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Chem. Soc. Rev.最新综述：有序介孔碳材料的直接合成
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最新一期的Chem. Soc. Rev.刊发了题为Direct synthesis of ordered mesoporous carbons的综述，详细的介绍了有序介孔碳的合成以及应用方面的研究进展。文章25页，引文232篇。 Ordered mesoporous carbon materials have recently aroused great research interest because of their widespread applications in many areas such as adsorbents, catalysts and supports, gas storage hosts, and electrode materials. The direct synthesis strategy from organic–organic self-assembly involving the combination of polymerizable precursors and block copolymer templates is expected to be more flexible in preparing mesoporous carbons, compared with the traditional nanocasting strategy of complicated and high-cost procedures using mesoporous silica materials as the hard template. In this review, we present the fundamentals and recent advances related to the field of ordered mesoporous carbon materials from the direct synthesis strategy of block copolymer soft-templating, with a focus on their controllable preparation, modification and potential applications. Under the guidance of their formation mechanism, the preparation of ordered mesoporous carbons are discussed in detail by consulting different experimental conditions, including synthetic pathways, precursors, catalysts and templates. Both the mesopore size and morphology control are introduced. The potential applications of pure mesoporous carbons, nonmetallic- and metallic-modified mesoporous carbons, and some interpenetrating carbon-based composites are demonstrated. Furthermore, remarks on the challenges and perspectives of research directions are proposed for further development of the ordered mesoporous carbons (232 references). .  1.jpg  2.jpg  3.jpg [ 来自科研家族 材料家族 ] |
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2012-11-08 19:17:16, 5.83 M
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