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lthy007金虫 (小有名气)
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[求助]
悬赏查询关于乙烯合成丙烯腈的资料
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在魏文德的《有机化工原料大全》（1990年）第一版第三册P106页中提到日本旭化成公司开发的以乙烯与氢氰酸和氧通过钯催化剂合成丙烯腈，具体反应式是： C2H4 + HCN +1/2O2 = CH2CHCN + H2O 据说是进行了中间试验。 但是在国内，我再也查不到相关的资料，有谁能否帮忙查到这个资料的日文或其它国外文献的资料呢？ 若能帮忙查到相关资料，必有重赏，谢谢。[ Last edited by lthy007 on 2013-7-28 at 09:48 ] |
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2013-07-28 09:47:17, 38.86 K
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lelelbom
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4楼2013-07-28 16:25:42
lelelbom
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【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ...
感谢参与，应助指数 +1
lthy007: 金币+150, ★★★很有帮助, 虽然不是旭化成的那个工艺资料，但是也是非常有价值的，谢谢了 2013-07-28 11:59:48
zyz666888: 金币+2, 感谢应助，欢迎常来！ 2013-07-29 11:10:21
感谢参与，应助指数 +1
lthy007: 金币+150, ★★★很有帮助, 虽然不是旭化成的那个工艺资料，但是也是非常有价值的，谢谢了 2013-07-28 11:59:48
zyz666888: 金币+2, 感谢应助，欢迎常来！ 2013-07-29 11:10:21
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T=800 - 870°C; Allied Chem.and Dye Corp. Patent: US2445693 , 1946 ; 专利下载路口地址http://www.drugfuture.com/uspat/us_patent.asp |
2楼2013-07-28 10:14:33
lthy007
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3楼2013-07-28 12:10:17
lelelbom
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With ammonia; oxygen; Nippon Shokubai catalyst (ACF ) in water ARKEMA FRANCE 4 Patent: US2010/48850 A1, 2010 ; T=420°C; Location in patent: Page/Page column 6 ; With air; ammonia; molybdenum(VI) oxide Distillers Co. T=365 - 400°C; Patent: US2836614 , 1953 ; Distillers Co. Patent: US2691037 , 1954 ; With air; phosphomolybdic acid on silica; ammonia Distillers Co. T=365 - 400°C; Patent: US2836614 , 1953 ; Distillers Co. Patent: US2691037 , 1954 ; 84% With INEOS USA LLC ammonia; oxygen; Ni Mg Fe Rb Cr Bi Ce Mo O +50 Patent: US2011/237820 A1, 2011 ; 4 3 0.9 0.192 0.05 0.72 1.76 12.806 51.539 Location in patent: Page/Page column 5-6; 8-9; 10 ; wt percent SiO 2 T=430°C; P=1277.21 Torr; Gas phase; Product distribution / selectivity; 84% With INEOS USA LLC ammonia; oxygen; Ni Mg Fe Rb Cr Bi Ce Mo O +50 Patent: US2011/237821 A1, 2011 ; 4 3 0.9 0.192 0.05 0.72 1.76 12.806 51.539 Location in patent: Page/Page column 5; 8-9; 10 ; wt percent SiO 2 T=430°C; P=1277.21 Torr; Gas phase; Product distribution / selectivity; 82.1% With ammonia; oxygen; catalyst C; catalyst A Asahi Kasei Chemicals Corporation T=430°C; P=367.786 Torr; Gas phase; Product distribution / selectivity; Patent: JP2005/162707 A, 2005 ; Location in patent: Page/Page column 8 ; 62% With ammonia; oxygen; Mo V Nb Te mixed oxides Guram, Anil; Hagemeyer, Alfred; Lugmair, Claus G.; Turner, Howard W.; 1 0.32 0.15 0.23 Volpe, Anthony F.; Weinberg, W. Henry; Yaccato, Karin T=420°C; atmospheric pressure; Product distribution; Further Advanced Synthesis and Catalysis, 2004 , vol. 346, # 2-3 p. 215 - 230 Variations:Catalysts; 61% With ammonia; oxygen; Mo V Sb Nb Te Ti Nd O(n) Lugmair, Claus G.; Cohen, Steven Alan 1 0.3 0175 0.06 0.02 0.1 0005 Patent: US2008/200715 A1, 2008 ; T=420°C; Gas phase; Product distribution / selectivity; Location in patent: Page/Page column 6 ; 60% With ammonia; oxygen; Mo V Sb Nb Te Ti Li Nd O(n) Lugmair, Claus G.; Cohen, Steven Alan 1 0.3 0.18 0.08 0.02 0.1 0016 0005 Patent: US2008/200715 A1, 2008 ; T=433°C; Gas phase; Product distribution / selectivity; Location in patent: Page/Page column 6-7 ; A: 6.1% With ammonia; oxygen; BiFeMoOx in water Seely, Michael J.; Godbole, Sanjay P.; Paparizos, Christos B: T=440°C; P=1277.21 Torr; Product distribution / selectivity; Patent: US2003/219372 A1, 2003 ; 79.6% Location in patent: Page/Page column 3-4 ; C: 1.5% A B C Rx-ID: 23664910 A: 5.8% With ammonia; oxygen; BiFeMoOx in water Seely, Michael J.; Godbole, Sanjay P.; Paparizos, Christos B: T=440°C; P=1277.21 Torr; pH=5; Product distribution / selectivity; Patent: US2003/219372 A1, 2003 ; 77.3% Location in patent: Page/Page column 3-4 ; C: 2.2% A: 5.8% With ammonia; oxygen; MoV Sb Nb Ti Ce On/silica PAPARIZOS, CHRISTOS; Sutradhar, Bhagya Chandra; Seely, Michael J. 0.3 0.2 0.08 0.1 0005 B: Brazdil, JR., James F.; Bhattacharyya, Alakananda T=440°C; P=1018.63 Torr; Product distribution / selectivity; 41.7% Patent: US2009/198081 A1, 2009 ; C: 0.8% Location in patent: Page/Page column 8 ; A: 3.7% With ammonia; water; oxygen; MoV Sb Nb On/Sb O /silica PAPARIZOS, CHRISTOS; Sutradhar, Bhagya Chandra; Seely, Michael J. 0.21 0.24 0.09 2 3 B: 41% Brazdil, JR., James F.; Bhattacharyya, Alakananda T=460°C; P=1277.21 Torr; Product distribution / selectivity; C: 2.5% Patent: US2009/198081 A1, 2009 ; Location in patent: Page/Page column 8-9 ; A: 5.3% With ammonia; water; oxygen; MoV Sb Nb Ti Ce On/silica PAPARIZOS, CHRISTOS; Sutradhar, Bhagya Chandra; Seely, Michael J. 0.3 0.2 0.08 0.1 0005 B: Brazdil, JR., James F.; Bhattacharyya, Alakananda T=440 - 460°C; P=1018.63 Torr; Product distribution / selectivity; 41.3% Patent: US2009/198081 A1, 2009 ; C: 0.1% Location in patent: Page/Page column 8 ; With ammonia; oxygen; VW Bi O(x) Saudi Basic Industries Corporation 0.5 1.6 Patent: US2007/123730 A1, 2007 ; T=500°C; P=760.051 Torr; Gas phase; Product distribution / selectivity; Location in patent: Page/Page column 5-6 ; With ammonia; oxygen; VW Bi B O(x) Saudi Basic Industries Corporation 0.8 1.6 0.5 Patent: US2007/123730 A1, 2007 ; T=500°C; P=760.051 Torr; Gas phase; Product distribution / selectivity; Location in patent: Page/Page column 5-6 ; With ammonia; oxygen; VW Bi Mg O(x) Saudi Basic Industries Corporation 0.8 1.6 0.05 Patent: US2007/123730 A1, 2007 ; T=500°C; P=760.051 Torr; Gas phase; Product distribution / selectivity; Location in patent: Page/Page column 5-6 ; A: 5.1% With ammonia; oxygen; germanium(IV) oxide INEOS USA LLC B: T=440°C; P=1277.21 Torr; 17 - 19 h; Gas phase; Product distribution / Patent: WO2009/48553 A2, 2009 ; 16.6% selectivity; Location in patent: Page/Page column 29 ; C: 13.8% D: 40.7% E: 1.9% F: 3.3% A: 4.5% With ammonia; oxygen; di antimony tetraoxide INEOS USA LLC B: T=440°C; P=1277.21 Torr; 15 - 18 h; Gas phase; Product distribution / Patent: WO2009/48553 A2, 2009 ; 14.1% selectivity; Location in patent: Page/Page column 28 ; C: 12.8% D: 40.9% E: 3.1% F: 2.6% A: 5.1% With ammonia; oxygen; cerium (IV) oxide INEOS USA LLC B: T=440°C; P=1277.21 Torr; 17 h; Gas phase; Product distribution / selectivity; Patent: WO2009/48553 A2, 2009 ; 15.5% Location in patent: Page/Page column 29 ; C: 14.1% D: 40.5% E: 2.2% F: 3.4% 94% With P(MeNCH CH )3N in acetonitrile Arumugam, Subramaniam; Verkade, John G. 2 2 Journal of Organic Chemistry, 1997 , vol. 62, # 14 p. 4827 - 4828 T=25°C; 0.0833333 h; T=430°C; P=109 Torr; variation of temperature and initial pressure; Kinetics; Chuchani, Gabriel; Dominguez, Rosa M. Journal of Physical Chemistry, 1989 , vol. 93, # 1 p. 203 - 205 ; (1+) (1-) Liu, Xiaodong; Verkade, John G. With sodium hydride HP(CH NCH CH )3N *Cl in acetonitrile-D 3 2 2 3 0.6 h; Journal of Organic Chemistry, 1999 , vol. 64, # 13 p. 4840 - 4843 我上传不了文件，所以有点乱，自己根据专利号看一下 |
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lthy0075楼2013-07-28 16:51:00
