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haijiaotang银虫 (正式写手)
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[求助]
求助维普
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求助以下数据的化合物，多谢！ 碳谱数据如下： 化合物1： 204.4 ，167.0， 122.2， 84.8， 78.2， 77.5， 70.2， 68.7， 68.6， 51.9， 50.62 ，50.22， 48.6， 43.1， 39.2 ，38.5， 35.0， 33.0， 32.6， 32.3， 30.6， 30.5， 27.9， 25 ，22.2， 22.0， 21.6， 18.45。溶剂为氘代吡啶。 化合物2： 202.9 ，164.6 ，120.6， 106.1， 84.3， 82.9， 81.7， 68.4 ，66.8 ，50.2， 48.6 ，49.0， 41.1 ，37.6 ，36.6 ，33.2 ，31.7 ，30.6， 30.2， 29.8， 29.1， 29.0， 26.9， 24.1， 23.4， 21.8， 20.9 ，20.2， 16.8。溶剂为DMSO. |
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wm0629
铁杆木虫 (著名写手)
- 应助: 341 (大学生)
- 金币: 6381.8
- 红花: 3
- 帖子: 1962
- 在线: 77.9小时
- 虫号: 2217415
- 注册: 2013-01-01
- 性别: GG
- 专业: 中药炮制
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感谢参与，应助指数 +1
PSA: 金币+2, 谢谢 2013-04-23 08:54:34
haijiaotang: 金币+15, ★★★很有帮助 2013-04-23 19:48:57
感谢参与，应助指数 +1
PSA: 金币+2, 谢谢 2013-04-23 08:54:34
haijiaotang: 金币+15, ★★★很有帮助 2013-04-23 19:48:57
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化合物1： 1 . 20-hydroxyecdysone 相似度:96.4% Chemistry & Biodiversity 2008 Vol. 5 707 Ecdysteroids from Vitex Species: Distribution and Compilation of Their 13C-NMR Spectral Data José G. Sena Filho, Jennifer Duringer, Gabriela L. A. Maia, Josean F. Tavares, Haroudo S. Xavier, Marcelo Sobral da Silva, Em.dio V. L. da-Cunha, and José M. Barbosa-Filho Structure 13C NMR 碳谱模拟图 2 . 20-hydroxyecdysone 相似度:96.4% Journal of Natural Products 2002 65 1194-1197 Ecdysteroids from a Zoanthus sp. Apichart Suksamrarn,Aroon Jankam, Bongkoch Tarnchompoo, and Sumaitt Putchakarn Structure 13C NMR 碳谱模拟图 3 . 20-hydroxyecdysone 相似度:96.4% Journal of Natural Products 2002 65 1690-1692 Ecdysteroids of Vitex scabra Stem Bark Apichart Suksamrarn, Saowanee Kumpun, and Boon-ek Yingyongnarongkul Structure 13C NMR 碳谱模拟图 4 . dcdysterone 相似度:96.4% Chemical & Pharmaceutical Bulletin 1994 42 1116-1122 Three New Furostanol Saponins from the Bulbs of Ipheion uniflorum Osamu NAKAMURA,Yoshihiro MIMAKI,Yutaka SASHIDA,Tamotsu NIKAIDO and Taichi OHMOTO Structure 13C NMR 碳谱模拟图 5 . 2β,3β,14α,20β,22α,25β-hexahydroxycholest-7-en-6-one 相似度:96.4% Chemistry of Natural Compounds 2007 43 672-677 SEPARATION AND IDENTIFICATION OF STEROIDAL COMPOUNDS WITH CYTOTOXIC ACTIVITY AGAINST HUMAN GASTRIC CANCER CELL LINES IN VITRO FROM THE RHIZOMES OF Paris polyphylla VAR. chinensis Huang Yun, Cui Lijian, Zhan Wenhong Dou Yuhong,Wang Yongli, Wang Qiang, and Zhao Ding Structure 13C NMR 碳谱模拟图 6 . β-Ecdysone 相似度:96.4% Journal of Asian Natural Products Research 2005 7 181-184 A new phytosterone from Achyranthes bidentata Bl DA-LI MENG, XIAN LI, JIN-HUI WANG and WEI LI Structure 13C NMR 碳谱模拟图 7 . ecdysterone 相似度:96.4% Journal of Asian Natural Products Research 2000 2 225-229 A New Phytoecdysone from the Roots of Rhaponticum uniflorum XI-QIANGLI,JIN-HUI WANG,SU-XIAN WANG and XIAN LI Structure 13C NMR 碳谱模拟图 8 . hexahydroxycholest-7-en-6-one 相似度:96.4% China Journal of Chinese Materia Medica 2007 32 500-503 Studies on chemical constituets of Cynanchum forrestii LIU Yue, LIU Jing, YU Shishan, HUANG Xiangzhong, HU Youcai Structure 13C NMR 碳谱模拟图 9 . 20-hydroxy ecdysone 相似度:96.4% China Journal of Chinese Materia Medica 2004 29 650-652 Studies on watersoluble chemical constituents in root of Achyranthes bidentata WANG Tao, CUI Shuya, SUO Yourei, LU Runhua Structure 13C NMR 碳谱模拟图 10 . 20-hydroxyecdysone 相似度:96.4% Phytochemistry 1995 38 473-476 Ecdysteroids from Vitex canescens Apichart Suksamrarn, Chatriwat Sommechai, Panuwat Charulpong, Bordin Chitkul Structure 13C NMR 碳谱模拟图 11 . 20-Hydroxyecdysone 相似度:96.4% Phytochemistry 1993 32 303-306 Ecdysteroids from Vitex pinnata Apichart Suksamrarn, Chatriwat Sommechai Structure 13C NMR 碳谱模拟图 12 . ecdysterone C27H44O7 相似度:96.4% Phytochemistry 1987 26 2505-2507 Ecdysteroids from Pfaffia iresinoides and reassignment of some 13CNMR chemical shifts Nobushige Nishimoto,Yoshinori Shiobara,Masumi Fujino,Shun-Suke Inoue,Tsunematsu Takemoto,Fernando De Oliveira,Gokithi Akisue,Maria Kubota Akisue,Goro Hashimoto,Osamu Tanaka,Ryoji Kasai,Hiromichi Matsuura Structure 13C NMR 碳谱模拟图 13 . ecdysterone 相似度:96.4% Phytochemistry 1988 27 1665-1668 Three ecdysteroid glycosides from Pfaffia iresinoides Nobushige Nishimoto,Yoshinori Shiobara,Shun-suke Inoue,Masumi Fujino,Tsunematsu Takemoto,Cheow Lin Yeoh,Fernando de Oliveira,Gokithi Akisue,Maria Kubota Akisue,Goro Hashimoto Structure 13C NMR 碳谱模拟图 14 . ecdysterone 相似度:96.4% Phytochemistry 1989 28 1073-1075 Ecdysterone from stem of Diploclisia glaucescens B.M.Ratnayake Bandara,Lalith Jayasinghe,Veranja Karunaratne,G.Percy Wannigama,Michael Bokel,Wolfgang Kraus,Subramaniam Sotheeswaran Structure 13C NMR 碳谱模拟图 15 . 20-Hydroxyecdysone 相似度:96.4% Phytochemical Analysis 2007 18 441-450 Ecdysteroids from the medicinal fern Microsorum scolopendria (Burm. f.) Eva Snogan, Isabelle Vahirua-Lechat, Raimana Ho, Gildas Bertho, Jean-Pierre Girault, Sophie Ortiga, Annick Maria and René Lafont Structure 13C NMR 碳谱模拟图 16 . ecdysterone 相似度:96.4% Chinese Traditional and Herbal Drugs 2009 40 522-525 Chemical constituents from Pfaffia paniculata GAO Hui; MA Xiao-jun; WEN Xue-sen; CHEN Di-hua; SI Jian-yong Structure 13C NMR 碳谱模拟图 17 . 20-Hydroxyecdysone 相似度:96.4% Chemistry of Natural Compounds 2010 46 738-741 Three phytoecdysteroids from Sagina japonica and potential biotransforming pathways of japonicone Aiqun Jia, Yan Li, Jun Zhou and Jinming Gao Structure 13C NMR 碳谱模拟图 18 . β-ecdysterone 相似度:96.4% Journal of Shenyang Pharmaceutical University 2007 24 207-209 Chemical constituents of Achyranthes bidentata Bl. ZHAO Wan-ting, MENG Da-li, LI Xian, LI Wei Structure 13C NMR 碳谱模拟图 19 . ecdysterone 相似度:96.4% Journal of Shenyang Pharmaceutical University 2002 19 325-327 Study on the chemical constituents of Achyranthes bidentata Bl. MENG Da-li, LI Xian, XIONG Yin-hua, WANG Jin-hui Structure 13C NMR 碳谱模拟图 20 . β-蜕皮甾酮 相似度:96.4% Journal of Shenyang Pharmaceutical University 2001 18 267-268 Constituents of phytosterone in Cyanotis arachnoidea C. B. Clarke TAN Cheng-yu, WANG Jin-hui, LI Xia, MENG Da-li, LI Xian Structure 13C NMR 碳谱模拟图 21 . ecdysterone 相似度:96.4% Journal of Shenyang Pharmaceutical University 2000 17 260-262 Phytoecdysones of Rhaponticum uniflorum (L.) DC. Li Xiqiang, Wang Jinhui, Wang Suxian, Li Xian Structure 13C NMR 碳谱模拟图 22 . 20-hydroxyecdysone 相似度:96.4% Tetrahedron 1994 50 7247-7252 New ecdysteroids from Polypodium vulgare Josep Coll, Natàlia Reixach, Francisco Sánchez-Baeza, Josefina Casas, Francisco Camps Structure 13C NMR 碳谱模拟图 23 . ecdysterone 相似度:96.4% Experientia 1982 38 1184-1185 A new, unexpected marine source of a molting hormone. Isolation of ecdysterone in large amounts from the zoanthidGerardia savaglia A. Sturaro, A. Guerriero, R. De Clauser and F. Pietra Structure 13C NMR 碳谱模拟图 24 . β-ecdysterone C27H44O7 相似度:92.8% Acta Botanica Yunnanica 2000 22(3) 351-357 Phytoecdysones from Porana discifera ZHU Wei-Ming,YANG Xiao-Sheng,HE Hong-Ping,HAO Xiao-Jiang Structure 13C NMR 碳谱模拟图 化合物2： 1 . 20-hydroxyecdysone 20,22-acetonide 相似度:93.3% Journal of Shenyang Pharmaceutical University 2006 23 702-705 Isolation and structural modif ication of 20-hydroxyecdysone YAN Jing-yu, CHENG Mao-sheng, HE Yan, LI Xian Structure 13C NMR 碳谱模拟图 2 . 2'-hydroxyecdysone 相似度:79.3% Phytochemistry 2003 1179-1184 Ecdysteroids and other constituents from Sida spinosa L. Faten M.M. Darwish, Manfred G. Reinecke Structure 13C NMR 碳谱模拟图 3 . 20-Hydroxyecdy sone C27H44O7 相似度:79.3% Chinese Journal of Natural Medicines 2008 6 186-190 Chemical Constituents of Two Original Plants Used as Radix Tinosporae SHI Qi-Rong; SHEN Yun-Heng; ZHANG Chuan; LIU Run-Hui; ZHANG Wei-Dong Structure 13C NMR 碳谱模拟图 4 . 2β,3β,14α,20β,22α,25-hexahydroxy-cholest-7-en-6-one 相似度:79.3% Chinese Pharmaceutical Journal 2006 41 1295-1297 Studies on Steroid Constituents of Achyranthes bientata Bl. LIN Da-zhuan, WANG Guang-shu, YANG Xiao-hong, XU Jing-da Structure 13C NMR 碳谱模拟图 5 . β-ecdysterone 相似度:79.3% Chinese Pharmaceutical Journal 2009 44 1287-1290 Studies on Chemical Constituents from Rhaponticum carthamoides (Willd.) Iljin HUANG Min-fang, LI Ning, NI Hui, JIA Xiao-guang*, LI Xian Structure 13C NMR 碳谱模拟图 6 . 24-(2-hydroxyethyl)-20-hydroxyecdysone 相似度:79.3% Chinese Journal of Chemistry 2002 20 497-501 Antioxidant Activity of Ecdysteroids from Serratula strangulata Jing-Qiu Dai, Yu-Jun Cai, Yan-Ping Shi, Yong-Hong Zhang, Zhong-Li Liu, Li Yang and Yu Li Structure 13C NMR 碳谱模拟图 7 . 2'-hydroxy,24-hydroxymethyl ecdysone 相似度:75.8% Phytochemistry 2003 1179-1184 Ecdysteroids and other constituents from Sida spinosa L. Faten M.M. Darwish, Manfred G. Reinecke Structure 13C NMR 碳谱模拟图 8 . 20-Hydroxyecdysone 相似度:75.8% Journal of Agricultural and Food Chemistry 2001 49 2576-2578 Ecdysteroids of Quinoa Seeds (Chenopodium quinoa Willd.) Nanqun Zhu, Hiroe Kikuzaki, Bret C. Vastano, Nobuji Nakatani, Mukund V. Karwe, Robert T. Rosen, and Chi-Tang Ho Structure 13C NMR 碳谱模拟图 9 . 2'-hydroxyecdysone-2',22-monoacetonide 相似度:73.3% Phytochemistry 2003 1179-1184 Ecdysteroids and other constituents from Sida spinosa L. Faten M.M. Darwish, Manfred G. Reinecke Structure 13C NMR 碳谱模拟图 10 . makisterone C 相似度:72.4% Phytochemistry 2003 1179-1184 Ecdysteroids and other constituents from Sida spinosa L. Faten M.M. Darwish, Manfred G. Reinecke Structure 13C NMR 碳谱模拟图 11 . 2-D-eoxy-20-hydroxy ecdysone C27H44O6 相似度:68.9% Chinese Journal of Natural Medicines 2008 6 186-190 Chemical Constituents of Two Original Plants Used as Radix Tinosporae SHI Qi-Rong; SHEN Yun-Heng; ZHANG Chuan; LIU Run-Hui; ZHANG Wei-Dong Structure 13C NMR 碳谱模拟图 12 . ponasteroside A 相似度:66.6% Phytochemistry 2010 71 975-981 Phytoecdysteroids from the rhizomes of Brainea insignis Ping Wu, Haihui Xie, Wenqin Tao, Shenyu Miao, Xiaoyi Wei Structure 13C NMR 碳谱模拟图 13 . turkesterone 相似度:65.5% Phytochemistry 2003 1179-1184 Ecdysteroids and other constituents from Sida spinosa L. Faten M.M. Darwish, Manfred G. Reinecke Structure 13C NMR 碳谱模拟图 14 . cyasterone C29H44O8 相似度:65.5% Chinese Traditional and Herbal Drugs 2004 35 978-979 川牛膝化学成分的鉴定 陈幸,黎万寿,梁溢,李彬 Structure 13C NMR 碳谱模拟图 15 . modified fusidic acid C29H44O4 相似度:62.0% The Journal of Antibiotics 1991 44 785-792 INACTIVATION OF FUSIDIC ACID BY RESISTANT Streptomyces STRAINS BEATE VON DER HAAR, DOUWE ROSENBERG, WERNER DITTRICH, HILDGUND SCHREMPF Structure 13C NMR 碳谱模拟图 16 . FAIP-1 相似度:62.0% The Journal of Antibiotics 1999 52 335-339 Inactivation of Fusidic Acid by Pathogenic Nocardia KEN-ICHI HARADA, KOJI TOMITA, KIYONAGA FUJII, NORIKO SATO, HIDEAKI UCHIDA, KATSUKIYO YAZAWA, YUZURU MIKAMI Structure 13C NMR 碳谱模拟图 17 . 2-D-eoxy-20-hydroxy ecdysone 3-O-β-D-glucopyranoside C33H54O11 相似度:60.6% Chinese Journal of Natural Medicines 2008 6 186-190 Chemical Constituents of Two Original Plants Used as Radix Tinosporae SHI Qi-Rong; SHEN Yun-Heng; ZHANG Chuan; LIU Run-Hui; ZHANG Wei-Dong Structure 13C NMR 碳谱模拟图 18 . (20R,22R)-14α,25-dihydroxy-2β,3β:20,22-bis-(isopropylidenedioxy)-5a-oxa-5a-homo-5β,8α-cholestan-6-one 相似度:60.6% Russian Journal of Organic Chemistry 2008 44 1392-1394 Regio-andstereoselectivityofperacidoxidationof20-hydroxy-2,3:20,22-di-O-isopropylidene-7,8-dihydroecdysone V. N. Odinokov, R. V. Shafikov, R. G. Savchenko, S. R. Afon’kina and A. S. Shashkov Structure 13C NMR 碳谱模拟图 19 . 3,4-seco- olean-13-en-4,7,15,22,24-pentaol-3-oic acid C30H50O7 相似度:60% Phytochemistry 2008 69 511-517 A-seco-oleane-type triterpenes from Phomopsis sp. (strain HKI0458) isolated from the mangrove plant Hibiscus tiliaceus Liya Li, Isabel Sattler, Zhiwei Deng, Ingrid Groth, Grit Walther, Klaus-Dieter Menzel, Gudrun Peschel, Susanne Grabley, Wenhan Lin Structure 13C NMR 碳谱模拟图 20 . (20R,22R)-20,22-isopropylidenedioxy-5β-cholest-8(14)ene-2β,3β,6β,25-tetraol 相似度:60% Russian Journal of Organic Chemistry 2008 44 671-674 Analogs of ecdysteroids with a tetrasubstituted Δ8,14-bond V. N. Odinokov, R. V. Shafikov, R. G. Savchenko, S. R. Afon’kina and I. V. Galyautdinov, et al. Structure 13C NMR 碳谱模拟图 21 . 9β,20-Dihydroxyecdysone C27H45O8 相似度:58.6% Steroids 2004 69 389-394 A new ecdysteroid with unique 9β-OH and four other ecdysteroids from Silene italica ssp. nemoralis András Simon, Zita Pongrácz, Gábor Tóth, Marianna Mák, Imre Máthé, Mária Báthori Structure 13C NMR 碳谱模拟图 22 . polypodine B 相似度:58.6% China Journal of Chinese Materia Medica 2005 30 272-274 Studies on chemical constituents in herb of Lamium maculatum var. kansuense DENG Yanru, DING Lan, WU Shuixian, WANG Hanqing Structure 13C NMR 碳谱模拟图 23 . Polypodine B 相似度:58.6% Chinese Pharmaceutical Journal 2006 41 1295-1297 Studies on Steroid Constituents of Achyranthes bientata Bl. LIN Da-zhuan, WANG Guang-shu, YANG Xiao-hong, XU Jing-da Structure 13C NMR 碳谱模拟图 |
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