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[求助] 求助cause a downshift in d-band energy center

because of the interactions between the Ni core and the Pd shell, such as the ligand effect, cause a downshift in d-band energy center, which is favourable for the promotion of the electrochemical activity and stability of Ni@Pd/graphene compared to Pd/graphene.求助高手这段话中cause a downshift in d-band energy center是什么意思?
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