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PSCs typically have ideality factors in the range 1.5¨C2 due to their inherent disorder, and departures from unity are attributed to various recombination mechanisms inside band-to-band transitions, that is, trapassisted and tail state recombination. |
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nacreous [ 'nekrɪəs ] a. ÕæÖéÖʵÄ, Óйâ²ÊµÄ [Ò½] ÕæÖéÉ«µÄ PSCs Web definitions Polar stratospheric clouds or PSCs, also known as // nacreous clouds/, are clouds in the winter polar stratosphere at altitudes of 15,000¨C25,000 meters. They are best observed during civil twilight when the sun is between 1 and 6 degrees below the horizon. ... https://en.wikipedia.org/wiki/PSCs # stratospheric strat.o.spher.ic adj.£¨ÐÎÈÝ´Ê£© 1. Of, relating to, or characteristic of the stratosphere. ƽÁ÷²ãµÄ£ºÊôÓÚ¡¢¹ØÓÚÆ½Á÷²ãµÄ»ò¾ßÓÐÆ½Á÷²ãµÄµäÐÍÌØÕ÷µÄ 2. Extremely or unreasonably high: ¼«¸ßµÄ£º¼«¸ßµÄ»ò¸ßµÃ²»ºÏÇéÀíµÄ£º ¡°money borrowed at today's stratospheric rates of interest¡±(&b{New York Times}) ¡°ÔÚ½ñÌ켫¸ßÀûÏ¢ÂʵÄʱ´ú½èµÄÇ®¡±(ŦԼʱ±¨) # unity ¡¶Ô´×ÔÀ¶¡ÎÄ¡°1¡±µÄÒâ˼¡· # stratosphere 1. The region of the atmosphere above the troposphere and below the mesosphere. ƽÁ÷²ã£ºÎ»ÓÚ¶ÔÁ÷²ãÖ®ÉÏÖж¥²ã֮ϵķ¶Î§µÄ´óÆø 2. An extremely high or the highest point or degree on a ranked scale: ¸ß²ã£ºÔÚijһ·Ö¼¶±ê¶ÈÄڵ𢡊ߵĻò×î¸ßµÄµã»ò³Ì¶È£º the governmental stratosphere; business expenses in the stratosphere. Õþ¸®×î¸ß²ã£»¼«¸ßµÄÉÌÒµÖ§³ö·ÑÓà strato= [É¢¿ª] *²Î¼û stratus band-to-band transition ´ø¼äԾǨ [µç×Ó] Polymer solar cells with enhanced fill factors https://www.nature.com/nphoton/j ... c_id=NPHOTON-201310 Recent advances [×îнøÕ¹/] in # polymer solar cell (PSC)[¾ÛºÏÎïÌ«ÑôÄÜµç³Ø/] performance [ÐÔÄÜ/] have resulted from //compressing the bandgap[:ѹËõ´øÏ¶] to enhance the //short-circuit current[:¶Ì·µçÁ÷] while lowering the highest occupied molecular orbital to increase the //open-circuit voltage[:¶Ï·µçѹ]. Nevertheless, PSC power //conversion efficiencies[:ת»»Ð§ÂÊ] are still constrained by low //fill factors[:Ìî³äÒò×Ó], typically[ͬusually] below 70%. Here, we report[Ìá³ö] PSCs with exceptionally [ͬ:to an exceptional degree = Òì³£µÄ] high fill factors by combining //complementary materials design[:¸¨Öú²ÄÁÏÉè¼Æ], synthesis, processing[¼Ó¹¤] and device engineering[Éè¼Æ] strategies. The //donor polymers[:¾ÛºÏÎ﹩Ìå], PTPD3T and PBTI3T, when incorporated into #inverted bulk-heterojunction PSCs with a PC71BM acceptor, result in PSCs with fill factors of 76¨C80%. [----------------ÎÊÌâÖеÄdepartures from unityµÄ ͬÒåת»» ¾ÍÔÚϾ仰ÖÐ-----------] The //enhanced performance/ is attributed to //highly ordered, closely packed and properly oriented[:¸ß¶ÈÓÐÐò£¬½ôÃÜÅÅÁкͷ½ÏòÕýÈ·µÄ ;¾ÍÊÇunityµÄ¸Äд] active-layer microstructures[΢¹Û½á¹¹] with //optimal horizontal phase separation and vertical phase gradation[×îÓŵÄˮƽ Ïà·ÖÀëºÍ´¹Ö±µÄ Ïཥ±ä]. The result is efficient charge extraction and suppressed bulk and interfacial bimolecular recombination[?????]. The high fill factors yield// power conversion efficiencies/ of up to 8.7% from polymers with suboptimal[µÚ¶þ×îºÃµÄ=´ÎÓŵÄ?] bandgaps, suggesting that efficiencies above 10% should be realizable by bandgap modification. # inverted bulk-heterojunction #heterojunction n.ÒìÖʽá heterojunction is a //semiconductor junction[:°ëµ¼Ìå½á] which is composed of layers of dissimilar[:²»Í¬µÄ;unlike] semiconductor material, these materials having non-equal band gaps. In such a structure, the implementable[:¿ÉʵÏÖµÄ] diode [¶þ¼«¹Ü]characterstics can closely approach[½Ó½ü] those of an idealized diode. Furthermore[´ËÍâ], the diode model parameters that #define //the diode current vs. voltage response [???]can be tuned by adjusting the thicknesses and //band gaps[´øÏ¶] of the layers. °ëµ¼ÌåµÄÒìÖʽáÊÇÒ»ÖÖÌØÊâµÄPN½á£¬ÓÉÁ½²ãÒÔÉϲ»Í¬µÄ°ëµ¼Ìå²ÄÁϱ¡Ä¤ÒÀ´Î³Á»ýÔÚͬһ»ù×ùÉÏÐγɣ¬ÕâЩ²ÄÁϾßÓв»Í¬µÄ[ÄÜ´øÏ¶]£¬ËüÃÇ¿ÉÒÔÊÇÉ黯ïØÖ®ÀàµÄ»¯ºÏÎҲ¿ÉÒÔÊǹè-ÕàÖ®ÀàµÄ°ëµ¼ÌåºÏ½ð¡£ °ëµ¼ÌåÒìÖʽṹµÄ¶þ¼«¹ÜÌØÐԷdz£½Ó½üÀíÏë¶þ¼«¹Ü¡£ÁíÍ⣬ͨ¹ýµ÷½Ú°ëµ¼Ìå¸÷²ÄÁϲãµÄºñ¶ÈºÍÄÜ´øÏ¶£¬¿ÉÒԸıä¶þ¼«¹ÜµçÁ÷ÓëµçѹµÄÏìÓ¦²ÎÊý¡£°ëµ¼ÌåÒìÖʽṹ¶Ô°ëµ¼Ìå¼¼Êõ¾ßÓÐÖØ´óÓ°Ï죬ÊÇ¸ßÆµ¾§Ìå¹ÜºÍ¹âµç×ÓÆ÷¼þµÄ¹Ø¼ü³É·Ö¡£ https://zh.wikipedia.org/wiki/ÒìÖʽá in an environmentally benign fashion. in an environmentally benign fashion. in an environmentally benign fashion. ÔÚÒ»¸ö»·¾³ÓѺõķ½Ê½¡£ https://groups.yahoo.com/neo/gro ... sations/topics/3624 polymer (plastic) solar cells ¾ÛºÏÎËÜÁÏ?£©Ì«ÑôÄÜµç³Ø ×¢ rganic solar cells (also called "plastic solar cells"# amorphous[ûÓÐÐÎ×´µÄ=·Ç¾§ÌåµÄ] silicon solar cell [ ] ·Ç¾§¹èÌ«Ñôµç³Ø environmentally benign materials environmentally benign materials environmentally benign materials ¶Ô»·¾³ÎÞº¦µÄ²ÄÁÏ With our high fill factors, polymers with very good but not champion light absorption still are able to achieve very good efficiency." ¡°Ëæ×ÅÎÒÃǵĸßÌî³äÒò×Ó£¬#¾ßÓзdz£ºÃµÄ£¬µ«²»Êǹھü/µÄ¹âÎüÊÕ¾ÛºÏÎïÈÔÈ»Äܹ»´ïµ½ºÜºÃµÄЧÂÊ¡£ very good but not champion very good but not champion very good but not champion photovoltaic effect. photovoltaic effect ¡®ÎïÀí¡¯¹âÉú·üÌØÐ§Ó¦ ×¢:voltaic = ·ü´òµçµÄ µçÁ÷µÄ£¬·ü´ò£¨Ê½£©µÄ µçÁ÷µÄ£¬·ü´ò£¨Ê½£©µÄ µçÁ÷µÄ£¬·ü´ò£¨Ê½£©µÄ µçÁ÷µÄ£¬·ü´ò£¨Ê½£©µÄ voltaic [Ò½] ·ü´òµçµÄ, [Ö±]Á÷µçµÄ; ¶¯µçµÄ[¡ßvolt = ת¶¯ ] µçÁ÷µÄ£¬·ü´ò£¨Ê½£©µÄ£ºÍ¨¹ý»¯Ñ§·´Ó¦²úÉúµÄµçÁ÷µÄ #¶¯Éúµç¶¯ÊÆ motional electromotive force #¸ÐÉúµç¶¯ÊÆ [ ] induced electromotive force antithetical adj.¶ÔÁ¢µÄ antipodal adj.Õý·´¶ÔµÄ,ǡǡÏà·´µÄ de.fine v.tr.£¨¼°Îﶯ´Ê£© 1. To //state the precise meaning of/(a word or sense of a word, for example). state the precise meaning of state the precise meaning of state the precise meaning of state the precise meaning of ¸ø¡Ï¶¨Ò壺#¸ø£¨ÀýÈ磬µ¥´Ê»ò´ÊÒ壩Ͼ«È·µÄ¶¨Òå 2. To //describe the nature or basic qualities of; explain: ²ûÊÍ£ºÃèÊö¡µÄÐÔÖÊ»ò»ù±¾ÌØÕ÷£»½âÊÍ£º define the properties of a new drug; a study that defines people according to their median incomes. define the properties of a new drug define the properties of a new drug define the properties of a new drug ½âÊÍÒ»ÖÖÐÂÒ©µÄÌØÐÔ£»¸ù¾ÝÈËÃÇµÄÆ½¾ùÊÕÈë²ûÊ͵ĵ÷²é #3. To //delineate the outline or form of/: ¹´»³ö¡µÄÂÖÀª»òÍâÐΣº gentle hills that were defined against the sky. ÔÚÌì¿ÕµÄ³ÄÍÐÏÂÏÔµÃÂÖÀª·ÖÃ÷µÄÇðÁê 4. To specify distinctly: Çå³þµØ¹æ¶¨£º define[:Ã÷È·µØ¹æ¶¨] the weapons to be used in //limited warfare[:¾Ö²¿Õ½Õù]. 5. To //serve to[:ÓÃÓÚ] distinguish; characterize: ÓÃÓڷֱ棻ÏÔʾ¡µÄÌØÉ«£º ¡°portraits that defined the style of an epoch¡±(&b{Gloria Vanderbilt}) defined the style of an epoch defined the style of an epoch defined the style of an epoch defined the style of an epoch ¡°±íÏÖÒ»¸öʱ´ú·ç¸ñÌØÕ÷ µÄÃèд¡±(¸ñÂåÀöÑÇ¡¤·¶µÂ±È¶ûÌØ) Fig. 1. Schematic [ʾÒâͼ;ͼ½â]of plastic solar cells. PET ¨C polyethylene terephthalate, ITO ¨C indium tin oxide, PEDOT SS ¨C poly(3,4-ethylenedioxythiophene), active layer (usually a polymer:fullerene blend), Al ¨C aluminium.Mechanism[edit] Polymer solar cells usually consist of an electron- or //hole-blocking layer[¿ÕѨ×èµ²²ã/] on top of an //indium tin oxide[î÷ÎýÑõ»¯Îï/] (ITO) //conductive glass[µ¼µç²£Á§ /] followed by //electron donor[µç×Ó¸øÌå/] and an //electron acceptor[µç×ÓÊÜÌå/] (in the case of bulk heterojunction solar cells), a hole or electron blocking layer, and metal electrode on top. The nature and order of the blocking layers ¨C as well as the nature of the metal electrode ¨C depends on whether the cell follows a regular or an inverted device architecture[¹¹Ô췽ʽ]. In bulk heterojunction polymer solar cells, light generates #excitons[¼¤×Ó] with subsequent separation of charges in the interface between an electron donor and acceptor blend within the device¡¯s active layer. //These charges[ÕâЩµçºÉ] then transport to the device¡¯s electrodes where these charges flow outside the cell, //perform work[??] and then re-enter the device on the opposite side. The cell's efficiency is limited by several factors especially //non-geminate recombination[·Ç³ÉË«µÄÖØ×é/]. Hole mobility [¿ÕÑ¨Ç¨ÒÆÂÊ/]leads to faster conduction[´«µ¼] across the active layer.[7][8] Exciton ¼¤×Ó£ºÓÉÓÚÎüÊÕ¹â×ÓÔÚ¹ÌÌåÖвúÉúµÄ¿ÉÒÆ¶¯µÄÊø¸¿µÄµç×Ó-¿Õ×Ó¶Ô An exciton is a bound state of an electron and an imaginary particle called an electron hole in an insulator (or semiconductor), or in other words, a Coulomb correlated electron-hole pair. It is an elementary excitation, or a quasiparticle of a solid. a localized, mobile excited state of a crystal, consisting of an electron and a hole bound together. roughage ´Ö²ÚʳÎï (¿É´Ì¼¤³¦µÄÈä¶¯ÓªÑø¼ÛÖµµÍ¶ø·ÖÁ¿¶àµÄʳÎï; ÀýÈçÏËάÖÊ,ʳÓÿ·µÈ) # bulk /bəlk/ ♫ ▶ noun the //mass or magnitude[ÖÊÁ¿»òÕß·ù¶È] of something large: the sheer bulk of the bags. • a large mass or shape, for example of a building or a //heavy body[¸ßÈÝÁ¿]: he moved quickly in spite of his bulk. • [as modifier] large in quantity[ÊýÁ¿;] or amount[Êý¶î]: bulk[´óÁ¿µÄ] orders of more than 100 copies. large in quantity or amount large in quantity or amount large in quantity or amount large in quantity or amount ×¢:ÊýÁ¿ºÍÊý¶îÓÐʲô²î±ð? ÊýÁ¿ ÓÃÓÚÎïÓÃÓÚ»õ Êý¶î ÓÃÓÚÇ®ÓÃÓÚ±Ò [´Ë½âÊÍ´¿ÊôÐé¹¹] • (the bulk) the majority[´ó¶àÊýµÄ] or greater[¶àµÄ] part of something: the bulk of the traffic had passed. • #roughage in food: bread and potatoes supply energy, essential protein, and bulk. ×¢:roughage = rough+age • cargo that is an unpackaged mass such as grain, oil, or milk. ▶ verb [no obj.] be or seem to be of great size or importance: territorial questions bulked large in diplomatic relations. [with obj.] treat (a product) so that its quantity appears greater than it in fact is: traders were bulking up their flour with chalk.??? • [no obj.] (bulk up)// build up body mass[ÔöÖØ], typically in training for athletic events. build up body mass[ÔöÖØ],??? put on weight [ ]ÌåÖØÔö¼Ó??? ¨C origin Middle English: the senses ¡®cargo as a whole¡¯ and ¡®heap, large quantity¡¯ (the earliest recorded) are probably from Old Norse b¨²lki ¡®cargo¡¯; the origin of other senses remains uncertain, perhaps arising by alteration[¸Ä±ä] of obsolete bouk ¡®belly, body.¡¯ The original senses are also reflected in the phrases break bulk and in bulk. break-bulk ÕâÊÇÐÎÈÝ´Ê Having, being, or related to shipments of goods packed in small, separable units. ·Ç¼¯×°Ï仯µÄ£¬·Ö¼þµÄ£º°Ñ»õÎï°ü×°³ÉСµÄ¡¢¿É·ÖÀëµÄµ¥Î»×°Ôص쬻òÓëÖ®Ïà¹ØµÄ break bulk µ«Õâ²»ÊÇÐÎÈÝ´Ê [¾] Ï»õ, ж»õ v in bulk (esp. of goods)// in large quantities[:´óÅúÁ¿µÄ], usually at a //reduced price[¼õ¼Û?;½µ¼Û?;´¦Àí¼Û¸ñ?;ÕÛ¿Û¼Û¸ñ?]: buying tomatoes in bulk from a local farmer. (of a cargo or commodity) loose[É¢×°µÄ]; not packaged: sugar is imported in bulk and bagged on the island. ÒÔÏÂÄÚÈÝ´¿ÊôÐé¹¹: ijijÒò×ÓÊÇÎïÀíÖÐʵÔڵĶ«Î÷,±ÈÈç ´Ö²Ú³Ì¶ÈµÈµÈ. ijijϵÊýÊÇÓÃÊý×ÖÀ´±ÈijijÒò×ӵĴóС²îÒì.ÊÇÈËÃÇΪÁË·½±ãÀí½âºÍ¼ÆËã https://zhidao.baidu.com/link?ur ... JemYNDGMXxuWVLzThH_ enhanced Ìá¸ßµÄ hance ¹°ÑüÍÖÔ²¹°½Å´¦µÄ×îС°ë¾¶ ¹°Ñü [½¨];¹°Ò¸ haunch 1. The hip, buttock, and upper thigh in human beings and animals. ÍÈÍβ¿£ºÈË»ò¶¯ÎïµÄ÷Ų¿¡¢Íβ¿¼°´óÍÈÉϲ¿ 2. The loin and leg of a four-footed animal, especially as used for food: ÑüÍÈ£ºËÄ×㶯ÎïµÄÑü²¿ºÍÍȲ¿£¬ÓÈÖ¸ÓÃÀ´Ê³ÓõIJ¿·Ö£º a haunch of venison. Ò»¿é¹µÄÑüÍÈÈâ 3. Architecture Either of the sides of an arch, curving down from the apex to an impost. ¡¾½¨Öþѧ¡¿ ÁºÒ¸£¬¹°Ò¸£º¹°ÃÅÉÏÈÎÒâÒ»¸ö´Ó¹°¶¥µ½¹°¶Õ¼äµÄ²¿·Ö[×¢ÊÇÒ»¸ö»¡ÐεÄÇøÓò] ÔÚ½ü´¦ÊØÎÀ ¹°Ò¸ ==¹°Ñü ==ÁºÒ¸ ==¹°ÃÅÉÏÈÎÒâÒ»¸ö´Ó¹°¶¥µ½¹°¶Õ¼äµÄ²¿·Ö ==haunch ==Either of the sides of an arch, curving down from the apex to an #impost.[¹°¶Õ] https://zhidao.baidu.com/link?ur ... ismsfWzqcG9-8yHt4jq trap[=hole?] assisted and //tail state[???] recombination.??? Recombination via tail states in polythiophene[¾Ûàç·Ô]: //fullerene solar cells[¸»ÀÕϩ̫ÑôÄÜµç³Ø] State-of-the-art [×îÐÂÐ͵Ä] models used for //drift-diffusion[Æ¯ÒÆÀ©É¢] simulations of organic //bulk heterojunction solar cells[±¾ÌåÒìÖʽáÌ«ÑôÄÜµç³Ø/] based on band transport are not capable of reproducing the voltage dependence of dark current density and carrier concentration of such devices, as determined by current-voltage and charge-extraction measurements. Here, we show how to correctly reproduce this experimental data by including an //exponential tail[Ö¸ÊýÇúÏßβ/] of //localized states[¶¨Óò̬/] into the //density of states[̬ÃܶÈ] for both electrons and holes, and allowing recombination to occur between free //charge carriers[ÔØÁ÷×Ó] and charge carriers trapped in these states. When this recombination via tail states is included, the dependence of charge-carrier concentration on voltage is distinctly different from the case of band-to-band recombination and the dependence of recombination current on //carrier concentration[ÔØÁ÷×ÓÃܶÈ] to a power higher than 2 can be explained. ©2011 American Physical Society # In probability theory, heavy-tailed distributions are probability distributions whose tails are not exponentially bounded[Óнç]:[1] that is, they have //heavier tails[½ÏÖØµÄ²»¿ÉºöÊÓµÄβ°Í] than the exponential distribution. In many applications it is the right tail of the distribution that is of interest, but a distribution may have a heavy left tail, or both tails may be heavy. There are three important subclasses[СÀà] of heavy-tailed distributions, the fat-tailed distributions[´Öβ·Ö²¼], the long-tailed distributions and the subexponential distributions[ÑÇÖ¸Êý·Ö²¼]. //In practice [ʵ¼ÊÉÏ/], all commonly [=normally/]used heavy-tailed distributions belong to the subexponential class. There is still some discrepancy[²»Ò»ÖÂ] over the use of the term heavy-tailed. There are two other definitions in use. Some authors use the term to refer to those distributions which do not have all their power[??????] moments[???????] finite[ÓÐÏÞµÄ]; and some others to those distributions that do not have a //finite variance[ÓÐÏÞ·½²î/]. The definition given in this article is the most general in use, and includes all distributions encompassed by the alternative definitions, as well as those distributions such as log-normal [¶ÔÊýÕý̬·Ö²¼] that possess all their power moments, yet which are generally acknowledged to be heavy-tailed. (Occasionally, heavy-tailed is used for any distribution that has heavier tails than the normal distribution.) |
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rganic solar cells (also called "plastic solar cells"
SS ¨C poly(3,4-ethylenedioxythiophene), active layer (usually a polymer:fullerene blend), Al ¨C aluminium.