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lxpk

铜虫 (初入文坛)

[交流] 请问CNT得Raman特征峰是多少?

请问CNT得Raman特征峰是多少?
谢谢!
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huazet2000

金虫 (正式写手)

多壁碳纳米管:大约1350 cm-1 处一个    1580cm-1左右一个     峰会分裂
单壁碳纳米管:200cm-1 处左右有几个峰  1350 cm-1 左右一个    1580cm-1左右一个
管的质量较高时 1350 cm-1处的峰会较低。

有时峰会有一些偏移,如在1350cm-1处没有,而在1344cm-1处有,但偏移不会很大
2楼2007-07-26 08:53:51
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不得不爱

有收获,谢谢
3楼2007-07-26 20:27:06
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lingyun79

木虫 (著名写手)

a strong sharp peak
at 1577.7 cm-1 (G line), which can be assigned to the
high-frequency E2g first-order mode, and a strong sharp
peak at 1349.9 cm-1 (D line) as well as a weak peak,
appeared as a shoulder peak of G line, at 1612.9 cm-1
(D¢ line). The origin of the D and D¢ lines has been
explained as disorder-induced features due to the finite
particle size effect or lattice distortion of graphite
crystals. Therefore, the very strong relative intensity
of the D line may be the result of a
high lattice distortion of graphite crystals in the HCNTs.
The weak peak at 1099.0 cm-1 was rarely reported
previously. The peak at 2447.0 cm-1 was frequently reported
previously, but the origin of it remains uncertain.
Here, the peak 2447.0 cm-1 seems to be the combination
of D line and the peak 1099.0 cm-1 (1349.9 + 1099.0 )
2448.9).

[ Last edited by lingyun79 on 2007-7-26 at 23:13 ]
4楼2007-07-26 23:11:42
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