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对天空说lrj

金虫 (正式写手)

[求助] 请高手帮忙翻译两句化学材料方面的英文

Of the t2g set of orbitals, the 3dxz and 3dyz
orbitals point in between the ligands and are involved in π
interactions. Since these interactions are weaker, the unfilled
antibonding π* states lie closer to the Fermi level at relatively
lower energies in the conduction band (correspondingly, the
filled π states lie higher in energy in the valence band).请高手解释一下,

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huangzx1314

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对天空说lrj: 金币+5, 翻译EPI+1 2013-05-05 19:37:34
固体物理中的比较专业,不懂。

Of the t2g set of orbitals, the 3dxz and 3dyz orbitals point in between the ligands and are involved in π interactions. Since these interactions are weaker, the unfilled antibonding π* states lie closer to the Fermi level at relatively lower energies in the conduction band (correspondingly, the filled π states lie higher in energy in the valence band)

配体之间的t2g轨道中,3dyz和3dxz轨道和参与π键的交互作用。由于这一交互作用比较弱,在导带中位于低能区的未饱和反π* 键接近费米能级(也就是说,在价带中的饱和的π 键位于较高能级)。
2楼2013-05-05 15:10:27
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