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laiyin_111

木虫 (正式写手)

梦想家

[求助] 求微谱数据

可能为降倍半萜类化合物:

18.1,20.5,26.2,30.0,32.5,35.5,43.8,44.4,59.8,63.8,131.5,152.8,205.8,208.5

谢谢了!
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wq0616

铁杆木虫 (正式写手)

【答案】应助回帖

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感谢参与,应助指数 +1
laiyin_111: 金币+10, ★★★★★最佳答案, 非常感谢!!! 2012-11-15 10:08:34
相似度大于55%的有

1 .     oxyphyllone A
C14H20O3     相似度:85.7%
Chinese Chemical Letters          2009          20          945-948
Oxyphyllones A and B, novel sesquiterpenes with an unusual 4,5-secoeudesmane skeleton from Alpinia oxyphylla
Jun Ju Xu, Ning Hua Tan, Jiang Xiong, Abiodun Humphrey Adebayo, Hong Jin Han , Guang Zhi Zeng , Chang Jiu Ji , Yu Mei Zhang , Mei Ju Zhu
Structure      13C NMR   碳谱模拟图

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2 .     cubebenone
C15H22O     相似度:60%
Journal of Natural Products          2001          64          1183-1190
Sequestered Chemistry of the Arminacean Nudibranch Leminda millecra in Algoa Bay, South Africa
Kerry L. McPhail, Michael T. Davies-Coleman, and John Starmer
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




3 .     drechslerine A
C14H24O2     相似度:57.1%
Journal of Natural Products          2002          65          306-313
Rare Sesquiterpenes from the Algicolous Fungus Drechslera dematioidea
Claudia Osterhage, Gabriele M. König, Ulrich Höller, and Anthony D. Wright
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




4 .     2,4,4-Trimethyl-8-oxononansaure-methylester
    相似度:57.1%
Helvetica Chimica Acta          1980          63          1833-1855
Photochemische Reaktionen 111. Mitteilung [1] Zur Photochemie , -ungesättigter , -Epoxyester I: Singulett- versus Triplettreaktivität
Alex Peter Alder, Hans Richard Wolf, Oskar Jeger
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




5 .     5,5-Dimethyl-9-oxodecansaure-methylester
C13H24O3     相似度:57.1%
Helvetica Chimica Acta          1980          63          1833-1855
Photochemische Reaktionen 111. Mitteilung [1] Zur Photochemie , -ungesättigter , -Epoxyester I: Singulett- versus Triplettreaktivität
Alex Peter Alder, Hans Richard Wolf, Oskar Jeger
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




6 .     6α-acetoxy-4β,5β-dimethyl-1(10)-α-epoxy-2α-hydroxy-7-oxodecalin
C14H20O4     相似度:57.1%
Journal of Natural Products          1992          Vol 55          1186
Secondary Metabolites of the Yellow and Gray Morphs of the Soft Coral Parerythropodium fulvum fulvum: Comparative Aspects
D. Green, Y. Kashman, Y. Benayahu
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




7 .     1(10)-epoxy-2-hydroxy-12-nornardosin-7,11-dione
C14H20O4     相似度:57.1%
Journal of Natural Products          1993          Vol 56          508
Sesquiterpenoids and Norsesquiterpenoids from the Soft Coral Lemnalia africana
Jaroslaw Jurek, Paul J. Scheuer
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




8 .     6-methyl-6-(3'-isopropenyl-cycloprop-1'-en-1'-yl)-heptan-2-on
C14H22O     相似度:57.1%
Helvetica Chimica Acta          1976          59          907-913
Photochemische Reaktionen. 89. Mitteilung [1]. Zur Photochemie konjugierter Epoxy-diene I. Versuche mit (E),β-Jonyliden-epoxiden
Alex Peter Alder, Hans Richard Wolf and Oskar Jeger
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




9 .     Compound 16
    相似度:57.1%
Bioorganic & Medicinal Chemistry Letters          1993          3          359-362
Enantioselective preparation of novel bicyclo[3.2.0]heptane derivatives using ester hydrolysis catalyzed by novo lipolaseTM
Omar Parve, Anne Pals, Vello Kadarpik, Lilja Lahe, Ülo Lille, Peeter Sikk, Aivar Lóokene and, Toomas Välimäe
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




10 .     clavularin A
C12H18O2     相似度:57.1%
Chemical Communications          1983                   322-323
Clavularins, a New Class of Cytotoxic Compounds isolated from the Soft Cora I, Clavularia koellikeri
Mamoru Endo, Masashi Nakagawa, Yoshihiro Hamamoto, and Toshihiro Nakanishi
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




11 .     6,10-dimethylundec-9-en-2-one
C13H24O     相似度:57.1%
Bioorganic & Medicinal Chemistry          2010          18          3116-3124
Structure–activity relationships in the conversion of vitamin K analogues into menaquinone-4. Substrates essential to the synthesis of menaquinone-4 in cultured human cell lines
Yoshitomo Suhara, Akimori Wada, Yoji Tachibana, Masato Watanabe, Kanae Nakamura, Kimie Nakagawa, Toshio Okano
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




12 .     compound 4
C15H25NO     相似度:57.1%
The Journal of Antibiotics          1994          47          6-15
HISPIDOSPERMIDIN, A NOVEL PHOSPHOLIPASE C INHIBITOR PRODUCED BY Chaetosphaeronema hispidulum (Cda) Moesz NR 7127 II. ISOLATION, CHARACTERIZATION AND STRUCTURAL ELUCIDATION
TATSUO OHTSUKA, YOSHIKO ITEZONO, NOBORU NAKAYAMA, AKIKO SAKAI, NOBUO SHIMMA, KAZUTERU YOKOSE, HARUO SETO
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




13 .     hypnophilin
    相似度:57.1%
The Journal of Antibiotics          1994          47          1348-1350
ANTIMICROBIAL METABOLITES FROM Lentinus crinitus
DAWIT ABATE, WOLF-RAINER ABRAHAM
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




14 .     compound
C14H24O2     相似度:57.1%
Journal of the American Chemical Society          2008          130          11114-11121
Total Synthesis, Revised Structure, and Biological Evaluation of Biyouyanagin A and Analogues Thereof
K. C. Nicolaou, T. Robert Wu, David Sarlah, David M. Shaw, Eric Rowcliffe and Dennis R. Burton
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




15 .     compound 5
C16H26O2     相似度:56.2%
Journal of Natural Products          2008          71(11)          1806-1811
Meroditerpenoids and Derivatives from the Brown Alga Cystoseira baccata and Their Antifouling Properties
Redouane Mokrini, Mohammed Ben Mesaoud, Mohammed Daoudi, Claire Hellio, Jean-Philippe Maréchal, Mohamed El Hattab, Annick Ortalo-Magné, Louis Piovetti, and Gérald Culioli
Structure      13C NMR   碳谱模拟图

--------------------------------------------------------------------------------




16 .     6,10,14-trimethylpentadec-13-en-2-one
C18H34O     相似度:56.2%
Bioorganic & Medicinal Chemistry          2010          18          3116-3124
Structure–activity relationships in the conversion of vitamin K analogues into menaquinone-4. Substrates essential to the synthesis of menaquinone-4 in cultured human cell lines
Yoshitomo Suhara, Akimori Wada, Yoji Tachibana, Masato Watanabe, Kanae Nakamura, Kimie Nakagawa, Toshio Okano
Structure      13C NMR   碳谱模拟图
艰难困苦,玉汝于成。
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