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yuhaiqian铜虫 (小有名气)
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[求助]
求助三个微谱查询 已有1人参与
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Hsb-13 13C NMR (126 MHz,CDCl3) δ 16.37,23.59,24.41,25.73,29.83,30.77,34.51,35.36,40.21,40.73,46.53,66.79,68.88,75.11 Hsb-14 13C NMR (126 MHz,CDCl3) δ 20.65,29.83,55.45,56.41,56.56,97.08,106.01,108.95,117.18,127.6,136.68,138.57,156.86,157.53,157.77 Hsb-15 13C NMR (126 MHz,CDCl3) δ 13.71,14.15,18.51,18.64,19.1,20.51,22.72,29.21,29.38,29.72,30.6,31.8,31.95,44.3,47.47,55.39,56.31,56.44,64.69,76.78,77.04,77.29,96.97,106.48,108.31,114.87,116.11,116.51,117.82,120.29,128.21,131.84,136.67,136.88,153.67,156.6,157.29,157.6 |
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lifeliuyan
至尊木虫 (职业作家)
- PhEPI: 1
- 应助: 3913 (副教授)
- 金币: 48805.6
- 散金: 890
- 红花: 208
- 帖子: 4735
- 在线: 635.4小时
- 虫号: 1141109
- 注册: 2010-11-07
- 性别: MM
- 专业: 中药药效物质
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★
yuhaiqian: 金币+10, ★★★★★最佳答案 2013-12-16 14:32:21
yuhaiqian: 金币+10, ★★★★★最佳答案 2013-12-16 14:32:21
|
查询结果：共查到657个化合物(查询结果仅供参考) -------------------------------------------------------------------------------- 1 . dendrantheinoside A aglycone C13H24O3 相似度:71.4% Planta Medica 1992 58 373-375 Structural Elucidation of endranthemosides A and B:Two New f3-Ionone Glucosides from Dendranthema shiwogiku Hideaki Otsuka, Yasuyuki Takeda,Kazuo Yamasaki, and Yoshio Takeda Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 2 . aglucone of dendranthemoside A 相似度:71.4% Phytochemistry 1994 35 1331-1334 Alangionosides A and B, ionol glycosides from leaves of Alangium premnifolium Hideaki Otsuka, Kenji Kamada, Choei Ogimi, Eiji Hirata, Anki Takushi, Yoshio Takeda Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 3 . 3S,5R,6S,9R)-3,6-dihydro-5,6-dihydro-β-ionol 相似度:71.4% Natural Product Research and Development 2001 13(4) 5-7 STUDY ON THE CHEMICAL CONSTITUENTS OF MEZZETTIOPSIS CREAGHII RIDL. CHEN Bin; YANG Juan; LI Bo gang; ZHANG Guo lin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 4 . Aglycone of crotonionoside C C13H24O3 相似度:71.4% Phytochemistry 2011 72 147-153 Crotonionosides A–G: Megastigmane glycosides from leaves of Croton cascarilloides Räuschel Susumu Kawakami, Katsuyoshi Matsunami, Hideaki Otsuka, Takakazu Shinzato, Yoshio Takeda Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 5 . (1S,4S,6S)-1-(3-Hydroxy-but-1E-enyl)-2,2,6-trimethyl-cyclohexane-1,4-diol or (3S,5S,6S,9R)-3,6-Dihydroxy-5,6-dihydro-b-ionol 相似度:71.4% Journal of the Brazilian Chemical Society 2009 20 1921-1924 Megastimanes and Ergostane Type Steroid from Leaves Cratylia mollis (Leguminosae) Luciano S. Lima, Marcos V. B. Lima, Juceni P. David, Ana M. Giulietti, Luciano P. de Queiroz and Jorge M. David Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 6 . 9β-bromo-4,8,11,11-tetramethylbicyclo[6.3.0]undecen-4-ene C15H25Br 相似度:66.6% Journal of Natural Products 1994 Vol 57 738 Inhibition of Botrytis cinerea by New Sesquiterpenoid Compounds Obtained from the Rearrangement of Isocaryophyllene Isidro G. Collado, Josefina Aleu, Antonio J. Macías-Sánchez, Rosario Hernández-Galán Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 7 . (8S,9R)-isocaryolan-9-ol 相似度:66.6% Journal of Natural Products 2013 76 1016-1024 Phytotoxic Activity and Metabolism of Botrytis cinerea and Structure–Activity Relationships of Isocaryolane Derivatives Jociani Ascari, Maria Amélia Diamantino Boaventura, Jacqueline Aparecida Takahashi, Rosa Durán-Patrón, Rosario Hernández-Galán, Antonio J. Macías-Sánchez, and Isidro G. Collado Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 8 . 9-bromo-3,3,7-trimethyltricyclo[5.4.0.02,9]undecan-8-one C14H21OBr 相似度:64.2% Journal of Natural Products 2003 66 520-523 An Efficient Formal Synthesis of the Sesquiterpenoid Longifolene Sasan Karimi, and Paula Tavares Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 9 . (3S,5R,6S,9R)-3,6-dihydroxy-5,6-dihydro-β-ionol C13H2403 相似度:64.2% Journal of Natural Products 1996 59 69-72 Absolute Structures of Two New C13-Norisoprenoids from Apollonias barbujana Cirilo Perez and Juan Trujillo Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 10 . 3-(1',6'-Epoxy-2',2',6'-trimethyl-cyclohexyl)propionsaremethylester C13H22O3 相似度:64.2% Helvetica Chimica Acta 1980 63 1833-1855 Photochemische Reaktionen 111. Mitteilung [1] Zur Photochemie , -ungesättigter , -Epoxyester I: Singulett- versus Triplettreaktivität Alex Peter Alder, Hans Richard Wolf, Oskar Jeger Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 11 . 9-epi-Kobusone C14H22O2 相似度:64.2% Phytochemistry 1994 35 1489-1494 Confirmation of structure and absolute stereochemistry of 9-epi-β-caryophyllene from Dacrydium cupressinum Simon F.R. Hinkley, Nigel B. Perry, Rex T. Weavers Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 12 . 7-megastigmene-3,6,9-triol 相似度:64.2% Natural Product Research and Development 2002 14(5) 26-28 FLAVONOIDS FROM KNEMA GLOBULARIA MEI Wen li; NI Wei; HUA Yan; CHEN Chang xiang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 13 . (1S,2R)-2-chlorocyclopropanecarboxylic acid (1S,2R,5S)-5-isopropyl-2-methylcyclohexyl ester C14H23O2Cl 相似度:64.2% Journal of the American Chemical Society 2002 124 10396-10415 Callipeltoside A: Total Synthesis, Assignment of the Absolute and Relative Configuration, and Evaluation of Synthetic Analogues Barry M. Trost, Janet L. Gunzner, Olivier Dirat, and Young H. Rhee Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 14 . Dihydroedulan C13H22O 相似度:64.2% European Journal of Organic Chemistry 1989 1989 1195-1201 Epoxytetrahydroedulan, a New Terpenoid from the Hairpencils of Euploea (Lep.: Danainae) Butterflies Wittko Francke, Stefan Schulz, Volker Sinnwell, Wilfried A. König and Yves Roisin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 15 . (1S,2S)-Di-(-)-menthyl Cyclohex-4-ene-1,2-dicarboxylate 相似度:64.2% Journal of Medicinal Chemistry 1989 32 197-202 Synthesis and biological evaluation of a monocyclic, fully functional analog of compactin Clayton H. Heathcock, Brian R. Davis, Cheri R. Hadley Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 16 . Wilsonol E (3S,4S,5S,6S,9R) C13H26O3 相似度:64.2% Journal of Natural Products 2013 76 1303-1312 Wilsonols A–L, Megastigmane Sesquiterpenoids from the Leaves of Cinnamomum wilsonii Penghua Shu, Xialan Wei, Yongbo Xue, Weijie Li, Jinwen Zhang, Ming Xiang, Mengke Zhang, Zengwei Luo, Yan Li, Guangmin Yao, and Yonghui Zhang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 17 . Wilsonol F C13H26O3 相似度:64.2% Journal of Natural Products 2013 76 1303-1312 Wilsonols A–L, Megastigmane Sesquiterpenoids from the Leaves of Cinnamomum wilsonii Penghua Shu, Xialan Wei, Yongbo Xue, Weijie Li, Jinwen Zhang, Ming Xiang, Mengke Zhang, Zengwei Luo, Yan Li, Guangmin Yao, and Yonghui Zhang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 18 . 1,10-Epoxylepidozenol 相似度:64.2% The Journal of Organic Chemistry 1990 55 3677-3679 Cytotoxic hydroperoxylepidozenes from the actinia Anthopleura pacifica Uchida Guo Chi Zheng, Akio Ichikawa, Midori O. Ishitsuka, Takenori Kusumi, Hiroshi Yamamoto, Hiroshi Kakisawa Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 19 . isothiocyanate 相似度:62.5% Experientia 1986 42 625-627 Minor nitrogenous sesquiterpenes from the marine spongeAxinella cannabina. A hypothesis for the biogenesis of the spiro-axane skeleton P. Ciminiello, E. Fattorusso, S. Magno and L. Mayol Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 20 . compound 8 相似度:62.5% Australian Journal of Chemistry 1988 41 979-983 New Isothiocyanate Sesquiterpenes From the Australian Marine Sponge Acanthella pulcherrima RJ Capon and JK Macleod Structure 13C NMR 碳谱模拟图 |
3楼2013-12-16 11:44:59
lifeliuyan
至尊木虫 (职业作家)
- PhEPI: 1
- 应助: 3913 (副教授)
- 金币: 48805.6
- 散金: 890
- 红花: 208
- 帖子: 4735
- 在线: 635.4小时
- 虫号: 1141109
- 注册: 2010-11-07
- 性别: MM
- 专业: 中药药效物质
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
yuhaiqian: 金币+10, ★★★★★最佳答案, 非常感谢，第一次用这个，谢谢提醒 2013-12-16 14:32:49
感谢参与，应助指数 +1
yuhaiqian: 金币+10, ★★★★★最佳答案, 非常感谢，第一次用这个，谢谢提醒 2013-12-16 14:32:49
|
查询结果：共查到657个化合物(查询结果仅供参考) -------------------------------------------------------------------------------- 1 . dendrantheinoside A aglycone C13H24O3 相似度:71.4% Planta Medica 1992 58 373-375 Structural Elucidation of endranthemosides A and B:Two New f3-Ionone Glucosides from Dendranthema shiwogiku Hideaki Otsuka, Yasuyuki Takeda,Kazuo Yamasaki, and Yoshio Takeda Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 2 . aglucone of dendranthemoside A 相似度:71.4% Phytochemistry 1994 35 1331-1334 Alangionosides A and B, ionol glycosides from leaves of Alangium premnifolium Hideaki Otsuka, Kenji Kamada, Choei Ogimi, Eiji Hirata, Anki Takushi, Yoshio Takeda Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 3 . 3S,5R,6S,9R)-3,6-dihydro-5,6-dihydro-β-ionol 相似度:71.4% Natural Product Research and Development 2001 13(4) 5-7 STUDY ON THE CHEMICAL CONSTITUENTS OF MEZZETTIOPSIS CREAGHII RIDL. CHEN Bin; YANG Juan; LI Bo gang; ZHANG Guo lin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 4 . Aglycone of crotonionoside C C13H24O3 相似度:71.4% Phytochemistry 2011 72 147-153 Crotonionosides A–G: Megastigmane glycosides from leaves of Croton cascarilloides Räuschel Susumu Kawakami, Katsuyoshi Matsunami, Hideaki Otsuka, Takakazu Shinzato, Yoshio Takeda Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 5 . (1S,4S,6S)-1-(3-Hydroxy-but-1E-enyl)-2,2,6-trimethyl-cyclohexane-1,4-diol or (3S,5S,6S,9R)-3,6-Dihydroxy-5,6-dihydro-b-ionol 相似度:71.4% Journal of the Brazilian Chemical Society 2009 20 1921-1924 Megastimanes and Ergostane Type Steroid from Leaves Cratylia mollis (Leguminosae) Luciano S. Lima, Marcos V. B. Lima, Juceni P. David, Ana M. Giulietti, Luciano P. de Queiroz and Jorge M. David Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 6 . 9β-bromo-4,8,11,11-tetramethylbicyclo[6.3.0]undecen-4-ene C15H25Br 相似度:66.6% Journal of Natural Products 1994 Vol 57 738 Inhibition of Botrytis cinerea by New Sesquiterpenoid Compounds Obtained from the Rearrangement of Isocaryophyllene Isidro G. Collado, Josefina Aleu, Antonio J. Macías-Sánchez, Rosario Hernández-Galán Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 7 . (8S,9R)-isocaryolan-9-ol 相似度:66.6% Journal of Natural Products 2013 76 1016-1024 Phytotoxic Activity and Metabolism of Botrytis cinerea and Structure–Activity Relationships of Isocaryolane Derivatives Jociani Ascari, Maria Amélia Diamantino Boaventura, Jacqueline Aparecida Takahashi, Rosa Durán-Patrón, Rosario Hernández-Galán, Antonio J. Macías-Sánchez, and Isidro G. Collado Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 8 . 9-bromo-3,3,7-trimethyltricyclo[5.4.0.02,9]undecan-8-one C14H21OBr 相似度:64.2% Journal of Natural Products 2003 66 520-523 An Efficient Formal Synthesis of the Sesquiterpenoid Longifolene Sasan Karimi, and Paula Tavares Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 9 . (3S,5R,6S,9R)-3,6-dihydroxy-5,6-dihydro-β-ionol C13H2403 相似度:64.2% Journal of Natural Products 1996 59 69-72 Absolute Structures of Two New C13-Norisoprenoids from Apollonias barbujana Cirilo Perez and Juan Trujillo Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 10 . 3-(1',6'-Epoxy-2',2',6'-trimethyl-cyclohexyl)propionsaremethylester C13H22O3 相似度:64.2% Helvetica Chimica Acta 1980 63 1833-1855 Photochemische Reaktionen 111. Mitteilung [1] Zur Photochemie , -ungesättigter , -Epoxyester I: Singulett- versus Triplettreaktivität Alex Peter Alder, Hans Richard Wolf, Oskar Jeger Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 11 . 9-epi-Kobusone C14H22O2 相似度:64.2% Phytochemistry 1994 35 1489-1494 Confirmation of structure and absolute stereochemistry of 9-epi-β-caryophyllene from Dacrydium cupressinum Simon F.R. Hinkley, Nigel B. Perry, Rex T. Weavers Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 12 . 7-megastigmene-3,6,9-triol 相似度:64.2% Natural Product Research and Development 2002 14(5) 26-28 FLAVONOIDS FROM KNEMA GLOBULARIA MEI Wen li; NI Wei; HUA Yan; CHEN Chang xiang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 13 . (1S,2R)-2-chlorocyclopropanecarboxylic acid (1S,2R,5S)-5-isopropyl-2-methylcyclohexyl ester C14H23O2Cl 相似度:64.2% Journal of the American Chemical Society 2002 124 10396-10415 Callipeltoside A: Total Synthesis, Assignment of the Absolute and Relative Configuration, and Evaluation of Synthetic Analogues Barry M. Trost, Janet L. Gunzner, Olivier Dirat, and Young H. Rhee Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 14 . Dihydroedulan C13H22O 相似度:64.2% European Journal of Organic Chemistry 1989 1989 1195-1201 Epoxytetrahydroedulan, a New Terpenoid from the Hairpencils of Euploea (Lep.: Danainae) Butterflies Wittko Francke, Stefan Schulz, Volker Sinnwell, Wilfried A. König and Yves Roisin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 15 . (1S,2S)-Di-(-)-menthyl Cyclohex-4-ene-1,2-dicarboxylate 相似度:64.2% Journal of Medicinal Chemistry 1989 32 197-202 Synthesis and biological evaluation of a monocyclic, fully functional analog of compactin Clayton H. Heathcock, Brian R. Davis, Cheri R. Hadley Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 16 . Wilsonol E (3S,4S,5S,6S,9R) C13H26O3 相似度:64.2% Journal of Natural Products 2013 76 1303-1312 Wilsonols A–L, Megastigmane Sesquiterpenoids from the Leaves of Cinnamomum wilsonii Penghua Shu, Xialan Wei, Yongbo Xue, Weijie Li, Jinwen Zhang, Ming Xiang, Mengke Zhang, Zengwei Luo, Yan Li, Guangmin Yao, and Yonghui Zhang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 17 . Wilsonol F C13H26O3 相似度:64.2% Journal of Natural Products 2013 76 1303-1312 Wilsonols A–L, Megastigmane Sesquiterpenoids from the Leaves of Cinnamomum wilsonii Penghua Shu, Xialan Wei, Yongbo Xue, Weijie Li, Jinwen Zhang, Ming Xiang, Mengke Zhang, Zengwei Luo, Yan Li, Guangmin Yao, and Yonghui Zhang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 18 . 1,10-Epoxylepidozenol 相似度:64.2% The Journal of Organic Chemistry 1990 55 3677-3679 Cytotoxic hydroperoxylepidozenes from the actinia Anthopleura pacifica Uchida Guo Chi Zheng, Akio Ichikawa, Midori O. Ishitsuka, Takenori Kusumi, Hiroshi Yamamoto, Hiroshi Kakisawa Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 19 . isothiocyanate 相似度:62.5% Experientia 1986 42 625-627 Minor nitrogenous sesquiterpenes from the marine spongeAxinella cannabina. A hypothesis for the biogenesis of the spiro-axane skeleton P. Ciminiello, E. Fattorusso, S. Magno and L. Mayol Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 20 . compound 8 相似度:62.5% Australian Journal of Chemistry 1988 41 979-983 New Isothiocyanate Sesquiterpenes From the Australian Marine Sponge Acanthella pulcherrima RJ Capon and JK Macleod Structure 13C NMR 碳谱模拟图 |
2楼2013-12-16 11:44:41
lifeliuyan
至尊木虫 (职业作家)
- PhEPI: 1
- 应助: 3913 (副教授)
- 金币: 48805.6
- 散金: 890
- 红花: 208
- 帖子: 4735
- 在线: 635.4小时
- 虫号: 1141109
- 注册: 2010-11-07
- 性别: MM
- 专业: 中药药效物质
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★
yuhaiqian: 金币+10, ★★★★★最佳答案 2013-12-16 14:32:14
yuhaiqian: 金币+10, ★★★★★最佳答案 2013-12-16 14:32:14
|
查询结果：共查到7个化合物(查询结果仅供参考) -------------------------------------------------------------------------------- 1 . Lyngbyastatin 8 C47H64N8O12 相似度:51.2% Marine drugs 2009 7 528-538 Lyngbyastatins 8–10,Elastase Inhibitors with Cyclic Depsipeptide Scaffolds Isolated from the Marine Cyanobacterium Lyngbya semiplena Jason C. Kwan,Kanchan Taori,Valerie J. Paul and Hendrik Luesch Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 2 . lyngbyastatin 5 C53H68N8O15 相似度:51.2% Journal of Natural Products 2007 70 1593-1600 Lyngbyastatins 5–7, Potent Elastase Inhibitors from Floridian Marine Cyanobacteria, Lyngbya spp. Kanchan Taori,Susan Matthew, James R. Rocca, Valerie J. Paul, and Hendrik Luesch Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 3 . cyanostatin A C38H57N5O9 相似度:50% Phytochemistry 2005 66 543-548 Leucine aminopeptidase M inhibitors, cyanostatin A and B,isolated from cyanobacterial water blooms in Scotland Tomoharu Sano, Hiroo Takagi, Louise F. Morrison, James S. Metcalf,Geoffrey A. Codd, Kunimitsu Kaya Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 4 . compound 21 C53H84N10O10 相似度:50% Tetrahedron Letters 2002 43 9405-9409 Total synthesis of (±)-martinelline Chengfeng Xia, Linshen Heng, Dawei Ma Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 5 . tetrahydropenitrem A C37H48ClNO6 相似度:50% Journal of the Chemical Society, Perkin Transactions 1 1983 1847-1856 Tremorgenic mycotoxins from Penicillium crustosum: isolation of penitrems A–F and the structure elucidation and absolute configuration of penitrem A Amelia E. de Jesus, Pieter S. Steyn, Fanie R. van Heerden, Robert Vleggaar, Philippus L. Wessels and William E. Hull Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 6 . compound 26 C36H43NO6 相似度:50% Bioorganic & Medicinal Chemistry 2010 18 6734-6741 Fluorescent schweinfurthin B and F analogs with anti-proliferative activity Joseph J. Topczewski, Craig H. Kuder, Jeffrey D. Neighbors, Raymond J. Hohl, David F. Wiemer Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 7 . compound 54 C36H48O4S 相似度:50% Bioorganic & Medicinal Chemistry 2011 19 7570-7581 Relevance of the C-5 position to schweinfurthin induced cytotoxicity Joseph J. Topczewski, Michael P. Callahan, John G. Kodet, Jery D. Inbarasu, Nolan R. Mente, John A. Beutler, David F. Wiemer Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- |
4楼2013-12-16 11:45:11
lifeliuyan
至尊木虫 (职业作家)
- PhEPI: 1
- 应助: 3913 (副教授)
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5楼2013-12-16 11:45:54
