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1 . ethyl (S)-N-tert-butoxycarbonylvalyl-(2e,4S)-N-methyl-4-amino-2,5-dimethylhex-2-enoate C22H40N2O5 ÏàËÆ¶È:55% Journal of Natural Products 2003 66 183-199 Synthesis and Antimitotic/Cytotoxic Activity of Hemiasterlin Analogues James A. Nieman, John E. Coleman, Debra J. Wallace, Edward Piers, Lynette Y. Lim, Michel Roberge, and Raymond J. Andersen Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 2 . ethyl (S)-N-tert-butoxycarbonyl-2-aminobutanoyl-(2e,4S)-N-methyl-4-amino-2,5-dimethylhex-2-enoate C21H38N2O5 ÏàËÆ¶È:52.9% Journal of Natural Products 2003 66 183-199 Synthesis and Antimitotic/Cytotoxic Activity of Hemiasterlin Analogues James A. Nieman, John E. Coleman, Debra J. Wallace, Edward Piers, Lynette Y. Lim, Michel Roberge, and Raymond J. Andersen Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 3 . 1,6-dimethyl-1,2,3,4-tetrahydro-5-(oxomethylene ethyl carboxyl)-naphthalene C16H22O3 ÏàËÆ¶È:52.9% Natural Product Research 2006 20 629-635 Alternative procedure for the synthesis of Mansonone F and Biflorin precursor Po S. Poon; ng Ajoy k. Banerjee Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 4 . cis-2-[2-(Tetrahydropyranyl-2-oxy) ethyl] 3-methyl oxirane C10H18O3 ÏàËÆ¶È:52.9% Bioorganic & Medicinal Chemistry 1996 4 1065-1075 Synthesis and biochemical properties of Z- and E-4,5-dehydrodethiobiotin Eric Jestin, François Moreau, Dominique Florentin, Andr¨¦e Marquet Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 5 . compound 2 C21H33N7O5 ÏàËÆ¶È:52.9% Bioorganic & Medicinal Chemistry 2000 8 2681-2687 Regioselective enzymatic aminoacylation of lobucavir to give an intermediate for lobucavir prodrug Ronald L Hanson, Zhongping Shi, David B Brzozowski, Amit Banerjee, Thomas P Kissick, Janak Singh, Annie J Pullockaran, Jeffrey T North, Junying Fan, Jeffrey Howell, Susan C Durand, Michael A Montana, David R Kronenthal, Richard H Mueller, Ramesh N Patel Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 6 . N,N',N''-[(SSS)-Nitrilotris[2-benzoylamino)-1-oxo-2,1-ethandiyl]]tris-[L-valyl-L-histidine] trimethyl ester C63H78N16O15 ÏàËÆ¶È:52.9% Bioorganic & Medicinal Chemistry 1999 7 699-707 Zinc(II) complexes of tripodal peptides mimicking the zinc(II)-coordination structure of carbonic anhydrase Ulrike Herr, Werner Spahl, Gunter Trojandt, Wolfgang Steglich, Florian Thaler, Rudi van Eldik Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 7 . octadeca-8,10,12-triynoic acid C18H24O2 ÏàËÆ¶È:50% Journal of Natural Products 1998 61 422-427 New Acetylenes Isolated from the Bark of Heisteria acuminata Christina M. Kraus, Andr¨¢s Neszm¨¦lyi, S¨¢ndor Holly, Beate Wiedemann, Anneli Nenninger, Kurt B. G. Torssell, Lars Bohlin, and Hildebert Wagner Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 8 . phthalic acid,butyl isobuty ester ÏàËÆ¶È:50% China Journal of Chinese Materia Medica 2007 32 1295-1298 Studies on Chemical Constituents of Phlomis medicinalis II YU Zhenxi, WANG Gangli, DAI Zhong, BLANBA Ciren, LIN Ruichao Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 9 . compound 8 ÏàËÆ¶È:50% Fitoterapia 2009 80 21-24 Sesquiterpene lactones from Carpesium abrotanoides Fei Wang , Ku Yang , Fu-Cai Ren , Ji-Kai Liu Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 10 . Compound 10b C17H32O4Si ÏàËÆ¶È:50% Tetrahedron Letters 2012 53 829-832 An enantiodivergent formal synthesis of paecilomycine A Goverdhan Mehta,Ramesh Samineni,Pabbaraja Srihari Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 11 . octadeca-8,10,12-triynoic acid ÏàËÆ¶È:50% Organic letters 2001 3 819-821 Synthesis of Polyacetylenic Acids Isolated from Heisteria acuminata Gilson Zeni,* Rodrigo B. Panatieri, Eliseo Lissner, Paulo H. Menezes, Antonio L. Braga, and H¨¦lio A. Stefani Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 12 . trans-4-acetyl-3-(4-chlorophenyl)-5-methyl-2,3-dihydrofuran-2,4-dicarboxylic acid diethyl ester ÏàËÆ¶È:50% Journal of Heterocyclic Chemistry 2010 47 671-676 A facile synthesis of tetrasubstituted 2,3-dihydrofuran derivatives using poly(ethylene glycol) as soluble support Chun Feng, Cuifen Lu, Zuxing Chen, Nianguo Dong, Jiawei Shi and Guichun Yang Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 13 . N-((3S)-4-hydroxy-2-methylhex-5-yn-3-yl)benzamide C14H17NO2 ÏàËÆ¶È:50% Heterocycles 2006 67 215-232 Tandem Palladium-catalyzed Allene Arylation and Oxazoline Formation Gregory R. Cook* and Wei Xu Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 14 . phthalic acid,butyl isobutyl ester ÏàËÆ¶È:50% Chinese Pharmaceutical Journal 2007 42 1295-1298 Studies on Chemical Constituents of Phlomis medicinalis ¢ò YU Zhen-xi, WANG Gang-li, DAI Zhong, BIANBA Ci-ren, LIN Rui-chao Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 15 . phthalic acid butyl isobutyl ester ÏàËÆ¶È:50% Natural Product Research and Development 2009 21 916-918 Studies on the Secondary Metabolites of Endophytic Fungus Epicoccum sp. Isolated from Azadirachta indica WANG Li-dong; WU Shao-hua; CHEN You-wei; YU Ying; YANG Li-yuan; LI Shao-lan; LI Zhi-ying Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 16 . 27-nor-24-methylcholesta-4,22E-dien-16¦Â,18,20¦Î-triol-3-one ÏàËÆ¶È:50% Experientia 1984 40 246-248 C-18 hydroxy steroids from the Mediterranean gorgonianLeptogorgia sarmentosa G. Cimino, S. De Rosa, S. De Stefano and G. Sodano Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 17 . compound 3a C21H36O6 ÏàËÆ¶È:50% The Journal of Antibiotics 1982 35 1480-1494 STUDIES ON MACROCYCLIC LACTONE ANTIBIOTICS. VI SKELETAL STRUCTURE OF COPIAMYCIN KAZUTAKA FUKUSHIMA, TADASHI ARAI, SHIGEO IWASAKI, MICHIO NAMIKOSHI, SHIGENOBU OKUDA Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 18 . compound 33 C16H22O2 ÏàËÆ¶È:50% European Journal of Organic Chemistry 2011 3146-3155 Intramolecular Butenolide Allene Photocycloadditions and Ensuing Retro-Ene Reactions of Some Photoadducts Ginger Lutteke, Roel A. Kleinnijenhuis, Ivo Jacobs, Pauli J. Wrigstedt, Ana C. A. Correia, Rowan Nieuwenhuizen, B. T. Buu Hue, Kees Goubitz, Ren¨¦ Peschar, Jan H. van Maarseveen and Henk Hiemstra Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 19 . (2R,3R)-5-(hydroxymethyl)-1-(2-nitrophenylsulfonyl)-2-propyl-1,2,3,6-tetrahydropyridin-3-ol C15H20N2O6S ÏàËÆ¶È:50% Heterocycles 2012 84 929-944 Asymmetric Synthesis of 2-Propylisofagomine Using Allylic Hydroxy Group Accelerated Ring-Closing Enyne Metathesis Tatsuya Taguchi, Tatsushi Imahori, Yuichi Yoshimura, Atsushi Kato, Isao Adachi, Masatoshi Kawahata, Kentaro Yamaguchi, and Hiroki Takahata Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 20 . (E)-2,3-diethyl-4-heptylidenecyclopent-2-enone C16H26O ÏàËÆ¶È:50% European Journal of Organic Chemistry 2010 3312-3336 Pauson¨CKhand Reaction of Allenic Hydrocarbons: Synthesis of 4-Alkylidenecyclopentenones Fr¨¦d¨¦ric Antras, St¨¦phane Laurent, Mohammed Ahmar, Henry Chermette and Bernard Cazes Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 21 . tert-butyl (S)-1-((S)-1-hydroxy-3-methylbutan-2-ylamino)-3-methyl-1-oxobutan-2-ylcarbamate C15H30N2O4 ÏàËÆ¶È:50% Tetrahedron 2012 68 10114-10121 An efficient entry to highly substituted chiral 2-oxopiperazines from ¦Á-amino acids via iodocyclization Amit Kumar Jana, Sanjit Kumar Das, Gautam Panda Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 22 . compound 9 C12H20O4 ÏàËÆ¶È:50% Angewandte Chemie International Edition 2002 41 4098-4101 Total Synthesis of Leucascandrolide A Alec Fettes and Erick M. Carreira Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 23 . 15¦Á-Butoxy-14,15-dihydronorsecurinine C16H23NO3 ÏàËÆ¶È:50% Natural Product Communications 2006 1 819-823 Alkaloids from the Root of Flueggea Virosa Li-She Gan and Jian-Min Yue Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 24 . Triisopropylsiloxymethyl 15-Triisopropylsiloxypentadecanoate C34H72O4Si2 ÏàËÆ¶È:50% Chemical & Pharmaceutical Bulletin 2012 60 1334-1339 A New Method for the Protection of Carboxylic Acids with a Triisopropylsiloxymethyl Group Hikaru Yoshimura, Kohei Eto, Keisuke Takahashi, Jun Ishihara, Susumi Hatakeyama Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 25 . 1,4-benzenedicarboxylic acid 1-butyl-4-(2-methylpropyl) ester C16H22O4 ÏàËÆ¶È:50% Acta Pharmaceutica Sinica 2012 47 1179-1182 A new monoterpenoid glucoside from the twigs of Chamaecyparis obtusa var.breviramea f.crippsii XU Jian; ZHANG Yu-mei; CHEN Ke-li; TAN Ning-hua; LIU Yi-mei Structure 13C NMR ̼Æ×Ä£Äâͼ -------------------------------------------------------------------------------- 26 . butyl isobutyl phthalate C16H22O4 ÏàËÆ¶È:50% Chinese Traditional and Herbal Drugs 2012 43 653-657 Chemical constituents in twigs and leaves of Melodinus fusiformis WANG Ding-wei; LUO Xiao-dong; JIANG Bei Structure 13C NMR ̼Æ×Ä£Äâͼ |

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