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[×ÊÔ´] JAPÉÏ ZnO µÄ±íÃæÌ¬Óë·¢¹âµÄ¹âÆ×ÐÔÖʵĹØÏµµÄ×îÐÂ×ÛÊö

Surface-state related luminescence in ZnO nanocrystals

Johannes Fallert,a Robert Hauschild, Felix Stelzl, Alex Urban, Markus Wissinger,
Huijuan Zhou, Claus Klingshirn, and Heinz Kalt
Institut f¨¹r Angewandte Physik, Universität Karlsruhe (TH), Wolfgang-Gaede-Strasse 1,
76131 Karlsruhe, Germany
Received 7 December 2006; accepted 14 February 2007; published online 4 April 2007

We investigate the optical properties of four different samples of ZnO nanocrystals, with a particle
size average varying from 70 up to 380 nm. The photoluminescence PL of all samples shows at
low temperature an emission band around 3.31 eV, which is several orders of magnitude stronger
compared to the PL of bulk ZnO at this energy. This band shows a clear dependence on the surface
to volume ratio of the nanocrystals and is therefore assigned to surface states. Temperature
dependent measurements reveal that this band plays a major role up to room temperature for all
examined ZnO powders. Additionally, intensity dependent measurements display that the origin of
this emission band can be assigned to bound exciton complexes BECs. Compared to the well
known shallow BECs the measured lifetimes of these relatively strong bound excitons states are
much longer. © 2007 American Institute of Physics. DOI: 10.1063/1.2718290

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