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jitingjian

铁虫 (小有名气)

[求助] 氯化镁与尿素反应生成啥???

怎么解释下面这句话:Magnesium chloride hexahydrate and urea were dissolved
in the distilled water followed by the addition of
PEG6000 as dispersant at room temperature. The mixture
was then stirred vigorously for about 4 h at 95C to get the
white basic magnesium carbonate precipitate. Finally,
ammonia solution (25%) was dropped into the resulting
precipitate by a precipitation conversion method to obtain
the Mg(OH)2 precipitate (coded as nanosheets A).
氯化镁与尿素生成碱式碳酸镁?又与氨水生成氢氧化镁?
那碳酸镁会和氨水生成氢氧化镁哇??
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fighting
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jitingjian

铁虫 (小有名气)

引用回帖:
2楼: Originally posted by ZBPJJ529810 at 2013-03-12 19:37:37
我看到一个资料:MgCl2 + 4CO(NH2)2 = MgCl2.4CO(NH2)2

可否告知资料来源撒?
fighting
3楼2013-03-12 21:48:02
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ZBPJJ529810

至尊木虫 (知名作家)

铸剑堂堂主


【答案】应助回帖

★ ★ ★
感谢参与,应助指数 +1
jitingjian: 金币+2, ★有帮助 2013-03-12 21:48:12
houchenxmc: 金币+1, 谢谢参与 2013-03-13 09:13:50
houchenxmc: 回帖置顶 2013-03-13 09:13:51
我看到一个资料:MgCl2 + 4CO(NH2)2 = MgCl2.4CO(NH2)2
2楼2013-03-12 19:37:37
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jiagle

专家顾问 (知名作家)

【答案】应助回帖

★ ★ ★ ★ ★ ★ ★ ★
感谢参与,应助指数 +1
jitingjian: 金币+5, ★★★很有帮助 2013-03-13 08:51:43
houchenxmc: 金币+3, 谢谢参与 2013-03-13 09:14:00
houchenxmc: 回帖置顶 2013-03-13 09:14:01
反应机理是这样的:
1、尿素水解
    CO(NH2)2 + 2H2O = (NH4)2CO3
2、碱式碳酸镁生成(文献中只说碳酸镁是不太准确的,碳酸根的浓度并不会太高)
    3CO3(2-) + 2H2O + Mg(2+) = Mg2(OH)2CO3(s) + HCO3(-)
3、氨水加入,将沉淀表面转化为Mg(OH)2(平衡移动原理),相当于coating,而氢氧化镁的结构是层状,所以是片状包覆(sheet)。
    Mg2(OH)2CO3 + 2NH3.H2O = 2Mg(OH)2 + (NH4)2CO3
4楼2013-03-13 08:05:18
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jitingjian

铁虫 (小有名气)

引用回帖:
4楼: Originally posted by jiagle at 2013-03-13 08:05:18
反应机理是这样的:
1、尿素水解
    CO(NH2)2 + 2H2O = (NH4)2CO3
2、碱式碳酸镁生成(文献中只说碳酸镁是不太准确的,碳酸根的浓度并不会太高)
    3CO3(2-) + 2H2O + Mg(2+) = Mg2(OH)2CO3(s) + HCO3(-)
3 ...

碱式碳酸镁与氨水反应是否是可逆反应?
fighting
5楼2013-03-13 08:52:15
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