| 查看: 1118 | 回复: 4 | |||
DongdongMeng木虫 (著名写手)
|
[交流]
一篇珍贵的文献，收费有可能也下不到的。希望能帮到大家。 已有2人参与
|
|
很不好下的文献“Highly Luminescent Lead Bromide Perovskite Nanoparticles Synthesized with Porous Alumina Media” 既然下到共享一下，希望能帮到各位。 |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : Highly_Luminescent_Lead_Bromide_Perovskite_NanoparticlesSynthesized_with_Porous_Alumina_Media.pdf
2013-12-02 07:52:27, 2 M
» 猜你喜欢
366求调剂
已经有9人回复
-
材料工程085601，270求调剂
已经有37人回复
-
279学硕食品专业求调剂院校
已经有18人回复
-
290调剂生物0860
已经有31人回复
-
一志愿085802 323分求调剂
已经有13人回复
-
277求调剂
已经有23人回复
-
322求调剂，08工科
已经有4人回复
-
材料工程281还有调剂机会吗
已经有30人回复
-
化学070300 求调剂
已经有16人回复
-
化工学硕294分，求导师收留
已经有12人回复
» 本主题相关价值贴推荐，对您同样有帮助:
- 期刊文献图收馆帐号密码大全
已经有31人回复
Meteorの泪
荣誉版主 (知名作家)
正在奋斗的----小星
- PEPI: 16
- 应助: 224 (大学生)
- 贵宾: 3.705
- 金币: 14378.4
- 散金: 9280
- 红花: 110
- 沙发: 19
- 帖子: 5442
- 在线: 873.6小时
- 虫号: 1446509
- 注册: 2011-10-17
- 性别: GG
- 专业: 高分子合成化学
- 管辖: 高分子
2楼2013-12-02 11:23:04
DongdongMeng
木虫 (著名写手)
- 应助: 63 (初中生)
- 金币: 4380.3
- 散金: 238
- 红花: 18
- 帖子: 2330
- 在线: 141.8小时
- 虫号: 1940469
- 注册: 2012-08-15
- 性别: GG
- 专业: 水泥与耐火材料
3楼2013-12-03 10:00:46
DongdongMeng
木虫 (著名写手)
- 应助: 63 (初中生)
- 金币: 4380.3
- 散金: 238
- 红花: 18
- 帖子: 2330
- 在线: 141.8小时
- 虫号: 1940469
- 注册: 2012-08-15
- 性别: GG
- 专业: 水泥与耐火材料
|
Abstract: Nanocrystallinelead bromide perovskite was synthesized by rapidself-organization on a mesoporous aluminum oxidefilm. With UV excitation, thefilm exhibited anintense green emission with a narrow bandwidth. The photoluminescenceintensity is optimizedfor the conditions ofsynthesis and the kind ofmetal oxide. High surface areas and activities realized by nanotextured materials create efficient mediafor energy conversion with use of small amounts of resources such as metals, semiconductors, and organic compounds. 1 Among semiconductive material, metal halide perovskites have been investigated as a lowdimensionallayered compound,inwhich perovskite units are surrounded by organic methyl- or phenylammonium groups. These materials possess semiconductivity with band-gap structures confined by the organicmolecule, exhibiting attractive optical and electrical properties due to quantum size effects. To date, quantum wells,2,3 wires, 4 and dots 5,6 characterized as organic-inorganic perovskite compounds have also been synthesized. There are onlyafew reports on zero-dimensional pure perovskite nanocrystalswithout organic insulator layers 7 because it isdifficult on synthesis to control theirdimension. Amonglead halide type perovskites, bulk crystals, CH3NH3-PbX3(X=Br, Cl, and I), 8,9 can be synthesizedfrom CH3NH3X and PbX2 by solid-phase or solution-based self-organization techniques. Such preparation methods, however, have not been successfully applied to nanocrystallization oflead halide perovskite. In our previous report, we have shownfor thefirst time photoelectric conversion using the perovskite nanocrystals CH3NH3PbBr3 and CH3NH3PbI3 as visiblelight sensitizers to an n-type semiconductor, TiO2. 10 High quantum conversion efficiency,i.e., electroninjectionfrom these perovskites to TiO2 surfaces, was realized byformation of perovskite nanocrystalline particles with a diameter of2-3 nm successfully synthesized by a solution technique. Here, we report fabrication of an efficientlight emission medium created with the CH3NH3PbBr3 nanoparticles. Self-organized withinanoxide mesoporousfilm, the nanocrystals proved to be capableof highintensity, green photoluminescence. In this study, a thinAl2O3film was chosen as a mesoporous medium, which, as aninsulator, possess alarge energy band gap of 8.7 eV 11 and highionization potential 12 so that photonic energy absorbed by CH3NH3PbBr3 can befully converted toluminescence. Alow-viscosity Al2O3paste was prepared by mixing 2.4 g of Al2O3 nanopowder (spherical particlewith size 40-50 nm, Wako Pure Chemical), 1.5 mL ofacetylacetone, 3 mL ofpurified water, 14 mL of ethanol, and 2 g of poly(ethylene glycol) (average molecular weight: 20000«5000) and subsequent grinding with an agate mortar. The paste was spin-coated onto a quartz glass substrate (2.5 cm©2.5 cm) at 4000 rpmfollowed by sintering at 500 °Cfor 1 hinair. The resultant porous filmis mostly amorphous and has thickness ofabout 1ˉm as confirmed by scanning electron microscopy observations. Semiconductor |
4楼2013-12-03 10:04:12
 谢谢分享 |
5楼2013-12-05 10:54:51
