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聚苯胺膜的成品
目的：制备高分子量聚苯胺（high molecular weight polyaniline）；
原因：PANI膜需要高分子量的聚苯胺，使其具备良好的机械性能。
求助：高分子量聚苯胺制备过程中的注意事项和方法可行性。
办法：低温合成方法制备的聚苯胺膜已经完成。有图为证。
参考文献：
[1] Stejskal J, Riede A, Hlavatá D, et al. The effect of polymerization temperature on molecular weight, crystallinity, and electrical conductivity of polyaniline[J]. Synthetic Metals. 1998, 96(1): 55-61.
[2] Beadle P M, Nicolau Y F, Banka E, et al. Controlled polymerization of aniline at sub-zero temperatures[J]. Synthetic Metals. 1998, 95(1): 29-45.
[3] Adams P N, Laughlin P J,Monkman A P. Synthesis of high molecular weight polyaniline at low temperatures[J]. Synthetic Metals. 1996, 76(1-3): 157-160.
[4] Adams P N, Laughlin P J, Monkman A P, et al. Low temperature synthesis of high molecular weight polyaniline[J]. Polymer. 1996, 37(15): 3411-3417.
[5] Mattoso L H C, MacDiarmid A G,Epstein A J. Controlled synthesis of high molecular weight polyaniline and poly(o-methoxyaniline)[J]. Synthetic Metals. 1994, 68(1): 1-11.
[ Last edited by 11900490 on 2012-12-29 at 19:57 ] |
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