with controlled shapes, sizes, compositions, and micro-/nanostructures, along with their applications as electrode materials for lithium-ion batteries and electrochemical capacitors, and efficient electrocatalysts for the oxygen reduction reaction in metal–air batteries and fuel cells. Some future trends and prospects to further develop advanced MTMOs for next-generation electrochemical energy storage/conversion systems are also presented.
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2014-01-02 23:23:37, 4.26 M