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Zhong Lin Wang - Nanowires and Nanobelts: Materials, Properties and Devices: Volume 2: Nanowires and Nanobelts of Functional Materials
Springer | Published: 2005-09-29 | ISBN: 038728706X | PDF | 313 pages | 20 MB


Volume 2, Nanowires and Nanobelts of Functional Materials covers a wide range of materials systems, from functional oxides (such as ZnO, SnO2, and In2O3), structural ceramics (such as MgO, SiO2 and Al2O3), composite materials (such as Si-Ge, SiC- SiO2), to polymers. This volume focuses on the synthesis, properties and applications of nanowires and nanobelts based on functional materials. Novel devices and applications made from functional oxide nanowires and nanobelts will be presented first, showing their unique properties and applications. The majority of the text will be devoted to the synthesis and properties of nanowires and nanobelts of functional oxides. Finally, sulphide nanowires, composite nanowires and polymer nanowires will be covered.

Contents
Preface ix
List of Contributors xi
I. Nanodevices Based on Nanowires and Nanobelts
Chapter 1. Nanodevice, Nanosensors and Nanocantilevers Based on
Semiconducting Oxide Nanobelts (Zhong Lin Wang) 3
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
2. Field-Effect Transistor Based on Single Nanobelts . . . . . . . . 3
3. Oxygen Sensor Using a Single Nanobelt . . . . . . . . . . . . . . . . 8
4. Photoconductivity of Nanobelts . . . . . . . . . . . . . . . . . . . . . . . 8
5. Gas Sensors Based on Nanobelts . . . . . . . . . . . . . . . . . . . . . . 9
6. Heat Transport Through Nanobelt . . . . . . . . . . . . . . . . . . . . . 11
7. Nanobelt as Nanoresonators . . . . . . . . . . . . . . . . . . . . . . . . . 11
8. Nanobelts as Nanocantilever . . . . . . . . . . . . . . . . . . . . . . . . . 13
9. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Chapter 2. Oxide Nanowires and Nanolasers (Peidong Yang and
Haoquan Yan) 21
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
2. Synthesis and Characterization of ZnO Nanowires . . . . . . . . 23
3. Controlled Growth of ZnO Nanowires . . . . . . . . . . . . . . . . . . 25
4. Photoluminescence and Lasing Properties . . . . . . . . . . . . . . . 29
5. Nonlinear Optical Mixing in Single Zinc Oxide Nanowires . . 35
6. Photoconductive Oxide Nanowires as Nanoscale
Optoelectronic Switches . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
7. Room Temperature NO2 Photochemical Sensing . . . . . . . . . . 39
8. Conclusions and Outlook . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
II. Functional Oxide Nanowires and Nanobelts
Chapter 3. Nanobelts and Nanostructures of Transparent
Conducting Oxides (Zhong Lin Wang) 47
1. Synthesis Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
2. Oxide Nanobelts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
3. Synthesis of New Materials using Nanobelts as Template . . . 56
4. Complex Nanobelt Structures . . . . . . . . . . . . . . . . . . . . . . . . 59
5. Nanosheets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
6. Nanodiskettes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
7. Planar Defects in Oxide Nanobelts . . . . . . . . . . . . . . . . . . . . 67
8. Growth Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
9. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Chapter 4. Nanomechanics and Mechanical Behavior of
Nanobelts (Scott X. Mao) 73
1. Nanomechanical Behavior of Semiconducting
Zinc Oxide Single Nanobelt . . . . . . . . . . . . . . . . . . . . . . . . . 73
2. Bending and Cutting on Nanorodes, Nanotube
and Nanobelt Using AFM Tip . . . . . . . . . . . . . . . . . . . . . . . . 75
3. Bending and Fundamental Resonance Frequency
of Nanotube Under TEM . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
4. Electromechanical Behavior of Carbon Nanotube . . . . . . . . . 78
5. Revolutionary Nanowires with a Twist . . . . . . . . . . . . . . . . . 80
Chapter 5. Ferroelectric Nanowires (Jonathan E. Spanier,
Jeffrey J. Urban, Lian Ouyang, Wan Soo Yun and Hongkun Park) 83
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
2. Synthesis of BaTiO3 and SrTiO3 Nanowires . . . . . . . . . . . . . 84
3. Scanned Probe Measurements of BaTiO3 Nanowires . . . . . . . 87
4. Conclusion and Future Prospects . . . . . . . . . . . . . . . . . . . . . . 91
Chapter 6. Growth of Oxide Nanorods through Sol
Electrophoretic Deposition (Steven J. Limmer and Guozhong Cao) 93
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
2. Sol¨CGel Processing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
3. Electrophoretic Deposition . . . . . . . . . . . . . . . . . . . . . . . . . . 97
4. Experimental . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
5. Various Oxide Nanorods . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
6. Concluding Remarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110
Chapter 7. Nanowires of Functional Oxides (Guanghou Wang) 113
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
2. From Nanoclusters to Nanowires of Titanium Oxides . . . . . . 114
3. Layered Structures of Potassium Hexatitanate
Nanowhisker . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
4. Rutile Stannic Oxide Nanorods . . . . . . . . . . . . . . . . . . . . . . . 127
5. Cu2O Nanowires . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130
6. V2O5 Nanofibres . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
7. Potential Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
Chapter 8. Controlled Growth and Optical Properties of Zinc Oxide
Nanostructures (Yue Zhang and Ying Dai) 139
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
2. Experimental . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140
3. Nanostructures of ZnO . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140
4. Growth Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148
5. Optical Properties of ZnO Nanostructures . . . . . . . . . . . . . . . 153
6. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154
Chapter 9. One-Step Hydrothermal Synthesis and
Characterizations of Titanate Nanostructures (L.-M. Peng, Q. Chen,
G. H. Du, S. Zhang and W. Z. Zhou) 157
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
2. Experimental Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . 158
3. Structural Characterization . . . . . . . . . . . . . . . . . . . . . . . . . . 159
4. Growth Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
5. Electric and Optical Properties . . . . . . . . . . . . . . . . . . . . . . . 169
6. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170
Chapter 10. Nanowires and Nanotubes of Complex Oxides
(Xun Wang, Xiaoming Sun, Jian Xu and Yadong Li) 173
1. Oxides of Nanowires Based on Vapor-Transport Method . . . . 174
2. Template-Confined Method to Oxides of Nanowires . . . . . . . 175
3. Solution-Based Synthetic Way to Oxides 1-D
Nanostructures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176
4. Prospects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 188
Chapter 11. Silica Nanowires/Nanotubes
(Jing Zhu, W. X. Sun and Jun Luo) 191
1. Synthesis of Silica Nanowires/Nanotubes . . . . . . . . . . . . . . . 191
2. Characterization of Structures and Properties of
Silica Nanowires/Nanotubes . . . . . . . . . . . . . . . . . . . . . . . . . 197
III. Sulphide, Polymer and Composite Nanowires
Chapter 12. Sulphide Nanowires (Shihe Yang) 209
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
2. From 0D to 1D Sulphides . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
3. Growth of Sulphide Nanowires . . . . . . . . . . . . . . . . . . . . . . . 211
4. Structural, Electronic, Optical, and Transport Properties . . . . 227
5. Potential Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
6. Summary and Prospects . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
Chapter 13. Generalized Solution Synthesis of Large Arrays of
Extended and Oriented Nanowires (Jun Liu, Zhengrong R. Tian,
James A. Voigt, Matthew J. Mcdermott and Bonnie Mckenzie) 239
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239
2. General Approach . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240
3. Results and Discussions . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
4. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252
Chapter 14. Composite Nanowires (Yuegang Zhang) 257
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 257
2. Phase Separation in Multi-Elemental Nanotubes . . . . . . . . . . 257
3. Filling in Carbon Nanotubes . . . . . . . . . . . . . . . . . . . . . . . . . 261
4. Coaxial Nanocables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 264
5. Summary and Prospect of Composite Nanowires . . . . . . . . . . 266
Chapter 15. Polymer Nanowires and Nanofibers (Liming Dai and
Darrell H. Reneker) 269
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 269
2. Nanofibrillar Conducting Polymers . . . . . . . . . . . . . . . . . . . . 270
3. Template Syntheses of Polymer Nanowires . . . . . . . . . . . . . . 271
4. Syntheses of Polymer Nanowires at a Scanning
Microscope Tip . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273
5. Electrospinning of Polymer Nanofibers . . . . . . . . . . . . . . . . . 276
6. Polymer Nanowires and Nanofibers with Special
Architectures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279
7. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 286
Published: 2005-09-29 | ISBN: 038728706X | PDF | 313 pages | 20 MB

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