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war3one

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andrewzhang

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war3one: ½ð±Ò+180, ·­ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, ллÁË 2013-08-01 16:48:15
When comparing to the pre-treatment by attenuated acid, the pre-treatment by basic solution was more powerful for raising the efficiency of enzymatic hydrolysis, and could work under less inihibitant. Yet its utilization was also limited, in respect that on one hand, the costs are higher than attenuated acid, on the other hand, the treated solution could not be discharged as easy as that of attenuated acid pre-treatment, because of the existence of high concentration of lignin and low concentration of monosaccharide. The direct discharge of basic treated solution would cause serious pollution and also a waste of source. But if the solution was treated by sulfuric acid to recover the lignin, the solution can be recovered and reused to treat raw materials, it is a very interesting research for the basic pre-treatment, it would not only reduce the cost by using the by-product in the place of cellulose alcohol, but also reduce the founds that spent on treatment of waste solution. The concentration changes of saccharides and inihibitants were showed in figure 3 and figure 4, respectively.
2Â¥2013-07-26 17:17:35
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andrewzhang

Ìú¸Ëľ³æ (ÖøÃûдÊÖ)

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2 g of lignin could be recovered by H2SO4, and these lignins were proven to can be used in various industrial domains after modification. The waste solution of pre-treatment, after been treated by centrifugation and acticarbon, showed a obvious decrease in the level of both saccharides and inihibitants. To use these recovered solutions, the concentration of pre-treatment solution must be raised, to reduce the requirement for equipment. The concentration of H2SO4 was replenished to 5%, pre-treatment lasted for 10h at 121 degree. The solution after the 2nd pre-treatment was analysed, and concentration of sacchariedes reached to 53g/L, among which the xylose was the principal material, with concentration of 73g/L. What's more, the concentration of inihibitant was very low, even lower than that of solution before pre-treatment, but 5-hydroxymethylfurfural was found (we believe such a small concentration could not great effect to the growth of bacteria). It is not so ideal to use this solution to product the C2H6O, because its sacchariede concentration was too low; but the solution was favorable as proliferation of yeast for seeding emulsion, after addition of nitration like yeast powder or peptone. By repeating this pretreatment process, the lignin and sacchariede could be recovered, purpose of full utilization of raw materials was achieved, in addition, no waste emission was issued.
3Â¥2013-07-26 17:53:49
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