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[资源] 生物基聚合物及其复合物（Bio-Based Polymers and Composites）

Bio-Based Polymers and Composites (640p)
Editors：Richard Wool & Xiuzhi Susan Sun
ISBN：978-0-12-763952-9
Copyright：2005 Elsevier
链接：http://www.sciencedirect.com/science/book/9780127639529
站内搜索：http://muchong.com/bbs/search.php?wd=Bio-Based+Polymers+and+Composites&fid=&uid=336485 （无重复）
目录：

Preface xiii
About the Authors xvii
1 Overview of Plant Polymers:
Resources, Demands, and
Sustainability 1
Xiuzhi Susan Sun
Plant Proteins 2
Plant Oils 5
Plant Starches 6
Agriculture Fibers and Cellulose 6
Market Potential for Plant Polymers 7
Sustainable Agriculture Industry of the Future 9
Conclusion 12
References 12
2 Plant Materials Formation
and Growth 15
Xiuzhi Susan Sun
Plant Material Synthesis 16
Plant Growth 27
Transgenic Plants 30
References 32
vii
3 Isolation and Processing of Plant
Materials 33
Xiuzhi Susan Sun
Oil Extraction and Refining 33
Starch Wet Milling 41
Protein Isolation 48
References 55
4 Polymers and Composite Resins
from Plant Oils 56
Richard P. Wool
Introduction 56
Synthetic Pathways for Triglyceride-Based Monomers 57
Polymers from Plant Oils 75
Properties of Plant Oil Resins 85
Castor Oil-Based Polymer Properties 102
Summary of Plant Oil-Based Polymer Properties 110
References 111
5 Composites and Foams from Plant
Oil-Based Resins 114
Richard P. Wool
Triglyceride-Based Composite Materials 115
Manufacturing of Glass Fiber-Reinforced Composites 117
Composite Properties 118
Sheet Molding Compound 123
Bio-Based Polymeric Foams 135
Summary of Bio-Based Composites 146
References 147
6 Fundamentals of Fracture in
Bio-Based Polymers 149
Richard P. Wool
Fracture of Polymers: Fundamental Theory 150
Applications of Fracture Theory 156
Microscopic to Macroscopic Fracture Relations 172
Polymer–Polymer Interfaces 176
Polymer–Solid Interfaces 191
viii Contents
Summary of Fractures in Bio-Based Polymers 198
References 199
7 Properties of Triglyceride-Based
Thermosets 202
Richard P. Wool
Introduction 203
Distribution of Fatty Acids and Unsaturation Sites in
Triglycerides 205
Distribution of Functional Groups on Triglycerides 206
Cross-Link Density 208
Tensile Properties 213
Computer Simulations of Triglyceride Structure and Strength 217
Glass Transition Temperature versus Structure 223
Rheology of Triglyceride Resins 232
Results and Discussion 235
Summary of Triglyceride Rheology 252
References 253
8 Pressure-Sensitive Adhesives,
Elastomers, and Coatings from
Plant Oil 256
Richard P. Wool
Introduction to Pressure-Sensitive Adhesives 257
Macroemulsion and Miniemulsion Polymerization 259
Polymer Characterization 261
Polymer Properties 261
Polymer–Solid Adhesion Modification of PSAs 269
Bio-Based Elastomers 274
Bio-Based Coatings 282
References 289
9 Thermal and Mechanical Properties
of Soy Proteins 292
Xiuzhi Susan Sun
Structure and Thermal Behavior of Soy Protein 292
Curing Strength of Soy Proteins 300
Mechanical Properties of Soy Proteins 305
Physical Aging of Soy Protein Plastics 311
Contents ix
Compatibility of Soy Protein with Polyester 313
Water Absorption of Soy Protein 319
Summary 323
References 323
10 Soy Protein Adhesives 327
Xiuzhi Susan Sun
Protein Adhesion Mechanism 328
Protein Unfolding and Adhesive Properties 332
Effects of Curing Temperature and Pressure on
Adhesive Strength 340
Viscosity of Soy Protein Adhesives 343
Natural Straw Composites with Soy Protein Adhesives 345
Production of Low-Cost Adhesive in Powder Form 349
Soy Protein Latex-Like Adhesives 354
Adhesive Strength and Water Resistance at Isoelectric pH 359
References 366
11 Plastics Derived from Starch
and Poly (Lactic Acids) 369
Xiuzhi Susan Sun
Starch Structure 369
Thermal Properties of Starch 372
Starch as a Filler 375
Starch as a Nucleating Agent 381
Coupling Reagents for Starch and PLA Blends 382
Role of Water in Starch and PLA Blends 394
Plasticization of Starch and PLA Blends 396
Physical Aging of Starch and PLA Blends 403
Summary 405
References 407
12 Bio-Based Composites from Soybean
Oil and Chicken Feathers 411
Richard P. Wool
Introduction 411
Processing of Chicken Feather Fiber Composites 413
Electronic Materials from Feather Composites 424
Mechanical and Fracture Properties 428
x Contents
Carbon Fibers from Chicken Feathers 435
Summary of KFS Composites 445
References 446
13 Hurricane-Resistant Houses from
Soybean Oil and Natural Fibers 448
Richard P. Wool
Introduction and Background 449
Bio-Based Materials 452
Composite Processing and Manufacturing 455
Applications: Housing Construction Material 460
Design of the Bio-Based Composite Roof 466
Design, Testing, and Evaluation of a Model Beam 468
Building a Bio-Based Composite Roof 475
Other Potential Applications 477
References 480
14 Carbon Nanotube Composites with
Soybean Oil Resins 483
Richard P. Wool
Introduction to Carbon Nanotubes 484
Single-Walled Carbon Nanotube Composites 485
Multiple-Walled Carbon Nanotube Composites 490
On the Dispersibility of Carbon Nanotubes 506
Summary 519
References 520
15 Nanoclay Biocomposites 523
Richard P. Wool
Preparation of Nanoclay–Soybean Oil Composites 526
Soy–Nanoclay Composites 529
Summary 549
References 549
16 Lignin Polymers and Composites 551
Richard P. Wool
Introduction to Lignin 552
Lignin Applications 557
Contents xi
Lignin Modification 562
Unmodified Lignin Addition to Soybean Oil Monomers 564
Chemical Modification of Kraft Lignin 569
Flory–Huggins Theory 574
Butyrated Kraft Lignin in Thermosetting Polymers 578
Comment on Biorefinery 591
References 593
Index 599

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