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Non-ionic surfactant and surfactant in aqueous solution in the form mixed micelles, non-ionic surfactant molecules into ionic surfactant sub-surface activity between ion, making the original ionic surfactant ion between the first Xinhua rejection of the weakened role, which micelle surface charge density reduction, coupled with two surfactant molecules of carbon chain between the hydrophobic interaction, making two surfactant between the strong interaction of the net , in the mixed solution was relatively easy to form cross-linked with large mesh solution skeleton structure. In addition, as anionic surfactant-base with a large number of negative charge can be produced with metal cation strong electrostatic attractive role for the complex structure of nanoparticles synthesis induced by providing skeleton.
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[ Last edited by cooboo on 2008-1-1 at 10:39 ]
2Â¥2008-01-01 10:16:22
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Hybrid gel clusters of non-ionic surfactant were formed in the aqeuous solution and the molecues of non-ionic surface active agents were inserted into sub-surface active ions of the ionic surfactant, which weakened the electric repulsion between ion head of the original ionic surfactant and consequently reduced the surface charge density of the gel clusters. Meanwhile there was dewatering interaction between carbon chains of the molecues of the two kinds of surfactants and combination of these effects resulted in strong net interaction between the two kinds of surfactants. A great deal of reticulated solution skeletal structures that were formed in solution.

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Additionally strong electrostatic attraction formed between the metallic cations and the anionics with a large number of negative charges on the terminal groups, which provided the synthesis of some nano-particles of complex structures with inducting skeleton.
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