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[资源] 好东东<<Modern Raman Spectroscopy-A Practical Approach.pdf>>

Modern Raman
Spectroscopy
– A Practical

Copyright 2005 John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester,
West Sussex PO19 8SQ, England
Telephone (t44) 1243 779777
Contents
Preface ix
Acknowledgements xi
CHAPTER 1 INTRODUCTION, BASIC THEORY
AND PRINCIPLES 1
1.1 Introduction 1
1.2 Basic Theory 2
1.3 Molecular Vibrations 8
1.4 Summary 20
CHAPTER 2 THE RAMAN EXPERIMENT – RAMAN
INSTRUMENTATION, SAMPLE PRESENTATION,
DATA HANDLING AND PRACTICAL ASPECTS
OF INTERPRETATION 23
2.1 Introduction 23
2.2 Choice of Instrument 24
2.3 Visible Excitation 24
2.4 NIR Excitation 30
2.5 Raman Sample Preparation and Handling 31
2.6 Sample Mounting Accessories 41
2.7 Microscopy 45
2.8 Calibration 51
2.9 Data Handling, Manipulation and Quantitation 53
2.10 Approach to Qualitative Interpretation 61
2.11 Summary 67
CHAPTER 3 THE THEORY OF RAMAN SPECTROSCOPY 71
3.1 Introduction 71
3.2 Absorption and Scattering 72
3.3 States of a System and Hooke’s Law 74
3.4 The Nature of Polarizability and the Measurement
of Polarization 76
3.5 The Basic Selection Rule
3.6 Number and Symmetry of Vibrations
3.7 Symmetry Elements and Point Groups
3.8 The Mutual Exclusion Rule
3.9 The Kramer Heisenberg Dirac Expression
3.10 Lattice Modes
3.11 Conclusions
HAPTER 4 RESONANCE RAMAN SCATTERING
4.1 Introduction
4.2 Theoretical Aspects
4.3 Practical Aspects
4.4 Examples of the Use of Resonance Raman Scattering
4.5 Conclusions
HAPTER 5 SURFACE-ENHANCED RAMAN SCATTERING
AND SURFACE-ENHANCED RESONANCE
RAMAN SCATTERING
5.1 Introduction
5.2 Theory
5.3 Electromagnetic and Charge Transfer Enhancement
5.4 Selection Rules
5.5 Applications of SERS
5.6 Applications of SERRS
5.7 The Basic Method
HAPTER 6 APPLICATIONS
6.1 Introduction
6.2 Inorganics and Minerals
6.3 Art and Archaeology
6.4 Polymers and Emulsions
6.5 Colour
6.6 Electronics Applications
6.7 Biological and Pharmaceutical Applications
6.8 Forensic Applications
6.9 Plant Control and Reaction Following
6.10 Summary
HAPTER 7 MORE ADVANCED RAMAN SCATTERING
TECHNIQUES
7.1 Flexible Optics
7.2 Tuneable Lasers, Frequency Doubling and Pulsed Lasers
7.3 Spatially Resolved Systems
7.4 Nonlinear Raman Spectroscopy
7.5 Time Resolved Scattering
7.6 Raman Optical Activity
7.7 UV Excitation
7.8 Conclusions
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