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zhoujian6787

铁杆木虫 (著名写手)

[求助] 微谱数据求助

13C  500M  CDCl3数据如下:
16.29,17.38,18.59,21.49,22.32,23.40,23.58,25.34,25.74,28.43,30.64,31.04,32.57,32.93,33.42,33.85,36.95,37.14,37.54,42.65,43.48,44.86,45.61,48.37,61.65,69.69,75.82,128.29,169.39,200.34
谢谢
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铁杆木虫 (著名写手)

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zhoujian6787: 金币+20, ★★★★★最佳答案 2013-04-22 10:18:00
1 .     3α-hydroxy-11-oxoolean-12-en-28-oic acid
C30H46O4     相似度:86.6%
Journal of Natural Products          2006          69          142-144
Lupane and Oleanane Triterpenoids from the Cones of Liquidamber styraciflua
Yuko Fukuda, Takeshi Yamada, Shun-ich Wada, Kuniyoshi Sakai, Shunyo Matsunaga, and Reiko Tanaka
Structure      13C NMR   碳谱模拟图
2 .     krukovine A
C30H46O3     相似度:86.6%
Journal of Natural Products          1997          60          1174-1177
Partial Synthesis of Krukovines A and B, Triterpene Ketones Isolated from the Brazilian Medicinal Plant Maytenus krukovii
Tadashi Honda, Heather J. Finlay, and Gordon W. Gribble
Structure      13C NMR   碳谱模拟图
3 .     krukovine A
C30H46O3     相似度:83.3%
Journal of Natural Products          1996          59          1072-1075
Triterpenes from Brazilian Medicinal Plant “Chuchuhuasi” (Maytenus krukovii)
Osamu Shirota, Toshihiko Tamemura, Hiroshi Morita, Koichi Takeya, and Hideji Itokawa
Structure      13C NMR   碳谱模拟图
4 .     3,11-dioxoolean-12-en-28-yl acetate
C32H48O4     相似度:81.2%
Journal of Natural Products          1997          60          1174-1177
Partial Synthesis of Krukovines A and B, Triterpene Ketones Isolated from the Brazilian Medicinal Plant Maytenus krukovii
Tadashi Honda, Heather J. Finlay, and Gordon W. Gribble
Structure      13C NMR   碳谱模拟图
5 .     3,11-dioxoolean-12-en-28-oic acid
    相似度:80%
Journal of Natural Products          2006          69          142-144
Lupane and Oleanane Triterpenoids from the Cones of Liquidamber styraciflua
Yuko Fukuda, Takeshi Yamada, Shun-ich Wada, Kuniyoshi Sakai, Shunyo Matsunaga, and Reiko Tanaka
Structure      13C NMR   碳谱模拟图
6 .     11-oxo-erythrodiol
C30H48O3     相似度:80%
Phytochemistry          1998          47          1101-1105
Oleanane-type triterpenes from Viburnum awabuki
Masami Kagawa, Hiroyuki Minami, Mai Nakahara, Hironobu Takahashi, Shigeru Takaoka, Yoshiyasu Fukuyama
Structure      13C NMR   碳谱模拟图
7 .     11-oxo-erythrodiol
C30H48O3     相似度:80%
Phytochemistry          1998          47          1337-1341
Oleanane-type triterpenes from Viburnum awabuki
Masami Kagawa, Hiroyuki Minami, Mai Nakahara, Hironobu Takahashi, Shigeru Takaoka, Yoshiyasu Fukuyama
Structure      13C NMR   碳谱模拟图
8 .     11-oxo-erythrodiol
    相似度:80%
Archives of Pharmacal Research          2002          25          617-620
Pentacyclic triterpenoids fromllex macropoda
Dae Keun Kim, II Yong Nam, Jin Wook Kim, Tae Yong Shin and Jong Pil Lim
Structure      13C NMR   碳谱模拟图
9 .     3β,28-epoxydihydroxy-11-oxo-12-ene
    相似度:80%
Journal of the Brazilian Chemical Society          2002          13          669-673
Fatty Acid Esters of Triterpenes from Erythroxylum passerinums
Marizeth L. Barreiros, Jorge M. David, Pedro A. de P. Pereira, Maria L. S. Guedes and Juceni P. David
Structure      13C NMR   碳谱模拟图
10 .     3β-acetoxy-12-oleanen-11-one
    相似度:78.1%
China Journal of Chinese Materia Medica          2010          35          2708-2711
Chemical constituents of Indigofera pseudotinctoria
WEN Erya; LIANG Hong
Structure      13C NMR   碳谱模拟图
11 .     11-keto-β-amyrenyl-acetate
    相似度:78.1%
Lishizhen Medicine and Materia Medica Research          2011          22          1329-1330
The Chemical Constituents of Euphorbia cyathophora
CHEN Lin; MU Shu-zhen; JIANG Chun-yong; GE Yong-hui; ZHANG Jian-xin; HAO Xiao-jiang
Structure      13C NMR   碳谱模拟图
12 .     (3α,18β,20β)-3-hydroxy-11-oxo-olean-12-en-29-oic acidmethyl ester
    相似度:77.4%
Bioorganic & Medicinal Chemistry          2010          18          433-454
Synthesis of glycyrrhetinic acid derivatives for the treatment of metabolic diseases
Igor Beseda, Laszlo Czollner, Priti S. Shah, Rupesh Khunt, Rawindra Gaware, Paul Kosma, Christian Stanetty, Maria Carmen del Ruiz-Ruiz, Hassan Amer, Kurt Mereiter, Thierry Da Cunha, Alex Odermatt, Dirk Claßen-Houben, Ulrich Jordis
Structure      13C NMR   碳谱模拟图
13 .     11-oxo-3β-hydroxy-olean-12-ene
    相似度:76.6%
Chinese Pharmaceutical Journal          2005          40          900-902
Studies on chemical constituents of Sabia schumanniana
LIANG Guang-yi, ZHOU Ying, CAO Pei-xue, XU Bi-xue
Structure      13C NMR   碳谱模拟图
14 .     (3α,18β,20β)-11-oxo-3-trifluoromethylsulfonylamino-olean-12-en-29-oic acid
    相似度:76.6%
Bioorganic & Medicinal Chemistry          2010          18          7522-7541
Synthesis of novel 3-amino and 29-hydroxamic acid derivatives of glycyrrhetinic acid as selective 11β-hydroxysteroid dehydrogenase 2 inhibitors
Christian Stanetty, Laszlo Czollner, Iris Koller, Priti Shah, Rawindra Gaware, Thierry Da Cunha, Alex Odermatt, Ulrich Jordis, Paul Kosma, Dirk Claßen-Houben
Structure      13C NMR   碳谱模拟图
15 .     (3α,18β,20β)-3-(acetylamino)-11-oxo-olean-12-en-29-oicacid
    相似度:75%
Bioorganic & Medicinal Chemistry          2010          18          7522-7541
Synthesis of novel 3-amino and 29-hydroxamic acid derivatives of glycyrrhetinic acid as selective 11β-hydroxysteroid dehydrogenase 2 inhibitors
Christian Stanetty, Laszlo Czollner, Iris Koller, Priti Shah, Rawindra Gaware, Thierry Da Cunha, Alex Odermatt, Ulrich Jordis, Paul Kosma, Dirk Claßen-Houben
Structure      13C NMR   碳谱模拟图
16 .     3,11-dioxo-18β-olean-12-en-28-oic acid
    相似度:74.1%
Chemistry of Natural Compounds          1992          28          1-23
13C NMR SPECTROSCOPY OF OLEANANE DERIVATIVES
A. I. Kalinovskii
Structure      13C NMR   碳谱模拟图
17 .     Methyl 11-oxo-olean-12-en-30-oate
    相似度:74.1%
Zeitschrift für Naturforschung B          2011          66          521-532
Synthesis and Antitumor Activity of Ring A-modified Glycyrrhetinic Acid Derivatives
R. Csuk, S. Schwarz, B. Siewert, R. Kluge, and D. Ströhl
Structure      13C NMR   碳谱模拟图
18 .     (3α,18β,20β)-N-hydroxy-N-methyl-11-oxo-3-[(trifluoro-methylsulfonyl)amino]-olean-12-en-29-amide
    相似度:74.1%
Bioorganic & Medicinal Chemistry          2010          18          7522-7541
Synthesis of novel 3-amino and 29-hydroxamic acid derivatives of glycyrrhetinic acid as selective 11β-hydroxysteroid dehydrogenase 2 inhibitors
Christian Stanetty, Laszlo Czollner, Iris Koller, Priti Shah, Rawindra Gaware, Thierry Da Cunha, Alex Odermatt, Ulrich Jordis, Paul Kosma, Dirk Claßen-Houben
Structure      13C NMR   碳谱模拟图
19 .     (3β,18β,20β)-3-acetoxy-N-methyl-N-methoxy-11-oxo-olean-12-en-29-amide
    相似度:73.5%
Bioorganic & Medicinal Chemistry          2010          18          7522-7541
Synthesis of novel 3-amino and 29-hydroxamic acid derivatives of glycyrrhetinic acid as selective 11β-hydroxysteroid dehydrogenase 2 inhibitors
Christian Stanetty, Laszlo Czollner, Iris Koller, Priti Shah, Rawindra Gaware, Thierry Da Cunha, Alex Odermatt, Ulrich Jordis, Paul Kosma, Dirk Claßen-Houben
Structure      13C NMR   碳谱模拟图
20 .     lantanone
C32H48O5     相似度:73.3%
Journal of Natural Products          2000          63          765-767
Nematicidal Constituents of the Aerial Parts of Lantana camara
Sabira Begum,Aneela Wahab, Bina S. Siddiqui, and Fatima Qamar
Structure      13C NMR   碳谱模拟图
21 .     krukovine C
C30H46O4     相似度:73.3%
Journal of Natural Products          1996          59          1072-1075
Triterpenes from Brazilian Medicinal Plant “Chuchuhuasi” (Maytenus krukovii)
Osamu Shirota, Toshihiko Tamemura, Hiroshi Morita, Koichi Takeya, and Hideji Itokawa
Structure      13C NMR   碳谱模拟图
22 .     olean-1 2-ene-3α,16β-diol
C30H50O2     相似度:73.3%
Planta Medica          1989          55          44-47
New Hepatoprotective Triterpenes from Canarium album
Masaharu Tamai, Naoharu Watanabe, Maywni Soineya,Hideaki Kondoh, Sadafumi Omura Zhang PeiLing, Rao Chang, and Chen Wei Ming
Structure      13C NMR   碳谱模拟图
23 .     23-Oxoerythrodiol
    相似度:73.3%
Chemistry of Natural Compounds          1992          28          1-23
13C NMR SPECTROSCOPY OF OLEANANE DERIVATIVES
A. I. Kalinovskii
Structure      13C NMR   碳谱模拟图
24 .     3β-hydroxyolean-12-en-11-one
    相似度:73.3%
Natural Product Sciences          1998          4          253-256
Oleanane Triterpenoids from Gordonia ceylanica
Herath, H.M.T.B.; Athukoralage, P.S.
Structure      13C NMR   碳谱模拟图
艰难困苦,玉汝于成。
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