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Ó´Ó´william

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Fig. 1 compares the X-ray diffraction (XRD) patterns of the
pure sulfur, sulfur¨Ccarbon composite, and carbon black. The Super
P carbon black, showing no sharp crystalline peaks, has amorphous
structure. The pure sulfur and sulfur¨Ccarbon composite
exhibit peaks perfectly matching with those of pure orthorhombic
sulfur (JCPDS 00-008-0247). The sulfur¨Ccarbon composite
shows much higher peak intensities than the pure sulfur as
the dispersed nanoparticles of carbon black act as numerous
deposition sites for elemental sulfur, leading to a favorable
precipitation environment. This in situ sulfur deposition route
thus provides an efficient means to produce high-purity sulfur
composites.


The microstructure of the carbon black, pure sulfur, and
sulfur¨Ccarbon composite is shown in Fig. 2. The particle size
of spherical carbon black is less than 100 nm. The pure sulfur
contains glue-like particles with a diameter of few microns.
Fig. 2(c) presents the structure of the sulfur¨Ccarbon composite
in which sulfur particles are uniformly distributed throughout
the network structure formed by carbon black. Carbon black partially
embeds in the sulfur, and the remainder wraps around the
matrix sulfur as a protective layer. This network structure confirms
close contact between the conductive carbon and sulfur,
providing not only excellent electron pathways for the insulating
sulfur but also many adsorbent points to avoid the loss of
the soluble polysulfides into the electrolyte. The TEM images in
Fig. 3(a) and (b) show that the carbon black nanoparticles in the
sulfur¨Ccarbon composite are chain-like, which effectively enhances
the conductivity of the composite material [13]. The elemental
analysis of the sulfur¨Ccarbon composite carried out by EDS is
shown in Fig. 3(c), demonstrating the existence of both sulfur and
carbon.

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Ó´Ó´william

ľ³æ (СÓÐÃûÆø)

ÒýÓûØÌû:
2Â¥: Originally posted by ´óè1860 at 2013-04-25 08:30:08
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3Â¥2013-04-25 10:20:35
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ruiyuan121

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Ó´Ó´william: ½ð±Ò+20, ·­ÒëEPI+1, ¡ïÓаïÖú 2013-04-25 13:17:06
Ó´Ó´william: ½ð±Ò+30, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, ´óÉñ£¬°ïÎÒÆäËûµÄÇóÖúÌùÒ²·­Òëϰ¡£¬ÕâÆªÂÛÎÄÊÇÄãµÄÇ¿Ïî°¡ 2013-04-26 18:28:41
Fig. 1 compares the X-ray diffraction (XRD) patterns of the pure sulfur, sulfur¨Ccarbon composite, and carbon black.
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The Super P carbon black, showing no sharp crystalline peaks, has amorphous structure.
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The pure sulfur and sulfur¨Ccarbon composite exhibit peaks perfectly matching with those of pure orthorhombic sulfur (JCPDS 00-008-0247).
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The sulfur¨Ccarbon composite shows much higher peak intensities than the pure sulfur as the dispersed nanoparticles of carbon black act as numerous deposition sites for elemental sulfur, leading to a favorable precipitation environment.
ÓÉÓÚÌ¿ºÚÖзÖÉ¢µÄÄÉÃ׿ÅÁ£ÎªÁòÔªËØÌṩÁË´óÁ¿µÄ³Á»ý³¡Ëù£¬¹¹³ÉÁËÒ»¸öÁ¼ºÃµÄ³Á»ý»·¾³¡£Ì¼Áò¸´ºÏÎïµÄ·å±È´¿ÁòµÄ·åֵǿ¶È¸ü¸ß¡£
This in situ sulfur deposition route thus provides an efficient means to produce high-purity sulfur composites.
Òò´ËÁòµÄÕâÖ־͵سÁ»ý·½Ê½ÎªÉú²ú¸ß´¿¶È¸´ºÏÁòÌṩÁËÒ»ÖÖºÜÓÐЧµÄ·½·¨¡£

The microstructure of the carbon black, pure sulfur, and sulfur¨Ccarbon composite is shown in Fig. 2.
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The particle size of spherical carbon black is less than 100 nm.
ÇòÐÎÌ¿ºÚµÄ¿ÅÁ£´óС²»×ã100ÄÉÃס£
The pure sulfur contains glue-like particles with a diameter of few microns.
´¿ÁòÖк¬ÓÐÖ±¾¶Îª¼¸Î¢Ã׵Ľº×´¿ÅÁ£¡£
Fig. 2(c) presents the structure of the sulfur¨Ccarbon composite in which sulfur particles are uniformly distributed throughout the network structure formed by carbon black.
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Carbon black partially embeds in the sulfur, and the remainder wraps around the matrix sulfur as a protective layer.
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This network structure confirms close contact between the conductive carbon and sulfur, providing not only excellent electron pathways for the insulating sulfur but also many adsorbent points to avoid the loss of the soluble polysulfides into the electrolyte.
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The TEM images in Fig. 3(a) and (b) show that the carbon black nanoparticles in the sulfur¨Ccarbon composite are chain-like, which effectively enhances
the conductivity of the composite material [13].
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The elemental analysis of the sulfur¨Ccarbon composite carried out by EDS is shown in Fig. 3(c), demonstrating the existence of both sulfur and carbon.
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Ó´Ó´william

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ľ³æ (СÓÐÃûÆø)

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8Â¥: Originally posted by ´óè1860 at 2013-04-26 17:41:34
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9Â¥2013-04-26 17:44:25
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