[½»Á÷] ÇóÖúÎü¸½¶¯Á¦Ñ§·½ÃæÊé¼®

9
Theoretical Approaches to the Kinetics
of Adsorption, Desorption, and
Reactions at Surfaces
H. J. KREUZER and STEPHEN H. PAYNE Department of Physics,
Dalhousie University, Halifax, Nova Scotia, Canada
I. Introduction 439
II. Desorption Under Quasi-equilibrium Conditions 441
A. Lattice gas models 443
B. The chemical potential 444
C. Transfer matrix method 446
D. Examples 453
III. Kinetic Lattice Gas Models 462
A. Nondissociative adsorption 463
B. Adsorption and desorption via precursors 470
C. Adsorption and desorption with surface reconstruction 472
IV. Concluding Remarks 476
References 477