±±¾©Ê¯ÓÍ»¯¹¤Ñ§Ôº2026ÄêÑо¿ÉúÕÐÉú½ÓÊÕµ÷¼Á¹«¸æ
²é¿´: 11129  |  »Ø¸´: 322
¡¾½±Àø¡¿ ±¾Ìû±»ÆÀ¼Û254´Î£¬×÷ÕßxiejfÔö¼Ó½ð±Ò 200.6 ¸ö
±¾Ìû²úÉú 1 ¸ö MN-EPI £¬µã»÷ÕâÀï½øÐв鿴

[×ÊÔ´] ÏÃÃÅ´óѧAcc. Chem. Res.×îÐÂ×ÛÊö£º¾ßÓиßÄܾ§ÃæµÄ½ðÊôÑõ»¯Îï΢Äɾ§Ìå¼°ÆäÓ¦ÓÃ

×îÐÂÒ»ÆÚµÄAcc. Chem. Res.ÔÓÖ¾¿¯·¢ÁËÓÉÏÃÃÅ´óѧлÕ×ÐÛ½ÌÊÚ¿ÎÌâ×éÓëÖ£À¼Ý¥ÔºÊ¿×«Ð´µÄÌâΪHigh-Energy-Surface Engineered Metal Oxide Micro- and Nanocrystallites and Their ApplicationsµÄÑо¿ÐÔ×ÛÊö£¬½éÉÜÁ˾ßÓиßÄܾ§ÃæµÄ½ðÊôÑõ»¯Îï΢Äɾ§Ìå¼°ÆäÓ¦ÓÃÕâÒ»ÁìÓòµÄ×îнøÕ¹¡£ÎÄÕÂ11Ò³£¬ÒýÎÄ53ƪ¡£
Because many physical and chemical processes occur at surfaces, surface atomic structure is a critical factor affecting the properties of materials. Due to the presence of high-density atomic steps and edges and abundant unsaturated coordination sites, micro- and nanocrystallites with high-energy surfaces usually exhibit greater reactivity than those with low-energy surfaces. However, high-energy crystal surfaces are usually lost during crystal growth as the total surface energy is minimized. Therefore, the selective exposure of high-energy facets at the surface of micro- and nanocrystallites is an important and challenging research topic. Metal oxides play important roles in surface-associated applications, including catalysis, gas sensing, luminescence, and antibiosis. The synthesis of metal oxide micro- and nanocrystallites with specific surfaces, particularly those with high surface energies, is more challenging than the synthesis of metal crystals due to the presence of strong metal¨Coxygen bonds and diverse crystal structures.

In this Account, we briefly summarize recent progress in the surface-structure-controlled synthesis of several typical metal oxide micro- and nanocrystallites, including wurtzite ZnO, anatase TiO2, rutile SnO2, and rocksalt-type metal oxides. We also discuss the improvement of surface properties, focusing on high-energy surfaces. Because of the huge quantity and diverse structure of metal oxides, this Account is not intended to be comprehensive. Instead, we discuss salient features of metal oxide micro- and nanocrystallites using examples primarily from our group.

We first discuss general strategies for tuning the surface structure of metal oxide micro- and nanocrystallites, presenting several typical examples. For each example, we describe the basic crystallographic characteristics as well as the thermodynamic (i.e., tuning surface energy) or kinetic (i.e., tuning reaction rates) strategies we have used to synthesize micro- and nanocrystallites with high surface energies. We discuss the structural features of the specific facets and analyze the basis for the enhanced performance of the metal oxide micro- and nanocrystallites in water splitting, the degradation of organic pollutants, gas sensing, catalysis, luminescence, and antibiosis. Finally, we note the future trends in high-energy-facet metal oxide micro- and nanocrystallite research. A comprehensive understanding of the properties of metal oxide micro- and nanocrystallites with high-energy crystal surfaces and related synthetic strategies will facilitate the rational design of functional nanomaterials with desired characteristics.
/ÏÃÃÅ´óѧAcc. Chem. Res.×îÐÂ×ÛÊö£º¾ßÓиßÄܾ§ÃæµÄ½ðÊôÑõ»¯Îï΢Äɾ§Ìå¼°ÆäÓ¦ÓÃ
ar-2013-00092x_0008.gif
»Ø¸´´ËÂ¥

» ±¾Ìû¸½¼þ×ÊÔ´Áбí

» ÊÕ¼±¾ÌûµÄÌÔÌûר¼­ÍƼö

﮵ç×ÊÔ´¹²Ïí ÄÉÃ×¼¼ÊõÓëÄÜÔ´¼°Ä£Äâ Nano&Micro ÄÉÃ×»úÀí
ÎÄÏ×ÍÆ¼ö ÄÉÃ×»¯Ñ§/µç»¯Ñ§×ÛÊö µç»¯Ñ§µçÔ´¡¢µçÔ´¹ÜÀí ¹â´ß»¯×¨¼­
ÎÒÒªµ±Ñ§ÊõµÛ ÎÞ»úÄÉÃײÄÁÏ reviews paper ¿Æ¼¼
uicorn3 ¹â·ü&¹â´ß»¯ ´ß»¯&²ÄÁÏ Ç°ÑØ¼¼Êõ
²ÄÁÏÀàÎÄÏ×Èȵ㠿ÆÑа¡ ŬÁ¦°¡ Ï£ÍûÓÐÓð¡ ²ÄÁϵÄ×é³É¡¢½á¹¹ÓëÆä¹â´ß»¯ÐÔÄܵĹØÏµ ½ðÊôÑõ»¯Îï-wy
ÄÉÃײÄÁϼ°Ó¦Óà ×ÛÊöר¼­ TiO2 ÄÉÃײÄÁÏ
ÔÂÑÀ¶ùµÄ°Ù±¦Ïä ÏȽø²ÄÁÏÓëÖÆ±¸ ʯīϩ zdµÄÊÕ²Ø
·ÂÉúºÏ³É ×ÊÔ´×ÊÁÏ Ñõ»¯Îï½çÃæÓë±íÃæ

» ±¾ÌûÒÑ»ñµÃµÄºì»¨£¨×îÐÂ10¶ä£©

» ²ÂÄãϲ»¶

» ±¾Ö÷ÌâÏà¹Ø¼ÛÖµÌùÍÆ¼ö£¬¶ÔÄúͬÑùÓаïÖú:

ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

Çó²´¾ý

ľ³æ (СÓÐÃûÆø)


¡ï¡ï¡ï¡ï¡ï ÎåÐǼ¶,ÓÅÐãÍÆ¼ö

¸ÐлÎÞ˽·ÖÏí£¡Ö§³Ö£¡
9Â¥2013-12-21 15:42:01
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

ţСÎÊ

½ð³æ (ÖøÃûдÊÖ)


¡ï¡ï¡ï¡ï¡ï ÎåÐǼ¶,ÓÅÐãÍÆ¼ö

ʦÐÖNB
14Â¥2013-12-21 17:39:11
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû

xinniyun

½ð³æ (СÓÐÃûÆø)


¡ï¡ï¡ï¡ï¡ï ÎåÐǼ¶,ÓÅÐãÍÆ¼ö

§Ý§Ý
21Â¥2013-12-21 19:44:08
ÒÑÔÄ   »Ø¸´´ËÂ¥   ¹Ø×¢TA ¸øTA·¢ÏûÏ¢ ËÍTAºì»¨ TAµÄ»ØÌû
¼òµ¥»Ø¸´
ptia2Â¥
2013-12-21 13:02   »Ø¸´  
ÎåÐÇºÃÆÀ  
w_wwb3Â¥
2013-12-21 13:33   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
jtkdpangzi4Â¥
2013-12-21 13:34   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
xzb3285Â¥
2013-12-21 13:53   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
2013-12-21 13:59   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
2013-12-21 14:07   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
huwei028Â¥
2013-12-21 14:40   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
41439931510Â¥
2013-12-21 15:58   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
jjseu11Â¥
2013-12-21 16:29   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
Solar_WB12Â¥
2013-12-21 17:08   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
yuedanhappy13Â¥
2013-12-21 17:10   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
c530269415Â¥
2013-12-21 17:56   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
yf.li16Â¥
2013-12-21 18:13   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
wkkkk17Â¥
2013-12-21 18:37   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
hewangcsu18Â¥
2013-12-21 18:56   »Ø¸´  
ÈýÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
glassman78219Â¥
2013-12-21 19:13   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
junyduan20Â¥
2013-12-21 19:29   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
arisun881822Â¥
2013-12-21 19:52   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
jlxi23Â¥
2013-12-21 20:02   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
dailun2024Â¥
2013-12-21 20:08   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
gtr200825Â¥
2013-12-21 20:48   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
2013-12-21 20:51   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
nickvo27Â¥
2013-12-21 20:55   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
gerrard128Â¥
2013-12-21 21:40   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
zxh7729Â¥
2013-12-21 21:58   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
ziki30Â¥
2013-12-21 22:40   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
hncu12345631Â¥
2013-12-21 23:19   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
King_Of_WS32Â¥
2013-12-21 23:27   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
hxsj33Â¥
2013-12-21 23:31   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
baozihit34Â¥
2013-12-21 23:34   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
cqu355535Â¥
2013-12-21 23:40   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
tianyiking36Â¥
2013-12-22 09:29   »Ø¸´  
ÈýÐÇºÃÆÀ  
zhanglexi37Â¥
2013-12-22 10:35   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
csheung38Â¥
2013-12-22 11:21   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
gengxin6039Â¥
2013-12-22 11:28   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
firechen98740Â¥
2013-12-22 11:38   »Ø¸´  
ÎåÐÇºÃÆÀ  
qiushouji41Â¥
2013-12-22 12:03   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
icleu42Â¥
2013-12-22 12:25   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
muxinjin43Â¥
2013-12-22 12:25   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
zjys588744Â¥
2013-12-22 12:53   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
gaofenglnnu45Â¥
2013-12-22 13:03   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
swallowqiu46Â¥
2013-12-22 13:03   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
2013-12-22 13:32   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
fmbs11048Â¥
2013-12-22 13:41   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
dragonjust49Â¥
2013-12-22 14:28   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
gaochunping50Â¥
2013-12-22 14:45   »Ø¸´  
ÎåÐÇºÃÆÀ  ¶¥Ò»Ï£¬¸Ðл·ÖÏí£¡
Ïà¹Ø°æ¿éÌø×ª ÎÒÒª¶©ÔÄÂ¥Ö÷ xiejf µÄÖ÷Ìâ¸üÐÂ
×î¾ßÈËÆøÈÈÌûÍÆ¼ö [²é¿´È«²¿] ×÷Õß »Ø/¿´ ×îºó·¢±í
[¿¼ÑÐ] 275Çóµ÷¼Á +10 Micky11223 2026-03-25 14/700 2026-03-28 15:48 by Micky11223
[¿¼ÑÐ] 317Çóµ÷¼Á +6 Ê®ÏÐwx 2026-03-24 6/300 2026-03-28 13:27 by Iveryant
[¿¼ÑÐ] 311Çóµ÷¼Á +9 lin0039 2026-03-26 9/450 2026-03-28 13:05 by ÌÆãå¶ù
[¿¼ÑÐ] Ò»Ö¾Ô¸ÄϾ©º½¿Õº½Ìì´óѧ²ÄÁÏѧ˶Çóµ÷¼Á +3 @taotao 2026-03-28 3/150 2026-03-28 10:26 by JourneyLucky
[¿¼ÑÐ] 331»·¾³¿ÆÑ§Ó빤³ÌÇóµ÷¼Á +3 ìÚÈ»ºÃÔËÆø 2026-03-27 3/150 2026-03-28 04:11 by fmesaito
[¿¼ÑÐ] 08¿ªÍ·275Çóµ÷¼Á +4 À­Ë­²»ÖØÒª 2026-03-26 4/200 2026-03-27 14:12 by Delta2012
[ÂÛÎÄͶ¸å] Journal of Mechanical Science and Technology +3 Russ_ss 2026-03-25 5/250 2026-03-27 10:49 by ½С¹û»­´ó±ý
[¿¼ÑÐ] 317Çóµ÷¼Á +7 µ°»ÆÏÌÈâôÕ 2026-03-26 7/350 2026-03-27 02:29 by fmesaito
[¿¼ÑÐ] 336²ÄÁÏÇóµ÷¼Á +7 ³ÂäÞÓ¨ 2026-03-26 9/450 2026-03-27 00:20 by wxiongid
[¿¼ÑÐ] Çóµ÷¼Á Ò»Ö¾Ô¸ ±¾¿Æ ±±¿Æ´ó »¯Ñ§ 343 +6 13831862839 2026-03-24 7/350 2026-03-26 22:57 by ²»³Ôô~µÄ؈
[¿¼ÑÐ] Ò»Ö¾Ô¸±±»¯Çóµ÷¼Á +3 Jsman 2026-03-22 3/150 2026-03-26 21:06 by ajpv·çÀ×
[¿¼ÑÐ] ²ÄÁϵ÷¼Á 5+4 ÏëÒªÒ»ºøÌÒ»¨Ë® 2026-03-25 10/500 2026-03-26 19:56 by ²»³Ôô~µÄ؈
[¿¼ÑÐ] 291 Çóµ÷¼Á +7 »¯¹¤2026½ì±ÏÒµÉ 2026-03-21 8/400 2026-03-26 11:25 by AlenQIN.
[¿¼ÑÐ] »¯Ñ§µ÷¼ÁÒ»Ö¾Ô¸ÉϺ£½»Í¨´óѧ336·Ö-±¾¿ÆÉϺ£211 +4 СÓã°®Óлú 2026-03-25 4/200 2026-03-26 10:19 by aa331100
[¿¼ÑÐ] ¿¼Ñе÷¼Á +6 À´ºÃÔËÀ´À´À´ 2026-03-21 7/350 2026-03-25 22:43 by 418490947
[¿¼ÑÐ] ¡¾2026¿¼Ñе÷¼Á¡¿ÖÆÒ©¹¤³Ì 284·Ö ÇóÏà¹Ø×¨Òµµ÷¼ÁÃû¶î +4 Ô¬Û¼Û¼ 2026-03-25 8/400 2026-03-25 14:32 by lbsjt
[¿¼ÑÐ] Ò»Ö¾Ô¸±±»¯315 Çóµ÷¼Á +3 akrrain 2026-03-24 3/150 2026-03-24 19:35 by ÁËÁËÁËÁË¡£¡£
[¿¼ÑÐ] 384Çóµ÷¼Á +3 ×Óϵ²© 2026-03-22 6/300 2026-03-23 21:45 by ×Óϵ²©
[¿¼ÑÐ] 269Çóµ÷¼Á +4 ÎÒÏë¶ÁÑÐ11 2026-03-23 4/200 2026-03-23 21:25 by pswait
[¿¼ÑÐ] 070300£¬Ò»Ö¾Ô¸±±º½320Çóµ÷¼Á +3 Jerry0216 2026-03-22 5/250 2026-03-23 09:16 by ¡£¡£ÌÃÌÃ
ÐÅÏ¢Ìáʾ
ÇëÌî´¦ÀíÒâ¼û