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[资源] Polymer nanocomposites

http://file.mofile.com 0845111547162075

Contributor contact details xiii
Preface xvii
Part I Layered silicates
1 Polyamide/clay nanocomposites 3
M KATO and A USUKI, Toyota Central R&D Labs Inc., Japan
1.1 Introduction 3
1.2 Nylon 6-clay hybrid (NCH) 4
1.3 Synthesis of nylon 6-clay hybrid (NCH) 4
1.4 Characterization of NCH 6
1.5 Crystal structure of NCH (Kojima, 1995) 12
1.6 Properties of NCH (Kojima, 1993a) 19
1.7 Synthesizing NCH using different types of clay (Usuki, 1995) 21
1.8 Improving the synthesis method of NCH 23
1.9 Other types of nylon 24
1.10 Conclusions 26
1.11 Future trends 27
1.12 References 27
2 Epoxy nanocomposites based on layered silicates
and other nanostructured fillers 29
O BECKER and G P SIMON, Monash University, Australia
2.1 Introduction 29
2.2 Epoxy-layered silicate nanocomposites 31
2.3 Epoxy-nanocomposites based on other nanofillers 47
2.4 Ternary epoxy nanocomposite systems 48
2.5 Future trends 53
2.6 References 54
Contents
3 Biodegradable polymer/layered silicate
nanocomposites 57
S SI N H A RA Y and M BO U SMI N A , Laval University, Canada
3.1 Introduction 57
3.2 Definition and categories of biodegradable polymers 58
3.3 Properties and drawbacks of biodegradable polymers 59
3.4 Polymer/layered silicate nanocomposite technology 59
3.5 Structure and properties of layered silicates 62
3.6 Techniques used for the characterization of nanocomposites 63
3.7 Biodegradable polymers and their nanocomposites 64
3.8 Properties 86
3.9 Biodegradability 101
3.10 Melt rheology and structure-property relationship 106
3.11 Foam processing of biodegradable nanocomposites 115
3.12 Conclusions 117
3.13 Acknowledgements 119
3.14 References 119
4 Polypropylene layered silicate nanocomposites 130
K JA Y A R AMA N and S KUMA R , Michigan State University,
USA
4.1 Introduction 130
4.2 Chemical compatibilization and compounding 131
4.3 Nanostructure 134
4.4 Performance 142
4.5 Conclusions 147
4.6 Acknowledgments 147
4.7 References 147
5 Polystyrene/clay nanocomposites 151
D-R YE I , H-K FU and F-C CH A N G , National Chiao-Tung
University, Taiwan
5.1 Introduction 151
5.2 Organically modified clay 152
5.3 Surface-initiated polymerization (SIP) 155
5.4 Syndiotactic polystyrene (s-PS)/clay nanocomposite 160
5.5 Properties of nanocomposites 163
5.6 Conclusions 169
5.7 References 169
vi Contents
6 Poly(ethyl acrylate)/bentonite nanocomposites 172
T TA N G , X TO N G , Z FE N G and B HU A N G , Chinese
Academy of Sciences, People's Republic of China
6.1 Introduction 172
6.2 Materials and characterization 174
6.3 Synthesis of PEA/bentonite nanocomposites through in situ
emulsion polymerization 175
6.4 Preparation and microstructure of casting-film of PEA/bentonite
nanocomposites from emulsion 176
6.5 Performance of PEA/bentonite nanocomposites 179
6.6 Conclusions and future trends 184
6.7 Acknowledgments 185
6.8 References 186
7 Clay-acrylate nanocomposite photopolymers 188
C DE C K E R , UniversiteÂ de Haute-Alsace, France
7.1 Introduction 188
7.2 Synthesis of clay-acrylate nanocomposites 190
7.3 Properties of clay-acrylic nanocomposites 195
7.4 Conclusions 202
7.5 References 203
8 Nanocomposites based on water soluble polymers
and unmodified smectite clays 206
K E ST R AWH E C K E R , Veeco Instruments Inc, USA and
E MA N I A S , The Pennsylvania State University, USA
8.1 Introduction 206
8.2 Dispersion of Na+ montmorillonite in water soluble polymers 207
8.3 Crystallization behavior 211
8.4 Overview of nanocomposite structure and crystallization
behavior 221
8.5 Materials properties of poly(vinyl alcohol)/Na+ montmorillonite
nanocomposites 222
8.6 Conclusions 231
8.7 References 231
9 Poly(butylene terephthlate) (PBT) based
nanocomposites 234
C-S HA , Pusan National University, Korea
9.1 Introduction 234
9.2 Impact modification of PBT by blending 235
Contents vii
9.3 PBT/organoclay nanocomposite 239
9.4 EVA/organoclay nanocomposite 242
9.5 PBT/EVA-g-MAH/organoclay ternary nanocomposite 247
9.6 Conclusions 251
9.7 Acknowledgments 254
9.8 References 254
10 Flammability and thermal stability of polymer/
layered silicate nanocomposites 256
M ZA N E T T I , University of Turin, Italy
10.1 Introduction 256
10.2 Nanocomposites and fire 257
10.3 Flame retardant mechanism 257
10.4 Nanocomposites and conventional flame retardants 265
10.5 Conclusion and future trends 267
10.6 References 268
11 Barrier properties of polymer/clay nanocomposites 273
A SO R R E N T I N O , G GO R R A S I , M TO R T O R A and
V VI T T O R I A , University of Salerno, Italy
11.1 Introduction 273
11.2 Background on polymer barrier properties 273
11.3 Experimental methods 277
11.4 Permeation and diffusion models relevant to polymer
nanocomposites 279
11.5 Polymer nanocomposites diffusivity 282
11.6 Polymer nanocomposites sorption 286
11.7 Polymer nanocomposites permeability 287
11.8 Conclusions and future trends 291
11.9 References 292
12 Rubber-clay nanocomposites 297
A MO H AMMA D and G P SIMO N , Monash University, Australia
12.1 Introduction 297
12.2 Overview of rubbers (elastomers) 297
12.3 Fillers predominantly used in the rubber industry 302
12.4 Rubber crosslinking systems 304
12.5 Types of rubber-clay nanocomposite structure 305
12.6 Comparison of properties achieved in rubber-clay nanocomposites 317
12.7 Conclusions 321
12.8 References 322
viii Contents
Part II Nanotubes, nanoparticles and inorganic-organic hybrid
systems
13 Single-walled carbon nanotubes in epoxy
composites 329
K LI A O and Y RE N , Nanyang Technological University,
Singapore and T XI A O , Shantou University, People's
Republic of China
13.1 Introduction 329
13.2 Mechanical properties: elastic properties and strength 331
13.3 Carbon nanotube ± polymer interface 337
13.4 Long-term performance of unidirectional CNT/epoxy
composites 346
13.5 Conclusions 353
13.6 References 354
14 Fullerene/carbon nanotube (CNT) composites 359
T KU Z UMA K I , The University of Tokyo, Japan
14.1 Introduction 359
14.2 Fabrication of the composite by the drawing process 362
14.3 Fabrication of the composite by ultra high-pressure sintering 372
14.4 Application potential 378
14.5 Conclusions 386
14.6 References 386
15 Filled polymer nanocomposites containing
functionalized nanoparticles 389
O OK PA R K , J H PA R K and T-H KIM, Korea Advanced
Institute of Science and Technology, Korea and Y T LIM,
Korea Research Institute of Bioscience and Biotechnology,
Korea
15.1 Introduction 389
15.2 Organic and polymer materials for light-emitting diodes 389
15.3 Luminescent polymer for device applications 391
15.4 Photo-oxidation of emitting polymers 393
15.5 Nanoparticles approaches to enhance the lifetime of emitting
polymers 396
15.6 Conclusions and future trends 409
15.7 References 409
Contents ix
16 Polymer/calcium carbonate nanocomposites 412
X LU , Nanyang Technological University, Republic of
Singapore and T LI U , Institute of Advanced Materials,
People's Republic of China
16.1 Introduction 412
16.2 Preparation and surface modification of nano-CaCO3 413
16.3 Fabrication of polymer/CaCO3 nanocomposites 417
16.4 Characterization 420
16.5 Applications 433
16.6 Conclusion and future trends 434
16.7 References 435
17 Magnetic polymer nanocomposites 440
A MI L L A N and F PA L A C I O , University of Zaragoza, Spain
and E SN O E C K , V SE R I N and P LE C A N T E , CEMES-CNRS,
France
17.1 Introduction 440
17.2 Classification of magnetic polymer nanocomposites 442
17.3 Synthesis 447
17.4 Characterization 455
17.5 Magnetic properties 466
17.6 Future trends 470
17.7 References 471
18 Phenolic resin/SiO2 organic-inorganic hybrid
nanocomposites 485
C-L CH I A N G , Hung-Kuang University, Taiwan and
C-C M MA , National Tsing-Hua University, Taiwan
18.1 Introduction 485
18.2 Experimental 487
18.3 Results when IPTS was used as a coupling agent 493
18.4 Results when GPTS was used as a coupling agent 500
18.5 Conclusions 506
18.6 References 507
19 Polymer/graphite nanocomposites 510
Y ME N G , Sun Yat-Sen University, People's Republic of China
19.1 Introduction 510
19.2 Features of graphite 511
19.3 Structures of polymer/graphite nanocomposites 519
19.4 Preparations of polymer/graphite nanocomposites 520
x Contents
19.5 Properties 529
19.6 Conclusions 532
19.7 Acknowledgments 533
19.8 References 533
20 Wear resisting polymer nanocomposites:
preparation and properties 540
M Q ZH A N G and M Z RO N G , Zhongshan University, People's
Republic of China and K FR I E D R I C H , Institute for Composite
Materials (IVW), Germany
20.1 Introduction 540
20.2 Surface treatment 542
20.3 Composites manufacturing 548
20.4 Wear performance and mechanisms 558
20.5 Conclusions and future trends 568
20.6 Acknowledgements 570
20.7 References 570
Index 578

[ Last edited by majunying81 on 2007-10-8 at 20:23 ]

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