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[交流] Chemical Reviews最新综述：异相纳米复合物催化剂中的催化协同作用已有32人参与

最新一期的顶级综述杂志Chemical Reviews刊发了由中科院上海硅酸盐研究所施剑林研究员撰写的综述，题目为On the Synergetic Catalytic Effect in Heterogeneous Nanocomposite Catalysts，介绍了异相纳米复合物催化剂的各种合成方法，并着重综述了纳米复合物中各组份活性物质在催化反应中的协同效应。全文43页，引文376篇。

1. Introduction
1.1. Definition of the “Synergetic Catalytic Effect” in Heterogeneous Composite Catalysts
1.2. Scope of the Present Review
2. Synthesis of Nanocomposite Catalysts Focused on Mesostructured Composites with a Crystallized Framework
2.1. General Description of Chemical Routes for Synthesizing Nanocomposite Catalysts
2.2. Soft Templating Routes for the Mesoporous Oxides, Mesostructured Zeolites, and Nanocomposites
2.3. Replication Routes for Crystallized Mesoporous Oxides and Binary Mesoporous Composites
2.4. Template-free Routes for Mesoporous Metal Oxides and Composites
2.5. Postencapsulation Routes for the Guest-Loaded Mesoporous Composites
3. Synergetic Catalytic Effects
3.1. One Component Activation by the Other between Two Catalytic Components
3.1.1. Synergetic Effect Proposals
3.1.2. CO Oxidation by Mesoporous CuO/CeO2 Composite Catalysts via Strong Metal–Semiconductor Interaction (SMSI)
3.1.3. Methanol Synthesis by Cu/ZnO-Based Catalysis via Strong Metal–Semiconductor Interaction (SMSI)
3.1.4. Suzuki/Heck C–C Coupling by Mesostructured Pd/NiFe2O4 Composite Catalysts
3.1.5. Selective Oxidation of Organics by Au/TiO2 and Au/CeO2 Nanocomposite Catalysts
3.1.6. Organics Degradation by Au/TiO2, TiO2/Carbon, and TiO2/Semiconductor Nanocomposite Photocatalysts
3.2. Successive Catalytic Functioning of Two Components in Multistep Reactions
3.2.1. Synergetic Effect Proposals
3.2.2. Henry and Adol Condensation Reactions by Mesoporous Acid–Base Catalysts
3.2.3. Dye Degradation by Fe-Doped Mesoporous Zeolite
3.2.4. Ammonia Selective Catalytic Oxidation (SCO) to Nitrogen by a Mesostructured CuO/RuO2 Composite
3.3. Degradation Prevention of the Main Catalyst(s) by Secondary Component(s) for Sustained Catalytic Reactions
3.3.1. Synergetic Effect Proposals
3.3.2. H2 Electro-oxidation by Mesostructured Pt/WO3 Composite Catalysts
3.3.3. Methanol Electro-oxidation by Mesostructured Pt/WO3 Composite Catalysts
3.4. Reactant Storage/Release by the Catalytic Assistants in Multireactant Redox Reactions Catalyzed by Tricomponent Catalysts
3.4.1. Synergetic Effect Proposal
3.4.2. Oxygen Storage/Release in Three Way Catalysis for Automobile Exhaust Purification
3.4.3. Promoted Redox Reaction between CO and NO and between NO and C3H6 by a Tricomponent Catalyst with an Oxygen Storage Support
4. Further Discussions: Role of Interface and Mesostructure in Synergetic Catalytic Effects
4.1. Role of Interface Formation and Contact Angle between Components in the Synergetic Catalytic Effects
4.2. Advantages of Mesostructured Composites for the Synergetic Effects
5. Conclusions and Outlook
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