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1. A chiral zinc borate Zn2(OH)BO3, which exhibits nonlinear optical, photoluminescent and photoelectronic properties, has been successfully prepared through a hydrothermal reaction. The structure of the compound has a ZnO matrix and the electronic structure of the compound can be regarded as that for ZnO modified by the presence of B atoms. The luminescence properties of Zn2(OH)BO3 were characterized by excitation and emission spectra. Photovoltage signals were observed for the as-synthesized compound and for samples calcined at various temperatures by surface photovoltage spectroscopy (SPS) and field-induced surface photovoltage spectroscopy (FISPS). The results show that Zn2(OH)BO3 has photoelectric transformation ability. Either thermal treatment or application of an external electric field enhances the photovoltage responses of the compound to a considerable extent.

2 A highly intense green-emitting phosphor BaY2Si2Al2O2N5 : Eu2+ (BYN : Eu2+) peaking at 511 nm was synthesized by a solid state reaction. The structure refinement, luminescence properties of BYN : Eu2+ phosphors as well as their thermal quenching and the fabrication of white-light-emitting diodes (W-LEDs) were firstly investigated. By partially substituting Ba by Sr, namely (Ba,Sr) Y2Si2Al2O2N5 : Eu2+ (BSYN : Eu2+), the emission peak was shifted to 565 nm, giving a yelloworange color, due to the splitting of the 5d energy level. By utilizing a mixture of blue-emitting BaMgAl10O17 : Eu2+, green-emitting BYN : Eu2+ and red-emitting CaAlSiN3 : Eu2+ phosphors as light converters, an intense white GaN-based n-UV-LED (380 nm) was fabricated to a exhibit good color-rendering index Ra of 84.5 at a correlated color temperature of 5089 K and CIE coordinates of (0.3425, 0.3478). Based on these results, we are currently evaluating the potential application of BYN : Eu2+ as a green-emitting near-UV convertible phosphor.
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1. ºÏ³ÉÁ˸ßЧ·¢ÉäUV ¹âµÄCaSiO3 : Pr3 + ÐÂÐÍÓ«¹âÌå,Ñо¿ÁËÊÒÎÂÏÂPr3 + µÄ4 f 5 d ̬µÄ·¢ÉäºÍ¼¤·¢¹âÆ×, Pr3 + µÄ4 f 5 d ̬µÄ×îµÍ×ÓÄܼ¶Ïò4 f 2 ×é̬µÄ3 H4 ,3 H6 ºÍ1 G4 Äܼ¶Ô¾Ç¨²úÉúUV ·¢Éä,²¢²»°éËæÓÐ4 f--4 f Äܼ¶Ô¾Ç¨µÄ¿É¼û¹â·¢Éä¡£Pr3 + µÄŨ¶Èâ§ÃðÊÇÓÉÓÚ·øÉäºÍÎÞ·øÉäÄÜÁ¿´«µÝÔì³ÉµÄ,ͬʱ,ÔÚCaSiO3 ÖÐ,´æÔÚPr3 +¡úGd3 + µÄÄÜÁ¿´«µÝ,̽ÌÖÁËÆäÄÜÁ¿´«µÝÌØÐÔ¡£

2. ÓùÌÏà·¨ÖÆ±¸»¯ºÏÎïCaY1 - xBO4¡ÃxEu , Ñо¿Eu3 +ÔÚCaYBO4 ÖеÄÈ¡´ú¸ñλºÍ·¢¹âÌØÐÔ¡£µ±Eu3 + ²ôÔÓŨ¶È²»´óʱ, ´æÔÚÁ½¸ö·¢¹âÖÐÐÄ,ÈÏΪÊÇÈ¡´ú»ùÖÊÖÐÓÐÁ½¸öY¸ñλµÄ½á¹û; ͨ¹ý¶ÔEu-O µÄµçºÉÇ¨ÒÆ¼¤·¢´øÎ»ÖõķÖÎö, ±íÃ÷Eu3 + Ëù´¦°ËÃæÌåÖÐÐĸñλµÄ¶Ô³ÆÐÔÔ½µÍ, Eu-OµÄµçºÉÇ¨ÒÆ´øÔ½Æ«ÏòÓڶ̲¨; µ±Eu3 + µÄ²ôÔÓŨ¶È½Ï´ó( x > 0110) ʱ, Eu3 + Àë×ÓÒ²¿ÉÕ¼¾ÝCa2 + ¸ñλ, ͬʱEu3 +»¹Ô­³ÉEu2 + ¡£

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[ Last edited by guoyujiao on 2012-12-30 at 11:36 ]

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°®ÓëÓêÏÂ: ½ð±Ò+3 2012-12-31 20:25:10
guoyujiao: ½ð±Ò+20, ·­ÒëEPI+1, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, Ê®·Ö¸Ðл£¬ÐÂÄê¿ìÀÖ~£¡ 2013-01-01 21:11:26
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¡ª¡ª¡ª¡ªA chiral zinc borate Zn2(OH)BO3, which exhibits nonlinear optical, photoluminescent and photoelectronic properties, has been successfully prepared through a hydrothermal reaction.
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¡ª¡ª¡ª¡ªThe structure of the compound has a ZnO matrix and the electronic structure of the compound can be regarded as that for ZnO modified by the presence of B atoms.
·­Ò룺»¯ºÏÎïµÄ½á¹¹ÖÐÓÐÒ»¸öÑõ»¯Ð¿»ù²¢ÇÒ»¯ºÏÎïµÄµç×Ó ½á¹¹Ê½¿ÉÒÔÊÓΪÑõ»¯Ð¿ÊÇÒòΪÅðÔ­×ӵĴæÔÚ¶ø¸Ä±äµÄ¡£#

¡ª¡ª¡ª¡ªThe luminescence properties of Zn2(OH)BO3 were characterized by excitation and emission spectra.
·­Ò룺¼îʽÅðËáпÑεķ¢¹âÐÔÄܵÄÌØÕ÷ÔÚÓÚÆä¼¤·¢ºÍ·¢Éä¹âÆ×¡£#


¡ª¡ª¡ª¡ªPhotovoltage signals were observed for the as-synthesized compound and for samples calcined at various temperatures by surface photovoltage spectroscopy (SPS) and field-induced surface photovoltage spectroscopy (FISPS).
·­Ò룺¹Û²ìµ½ËùºÏ³ÉµÄ»¯ºÏÎïµÄ¹âµçѹºÍÔÚ²»Í¬Î¶ÈÏÂìÑÉÕµÄÑùÆ·±íÃæ¹âµçѹ£¨SPS£©ºÍ³¡ÓÕµ¼±íÃæ¹âµçѹÆ×£¨FISPS£©

¡ª¡ª¡ª¡ªThe results show that Zn2(OH)BO3 has photoelectric transformation ability.
·­Ò룺£¨Ñо¿µÄ)½á¹û±íÃ÷£¬¼îʽÅðËáпӵÓйâµçת»»µÄÄÜÁ¦¡£#

¡ª¡ª¡ª¡ª Either thermal treatment or application of an external electric field enhances the photovoltage responses of the compound to a considerable extent.
·­Ò룺ÈÈ´¦Àí»òÕßÊ©¼ÓÓÀ¾ÃÐÔÍâµç³¡¶¼¿ÉÒÔÔÚÏ൱´óµÄ³Ì¶ÈÉÏÔöÇ¿»¯ºÏÎïµÄÏìÓ¦¹âµçѹ¡£#


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¡ª¡ª¡ª¡ªA highly intense green-emitting phosphor BaY2Si2Al2O2N5 : Eu2+ (BYN : Eu2+) peaking at 511 nm was synthesized by a solid state reaction.
·­Ò룺¿ÉÒÔͨ¹ý¹Ì̬·´Ó¦ºÏ³É ·¢³ö¸ßÇ¿¶ÈÂÌÉ«¹âµÄÓ«¹âÌå¡°îð²ÎÔÓîÆ¹èÂÁÑõµª¡±£¬ËüµÄ·åµÄ×î¸ßÖµ³öÏÖÔÚ511ÄÉÃ×´¦£¬


The structure refinement, luminescence properties of BYN : Eu2+ phosphors as well as their thermal quenching and the fabrication of white-light-emitting diodes (W-LEDs) were firstly investigated.
·­Ò룺Ê×ÏÈÑо¿ÁËBYN£ºEu2+Á×¹âÌ徫ϸ»¯µÄ½á¹¹£¬·¢¹âÐÔÄÜÒÔ¼°ËûÃǵÄÈÈ´ã»ðºÍ°×É«·¢¹â¶þ¼«¹ÜµÄÖÆÔì



By partially substituting Ba by Sr, namely (Ba,Sr) Y2Si2Al2O2N5 : Eu2+ (BSYN : Eu2+), the emission peak was shifted to 565 nm, giving a yelloworange color, due to the splitting of the 5d energy level.
·­Ò룺ͨ¹ý²¿·ÖµØÓÃïÈ´úÌæ±µ£¬Ò²¾ÍÊÇ£¨Ba£¬Sr£©Y2Si2Al2O2N5£ºEu2+£¨BSYN£ºEu2+£©£¬ÓÉÓÚ5d¹ìµÀÄܼ¶µÄ·ÖÁÑÄÜ£¬·¢Éä·å»áÒÆ¶¯µ½565ÄÉÃ×´¦£¬²¢ÏÔʾ³öéÙ»ÆÉ«¡£

By utilizing a mixture of blue-emitting BaMgAl10O17 : Eu2+, green-emitting BYN : Eu2+ and red-emitting CaAlSiN3 : Eu2+ phosphors as light converters, an intense white GaN-based n-UV-LED (380 nm) was fabricated to a exhibit good color-rendering index Ra of 84.5 at a correlated color temperature of 5089 K and CIE coordinates of (0.3425, 0.3478).
·­Ò룺ͨ¹ýʹÓ÷¢À¶É«µÄBaMgAl10O17£ºEu2+,·¢ÂÌÉ«¹âµÄBYN:Eu2+ºÍ·¢ºìÉ«¹âµÄCaAlSiN3£ºEu2+Á×¹âÖʵĻìºÏÎï×÷Ϊ¹âת»»¹¤¾ß£¬²¢×°±¸Á˺ÜÇ¿µÄ°×É«GaN»ùµÄ½ü×ÏÍâ·¢¹â¶þ¼«¹Ü£¬ÒÔÌṩÁ¼ºÃµÄÏÔɫָÊý°ë¾¶ÔÚ84.5£¬  Ïà¹ØÉ«Î¶ÈΪ5089¿ª¶ûÎÄ£¬CIE×ø±êΪ (0.3425, 0.3478).


Based on these results, we are currently evaluating the potential application of BYN : Eu2+ as a green-emitting near-UV convertible phosphor.
·­Ò룺»ùÓÚÕâЩ½á¹û£¬ÎÒÃÇÏÖÔÚÆÀ¹ÀBYN£ºEu2+×÷Ϊ·¢ÂÌÉ«¹âµÄ½ü×ÏÍâ¿Éת»»Ó«¹âÌåµÄDZÔÚÓ¦ÓüÛÖµ¡£

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ºÏ³ÉÁ˸ßЧ·¢ÉäUV ¹âµÄCaSiO3 : Pr3 + ÐÂÐÍÓ«¹âÌå,Ñо¿ÁËÊÒÎÂÏÂPr3 + µÄ4 f 5 d ̬µÄ·¢ÉäºÍ¼¤·¢¹âÆ×, Pr3 + µÄ4 f 5 d ̬µÄ×îµÍ×ÓÄܼ¶Ïò¡¾4 f 2 ×é̬µÄ3 H4 ,3 H6 ºÍ1 G4 ¡¿Äܼ¶Ô¾Ç¨²úÉúUV ·¢Éä,²¢²»°éËæÓÐ4 f--4 f Äܼ¶Ô¾Ç¨µÄ¿É¼û¹â·¢Éä¡£


·­Ò룺 Novel Fluorescent CaSiO3 : Pr3 + £¬which gives high efficient ultraviolet-emitting was synthesised .and research was given on  the emission and excitation spectra of 4f5d energy level of Pr3+ at roomtemperature£¬transition of lowest sublevels of the 4 f 5 d states of Pr3 +  to  energy levels of 3 H4, 3 H6 and 1 G4  of  4 f 2states will   produce UV emission, and was not accompanied by  a visible light in transition of 4 f - 4 f energy level .


Pr3 + µÄŨ¶Èâ§ÃðÊÇÓÉÓÚ·øÉäºÍÎÞ·øÉäÄÜÁ¿´«µÝÔì³ÉµÄ,ͬʱ,ÔÚCaSiO3 ÖÐ,´æÔÚPr3 +¡úGd3 + µÄÄÜÁ¿´«µÝ,̽ÌÖÁËÆäÄÜÁ¿´«µÝÌØÐÔ¡£

·­Ò룺The concentration quenching of Pr3+was due to the  radiation £¬nonradiative energy transfer£¬together with the presence of the energy transfer from Pr3 +¡úGd3 +ion in the CaSiO3 and the energy transfer characteristics was investigated.

¡¾µÚËĶΡ¿

ÓùÌÏà·¨ÖÆ±¸»¯ºÏÎïCaY1 - xBO4¡ÃxEu , Ñо¿Eu3 +ÔÚCaYBO4 ÖеÄÈ¡´ú¸ñλºÍ·¢¹âÌØÐÔ¡£
·­Ò룺Compound CaY1 - xBO4¡ÃxEu was prepared by the solid phase method£¬the site substitution and the luminescence propertities was researched.

µ±Eu3 + ²ôÔÓŨ¶È²»´óʱ, ´æÔÚÁ½¸ö·¢¹âÖÐÐÄ,ÈÏΪÊÇÈ¡´ú»ùÖÊÖÐÓÐÁ½¸öY¸ñλµÄ½á¹û; ͨ¹ý¶ÔEu-O µÄµçºÉÇ¨ÒÆ¼¤·¢´øÎ»ÖõķÖÎö, ±íÃ÷Eu3 + Ëù´¦°ËÃæÌåÖÐÐĸñλµÄ¶Ô³ÆÐÔÔ½µÍ, Eu-OµÄµçºÉÇ¨ÒÆ´øÔ½Æ«ÏòÓڶ̲¨; µ±Eu3 + µÄ²ôÔÓŨ¶È½Ï´ó( x > 0110) ʱ, Eu3 + Àë×ÓÒ²¿ÉÕ¼¾ÝCa2 + ¸ñλ, ͬʱEu3 +»¹Ô­³ÉEu2 + ¡£

When the doping congcentration of Eu 3+was not high, the existence of two luminesecence center can be regarded as the result of  two Y sites in the substitution matrix;through the analysis of the position of the excitation band of charge transfer of Eu-O,it indicated that the lower the symmetrysity of the central site of octahedron ,the  higher the inlination to shortwave the charge transfer band ;
when the doping concentration of Eu3+was high (above 110),Eu 3+will occupy the Ca2+site ,in the meanwhile  Eu3+reduced to Eu2+.


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