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| It is conventional to classify electrochemical reactions as outer-sphere and innersphere.The former involve the outer coordination sphere of a reacting ion. Thus, little if any change inside the ion solvate shell occurs; they proceed without breakingup intramolecular bonds. But in the latter, involving the inner coordination sphere, electron transfer is accompanied by breaking up or formation of such bonds. Often the inner-sphere reactions are complicated by adsorption of reactants and/or reaction products on the electrode surface. The electron transfer in the Fe(CN)63-/4- system is example of an outer-sphere reaction (with due reservation for some complications caused by O-containing groups on the carbon electrode surface [89]). The oxidation or reduction of water molecules with O2 or H2 evolution, respectively, exemplifies inner-sphere reactions. |
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