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Janus Particles: Synthesis, Self-Assembly, Physical Properties, and Applications 1. Introduction A 2. Synthetic Strategies C 2.1. Biological, Biobased, and Biomimetic JPs C 2.2. Unimolecular JPs: Dendrimers, Dendrimerlike Polymers, Heterografted Polymers, Polyhedral Oligomeric Silsesquioxanes E 2.3. Janus Micelles Using Self-Assembly of Block Copolymers in Solution J 2.3.1. Considerations on the Corona Phase Segregation J 2.3.2. Experimental Techniques To Probe the Corona Phase Behavior K 2.3.3. Experimental Systems L 2.3.4. Chemical Transformation of Self-Assemblies in Solution L 2.4. Janus Particles via Self-Assembled Block Terpolymer Bulk Structures N 2.5. Janus Particles via Desymmetrization at Interfaces Q 2.5.1. Modification Strategies at Planar Surfaces Q 2.5.2. Sequential Deposition in Sacrificial Templates T 2.5.3. Desymmetrization in High Internal Interface Systems U 2.6. Janus Particles via Symmetry-Breaking in Confined Volumes X 2.6.1. Phase Separation in (Mini)emulsions X 2.6.2. Phase Inversion Z 2.7. Seeded Emulsion Polymerization AA 2.8. Electrohydrodynamic Jetting AB 2.9. Microfluidics AC 2.9.1. Side-by-Side Emulsification AC 2.9.2. Continuous Flow Lithography AE 2.10. Inorganic Janus Nanoparticles AF 2.10.1. Desymmetrization at Interfaces AF 2.10.2. Dumbbell-Shape Inorganic Nanoparticles AH 2.10.3. Self-Assembly Strategies toward Janus Nanoparticles AH 2.10.4. DNA-Modified Janus NP AK 2.11. Miscellaneous Techniques AL 3. Self-Assembly AN 3.1. Self-Assembly of Soft, Nanoscale Janus Micelles, Cylinders, and Discs AP 3.2. Self-Assembly of Amphiphilic Janus Colloids AR 3.3. Dipolar Janus Colloids AS 3.4. Self-Assembly in External Fields AT 3.4.1. Self-Assembly in Electrical Fields AT 3.4.2. Self-Assembly in Magnetic Fields AU 4. Physical Properties and Applications AW 4.1. Interfacial Activity AW 4.2. Physical Phenomena and Application of Individual Janus Particles BC 4.2.1. Rotationally Anisotropic Optical Properties- Modulated Optical Nanoprobes BC 4.2.2. Anisotropic Probes for Optical Traps BD 4.2.3. E-Paper Display Technology BD 4.2.4. Self-Propulsion BD 4.3. Janus Particles Interfacing Bio and Life Science BE 5. Closing Remarks and Outlook BH Author Information BJ Corresponding Author BJ Notes BJ Biographies BJ References BJ |
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2013-04-05 11:23:28, 71.42 M
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