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jialete592(金币+2,VIP+0):感谢回答，虽然文献无法下载
这种物质存在的，你看一下以下几篇文章：
1、Burk, Mark Joseph; Bienewald, Frank; Zanotti-Gerosa, Antonio. Preparation of enantiomerically enriched carboxylic acid derivatives by asymmetric hydrogenation. PCT Int. Appl. (1999)
2、Hanyu, Takeshi; Yorozudo, Hidetoshi. High-contrast rapid-processing silver halide photographic material spectrally sensitized with merocyanine dye. Jpn. Kokai Tokkyo Koho (1987)
3、Sun, Xianfeng; Zhou, Le; Wang, Chun-Jiang; Zhang, Xumu. Rh-catalyzed highly enantioselective synthesis of 3-arylbutanoic acids. Angewandte Chemie, International Edition (2007), 46(15)
4、Padwa, Albert; Wang, Qiu. Rhodium(I)-Catalyzed Nucleophilic Ring-Opening Reactions of Oxabicyclo Adducts Derived from the [4 + 2]-Cycloaddition of 2-Imido-Substituted Furans. Journal of Organic Chemistry (2006), 71(8), 3210-3220.
5、Abarbri, Mohamed; Parrain, Jean-Luc; Kitamura, Masato; Noyori, Ryoji; Duchene, Alain. Palladium-Catalyzed Cross-Coupling of 3-Iodobut-3-enoic Acid with Organometallic Reagents. Synthesis of 3-Substituted But-3-enoic Acids. Journal of Organic Chemistry (2000), 65(22), 7475-7478
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CH2=C(Ph)-CH2-COCl 这种物质你看这篇文章
1、Padwa, Albert; Eidell, Cheryl K.; Lynch, Stephen M. A new construct of the CIS-3a-aryloctahydroindole skeleton via the [4+2] cycloaddition of furanyl carbamates. Heterocycles (2002), 58 227-242
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