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spin catalysisÊÇʲôÒâ˼ [ Last edited by rabbit7708 on 2007-11-12 at 19:00 ] |
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This phenomenon takes place in three-spin systems, when the third radical (or a paramagnetic ion) induces spin conversion in the pair, removes spin forbiddance, and thus changes the reactivity of the first two radicals. Kinetic equations for yields of spin catalyzed reactions have been derived. Russian Chemical Bulletin, 44 (1995) 1578 International Journal of Quantum Chemistry, Vol. 57, 519-532 (1996) |
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3Â¥2007-11-12 23:49:40














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