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4Â¥2007-11-05 19:54:51
whasn204
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I used the chelating reaction before. I can not answer your question completely this time. but I carefully searched literatures and found one example (De chelating) for you. Unfortunately it was an old literature (should be old!!). The abstract may provide some useful informaiton for you. See the following. I think there is no big difference for ion chelated citric acid, except numbers of ligand. Complex cerium citrates. Sil'nichenko, V. G. Redkozem. Elementy, Akad. Nauk SSSR, Inst. Geokhim. i Analit. Khim (1963), 145-8. Journal language unavailable. CAN 61:23010 AN 1964:423010 CAPLUS Abstract The complex formation of Ce(III) and Ce(IV) with Na citrate was investigated. The prepn. of CeC6H5O7.3H2O (I), Na3[Ce(C6H5O7)2] .3H2O (II), and Na4[CeO(C6H5O7)2].3HO (III) is described. The compds. were obtained through reaction of the corresponding stoichiometrical amts. of Ce(NO3)3 and Na3C6H5O7. In these compds. the coordination no. of Ce (6) is satd. by 2 citric acid residues which are bound through the O atoms of the carboxyl groups. Some Ce dicitrate complexes of the type M3[Ce(C6H5O7)2] (M = Na, K, NH4) were synthesized with different alkali metal in the outer coordination sphere. Addn. of heavy metals solns. to the solns. of these complex dicitrates resulted in substitutions in the complex inner sphere leading to the formation of ppts. of low soly. Particularly, addn. of Ce(III) soln. to the soln. of the Na dicitrate resulted in the pptn. of a compd. chem. characterized as CeC6H5O7 although it is assumed to be more probably an innersphere substitution product of the complex dicitrate whose formula Ce[Ce(C6H5O7)2] does not differ from that of the simple compd. from an anal. standpoint. The compds. I, II, and III were submitted to differential thermal and thermogravimetric analysis which showed that the water of crystn. was lost smoothly without decompn. up to 200 for I and II, while the corresponding curve of III showed a sharp max. at 120 related to the transformation of Ce(IV) into Ce(III). [ Last edited by whasn204 on 2007-11-5 at 19:30 ] |

2Â¥2007-11-05 19:28:58
daiqiguang
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3Â¥2007-11-05 19:33:31
whasn204
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Êǵġ£ ÄûÃÊËáÊÇÒ»ÖÖ³£¼ûµÄchelating agent£¬ÁíÍ⻹ÓÐÒ»¸ö½ÐEDTA. ËüÃÇÂçºÍµÄ»úÀíºÜÀàËÆ£¬¾ùÊÇͨ¹ýN, »ò Oµç¸ºÐÔ½ÏÇ¿µÄÒõÀë×Ó×÷ÓÃÓÚÑôÀë×ÓÖÐÐÄ£¬ÐγɵÄÊÇÒ»¸ö¸´ºÏÎ½á¹¹Ïà¶ÔÎȶ¨¡£ WikiÓÐÕâÑùÒ»¸ö½âÊÍ£º The ligand forms a chelate complex with the substrate. The term is reserved for complexes in which the metal ion is bound to two or more atoms of the chelating agent, although the bonds may be any combination of coordination or ionic bonds. Èç¹ûÏëÁ˽â¸ü¶à£¬¿ÉÒԲο´Õâ¸öÌõÄ¿£º http://en.wikipedia.org/wiki/Chelating_agent |

5Â¥2007-11-06 14:02:19














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