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免费共享(Chemistry of Carbon Nanotubes)
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Contents 1. Introduction 1 2. Covalent Approaches 1 2.1. Sidewall Halogenation of CNT 1 2.2. Hydrogenation 3 2.3. Cycloadditions 3 2.4. Radical Additions 5 2.5. Electrophilic Additions 7 2.6. Addition of Inorganic Compounds 7 2.7. Ozonolysis 7 2.8. Mechanochemical Functionalizations 7 2.9. Plasma Activation 8 2.10. Nucleophilic Additions 8 2.11. Grafting of Polymers 8 2.11.1. “Grafting to” Method 8 2.11.2. “Grafting from” Method 8 3. Defect Site Chemistry 9 3.1. Amidation/Esterification Reactions 9 3.2. Attachment of Biomolecules 11 3.3. Grafting of Polymers to Oxidized Nanotubes 12 4. Noncovalent Interactions 13 4.1. Polymer Composites 13 4.1.1. Epoxy Composites 13 4.1.2. Acrylates 14 4.1.3. Hydrocarbon Polymers 15 4.1.4. Conjugated Polymers 15 4.1.5. Other Nanotube-Polymer Composites 16 4.2. Interactions with Biomolecules and Cells 18 5. Endohedral Filling 21 5.1. Encapsulation of Fullerene Derivatives and Inorganic Species 21 5.2. Encapsulation of Biomolecules 22 5.3. Encapsulation of Liquids 23 6. Concluding Remarks 23 7. Acknowledgments 23 8. References 23 |
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