| 查看: 271 | 回复: 3 | |||
| 【奖励】 本帖被评价2次，作者xhyu增加金币 2 个 | |||
| 当前主题已经存档。 | |||
[资源]
Advanced supporting anodes for Sollid(要变金虫了,大家多支持!)
|
|||
|
Advanced supporting anodes for Solid Oxide Fuel Cells Three different ceramic materials for nickel-cermet anodes have been used to prepare and characterise supporting anodes for Solid Oxide Fuel Cells. Symmetrical cells with nominally identical supporting anodes were prepared and electrochemically tested. The three different cermets were nickel/yttria stabilised zirconia (YSZ), nickel/gadolinium doped ceria (CGO) and nickel/titania and yttria doped zirconia (YZT). The Ni/YSZ anodes contained different ratios of fine and coarse YSZ. Their polarisation resistances varied from 2.0 – 7.4 Ωcm2; the resistance increased with an increasing amount of coarse YSZ. The anodes suffered a lot from degradation, which makes a good analysis and comparison of the measurement data hard. Therefore it is hard to ascribe the impedances to certain electrochemical processes. The lowest polarisation resistance was found for the Ni/CGO anodes, with a polarisation resistance of 1.1 Ωcm2. In the first place, the fine microstructure plays an important role for the relatively low impedance. Secondly, the stability of this anode in contrast to the other materials is thought to be due to the high purity powder that was used. From the electrochemical characterisation, it is believed that an adsorption process and oxidation/reduction of the ceria cause the main impedances. The last material, Ni/YZT, performed a bit worse than the Ni/YSZ anodes. The impedances of these Ni/YZT anodes were fitted with a Finite Length Fractal Gerischer, resulting in consistent fit data. This Gerischer describes a diffusion process coupled to a side reaction, which limits the amount of diffusing species. A proper electrochemical explanation has yet to be formulated, but the mixed ionic and electronic conductivity of YZT is almost certainly involved. In any case, the total polarisation impedances for this material amounted 5.9 – 10 Ωcm2. Like the Ni/YSZ anodes, the impedance decreased with an increasing amount of fine YZT. page 74 It is good for material majors! http://rs175l3.rapidshare.com/cg ... =352603312628556130 [ Last edited by xhyu on 2007-10-23 at 17:41 ] |
回复此楼» 猜你喜欢
(出分啦!!!)26 考研调剂 20w+调剂信息火速更新中！【捡漏】qq 群：1087823172
已经有79人回复
-
085600材料工程一志愿中科大总分312求调剂
已经有6人回复
-
311求调剂
已经有6人回复
-
高分子化学与物理调剂
已经有4人回复
-
化工专硕348，一志愿985求调剂
已经有5人回复
-
博士自荐
已经有3人回复
-
求环氧树脂研发1名
已经有11人回复
-
博士推荐
已经有5人回复
-
0856材料求调剂
已经有9人回复
-
285求调剂
已经有3人回复
2楼2007-10-23 21:54:33
3楼2007-10-24 07:42:08
